strontium iodide

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| Verifiedfields = changed

| Watchedfields = changed

| verifiedrevid = 439308815

| ImageFile = Strontium-iodide-unit-cell-3D-balls.png

| ImageSize =

| IUPACName = Strontium iodide

| SystematicName =

| OtherNames =

|Section1={{Chembox Identifiers

| Abbreviations =

| CASNo_Ref = {{cascite|correct|??}}

| CASNo = 10476-86-5

| CASNo_Comment = (anhydrous)

| ChemSpiderID = 23637

| UNII_Ref = {{fdacite|correct|FDA}}

| UNII = F6V5HOR0O5

| EINECS = 233-972-1

| PubChem = 25304

| SMILES = I[Sr]I

| SMILES2 = [Sr+2].[I-].[I-]

| InChI = 1S/2HI.Sr/h2*1H;/q;;+2/p-2

| RTECS = WK9275000}}

|Section2={{Chembox Properties

| Formula = {{chem2|SrI2}} (anhydrous)
{{chem2|SrI2*6H2O}} (hexahydrate)

| Sr=1|I=2

| MolarMass_notes = (anhydrous)

| Appearance = Colorless to white crystalline plates

| Density = 4.55 g/cm3 (anhydrous){{Cite book| title =Thermophysical properties of chemicals and hydrocarbons| author =Yaws, C.L.| isbn =978-0-8155-1596-8| url =https://books.google.com/books?id=31O4upzTHQwC| year =2008| publisher =William Andrew}}
4.40 g/cm3 (hexahydrate)

| MeltingPtC = 507 to 645

| MeltingPt_ref = {{Citation | editor-last= Turner, Jr. | editor-first=Francis M. | year =1920 | title =The Condensed Chemical Dictionary | location =New York | publisher =The Chemical Catalog Company | pages = 449 | url =https://books.google.com/books?id=y8y0XE0nsYEC&pg=PA449 |access-date = 2007-12-10}}

| BoilingPtC = 1773

| BoilingPt_notes = (decomposes)

| Solubility = 177.0 g/100 mL (20 °C)
177 g/100 mL (20 °C){{Citation | last =Seidell| first =Atherton | year =1907 | title =Solubilities of Inorganic and Organic Substances | location =New York | publisher =D. Van Nostrand | pages = 318| url =https://books.google.com/books?id=7Y8AAAAAMAAJ&pg=PA318 | access-date = 2007-12-10}}

| SolubleOther = 3.1 g/100 ml (4 °C)

| Solvent = ethanol

| LogP =

| VaporPressure =

| HenryConstant =

| AtmosphericOHRateConstant =

| pKa =

| pKb =

| MagSus = −112.0·10−6 cm3/mol}}

|Section3={{Chembox Structure

| CrystalStruct = Orthorhombic, oP24

| SpaceGroup = Pbca, No. 61

}}

|Section4={{Chembox Thermochemistry

| DeltaHf =

| DeltaHc =

| Entropy =

| HeatCapacity = }}

|Section5={{Chembox Pharmacology

| PregCat_US = }}

|Section7={{Chembox Hazards

| MainHazards = Corrosive

| NFPA-H = 1

| NFPA-F = 0

| NFPA-R = 0

| NFPA-S =

| GHS_ref = {{cite web |title=Strontium iodide |url=https://www.sigmaaldrich.com/AU/en/product/ALDRICH/400696 |publisher=Sigma Aldrich}}

| GHSPictograms = {{GHS05}}

| GHSSignalWord = Danger

| HPhrases = {{H-phrases|314}}

| PPhrases = {{P-phrases|280|305+351+338|310}}

| FlashPt =

| AutoignitionPt =

| ExploLimits =

| LD50 =

| PEL = }}

|Section8={{Chembox Related

| OtherAnions = strontium fluoride
strontium chloride
strontium bromide

| OtherCations = beryllium iodide
magnesium iodide
calcium iodide
barium iodide

| OtherFunction =

| OtherFunction_label =

| OtherCompounds =

}}

}}

Strontium iodide is an inorganic compound with the chemical formula {{chem2|SrI2|auto=1}}. It is a salt of strontium and iodine. It forms a hexahydrate {{chem2|SrI2*6H2O}}. It is an ionic, water-soluble, and deliquescent compound that can be used in medicine as a substitute for potassium iodide.{{Citation | last =Shoemaker | first =John V. | year =1908 | title =A Practical Treatise on Materia Medica and Therapeutics | edition =7th | location =Philadelphia | publisher =F. A. Davis | pages = 854 | url =https://books.google.com/books?id=E-1xq8ScRD8C&pg=RA1-PA854 | access-date = 2007-12-10}}

It is also used as a scintillation gamma radiation detector, typically doped with europium, due to its optical clarity, relatively high density, high effective atomic number (Z=48), and high scintillation light yield.{{cite journal|last1=Prettyman|first1=Thomas|last2=Burger|first2=Arnold|last3=Yamashita|first3=Naoyuki|last4=Lambert|first4=James|last5=Stassun|first5=Keivan|last6=Raymond|first6=Carol|title=Ultra-bright scintillators for planetary gamma-ray spectroscopy|journal=SPIE Newsroom|year=2015|issn=1818-2259|doi=10.1117/2.1201510.006162}} In recent years, europium-doped strontium iodide ({{chem2|SrI2}}:{{chem2|Eu(2+)}}) has emerged as a promising scintillation material for gamma-ray spectroscopy with extremely high light yield and proportional response, exceeding that of the widely used high performance commercial scintillator {{chem2|LaBr3}}:{{chem2|Ce(3+)}}. Large diameter {{chem2|SrI2}} crystals can be grown reliably using vertical Bridgman technique {{Cite book|last1=Datta|first1=A.|last2=Lam|first2=S.|last3=Swider|first3=S.|last4=Motakef|first4=S.|title=2016 IEEE Nuclear Science Symposium, Medical Imaging Conference and Room-Temperature Semiconductor Detector Workshop (NSS/MIC/RTSD) |chapter=Crystal growth of large diameter strontium iodide scintillators using in Situ stoichiometry monitoring |date=October 2016|pages=1–4|doi=10.1109/NSSMIC.2016.8116640|isbn=978-1-5090-1642-6|s2cid=31775311}} and are being commercialized by several companies.{{Cite web|url=http://www.capesym.com/sri2.html|title=CapeSym {{!}} SrI2(Eu)|last=Inc.|first=CapeSym|website=www.capesym.com|access-date=2018-02-13}}{{Cite web|url=http://rmdinc.com/strontium-iodide/|title=Strontium Iodide {{!}} RMD|website=rmdinc.com|language=en-US|access-date=2018-02-13|archive-date=2018-02-14|archive-url=https://web.archive.org/web/20180214051051/http://rmdinc.com/strontium-iodide/|url-status=dead}}

Reactions

Strontium iodide can be prepared by reacting strontium carbonate with hydroiodic acid:

:{{chem2|SrCO3 + 2 HI(aq) → SrI2 + H2O + CO2}}

Strontium iodide forms a white powder that slowly changes to a yellowish colour when exposed to air. At high temperatures (in the presence of air) strontium iodide completely decomposes to form strontium oxide and free iodine.

{{Citation|last =Bartley| first =Elias H.|year =1898|title =Text-book of Medical and Pharmaceutical Chemistry| edition =5th|location =Philadelphia|publisher =P. Blakiston|pages = 267–268| url =https://books.google.com/books?id=qdwUkA_aHWsC&pg=PA267|access-date = 2007-12-10}}

References