strontium iodide
{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 439308815
| ImageFile = Strontium-iodide-unit-cell-3D-balls.png
| ImageSize =
| IUPACName = Strontium iodide
| SystematicName =
| OtherNames =
|Section1={{Chembox Identifiers
| Abbreviations =
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 10476-86-5
| CASNo_Comment = (anhydrous)
| ChemSpiderID = 23637
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = F6V5HOR0O5
| EINECS = 233-972-1
| PubChem = 25304
| SMILES = I[Sr]I
| SMILES2 = [Sr+2].[I-].[I-]
| InChI = 1S/2HI.Sr/h2*1H;/q;;+2/p-2
| RTECS = WK9275000}}
|Section2={{Chembox Properties
| Formula = {{chem2|SrI2}} (anhydrous)
{{chem2|SrI2*6H2O}} (hexahydrate)
| Sr=1|I=2
| MolarMass_notes = (anhydrous)
| Appearance = Colorless to white crystalline plates
| Density = 4.55 g/cm3 (anhydrous){{Cite book| title =Thermophysical properties of chemicals and hydrocarbons| author =Yaws, C.L.| isbn =978-0-8155-1596-8| url =https://books.google.com/books?id=31O4upzTHQwC| year =2008| publisher =William Andrew}}
4.40 g/cm3 (hexahydrate)
| MeltingPtC = 507 to 645
| BoilingPtC = 1773
| BoilingPt_notes = (decomposes)
| Solubility = 177.0 g/100 mL (20 °C)
177 g/100 mL (20 °C){{Citation | last =Seidell| first =Atherton | year =1907 | title =Solubilities of Inorganic and Organic Substances | location =New York | publisher =D. Van Nostrand | pages = 318| url =https://books.google.com/books?id=7Y8AAAAAMAAJ&pg=PA318 | access-date = 2007-12-10}}
| SolubleOther = 3.1 g/100 ml (4 °C)
| Solvent = ethanol
| LogP =
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| HenryConstant =
| AtmosphericOHRateConstant =
| pKa =
| pKb =
| MagSus = −112.0·10−6 cm3/mol}}
|Section3={{Chembox Structure
| CrystalStruct = Orthorhombic, oP24
| SpaceGroup = Pbca, No. 61
}}
|Section4={{Chembox Thermochemistry
| DeltaHf =
| DeltaHc =
| Entropy =
| HeatCapacity = }}
|Section5={{Chembox Pharmacology
| PregCat_US = }}
|Section7={{Chembox Hazards
| MainHazards = Corrosive
| NFPA-H = 1
| NFPA-F = 0
| NFPA-R = 0
| NFPA-S =
| GHSPictograms = {{GHS05}}
| GHSSignalWord = Danger
| HPhrases = {{H-phrases|314}}
| PPhrases = {{P-phrases|280|305+351+338|310}}
| FlashPt =
| AutoignitionPt =
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| PEL = }}
|Section8={{Chembox Related
| OtherAnions = strontium fluoride
strontium chloride
strontium bromide
| OtherCations = beryllium iodide
magnesium iodide
calcium iodide
barium iodide
| OtherFunction =
| OtherFunction_label =
| OtherCompounds =
}}
}}
Strontium iodide is an inorganic compound with the chemical formula {{chem2|SrI2|auto=1}}. It is a salt of strontium and iodine. It forms a hexahydrate {{chem2|SrI2*6H2O}}. It is an ionic, water-soluble, and deliquescent compound that can be used in medicine as a substitute for potassium iodide.{{Citation | last =Shoemaker | first =John V. | year =1908 | title =A Practical Treatise on Materia Medica and Therapeutics | edition =7th | location =Philadelphia | publisher =F. A. Davis | pages = 854 | url =https://books.google.com/books?id=E-1xq8ScRD8C&pg=RA1-PA854 | access-date = 2007-12-10}}
It is also used as a scintillation gamma radiation detector, typically doped with europium, due to its optical clarity, relatively high density, high effective atomic number (Z=48), and high scintillation light yield.{{cite journal|last1=Prettyman|first1=Thomas|last2=Burger|first2=Arnold|last3=Yamashita|first3=Naoyuki|last4=Lambert|first4=James|last5=Stassun|first5=Keivan|last6=Raymond|first6=Carol|title=Ultra-bright scintillators for planetary gamma-ray spectroscopy|journal=SPIE Newsroom|year=2015|issn=1818-2259|doi=10.1117/2.1201510.006162}} In recent years, europium-doped strontium iodide ({{chem2|SrI2}}:{{chem2|Eu(2+)}}) has emerged as a promising scintillation material for gamma-ray spectroscopy with extremely high light yield and proportional response, exceeding that of the widely used high performance commercial scintillator {{chem2|LaBr3}}:{{chem2|Ce(3+)}}. Large diameter {{chem2|SrI2}} crystals can be grown reliably using vertical Bridgman technique {{Cite book|last1=Datta|first1=A.|last2=Lam|first2=S.|last3=Swider|first3=S.|last4=Motakef|first4=S.|title=2016 IEEE Nuclear Science Symposium, Medical Imaging Conference and Room-Temperature Semiconductor Detector Workshop (NSS/MIC/RTSD) |chapter=Crystal growth of large diameter strontium iodide scintillators using in Situ stoichiometry monitoring |date=October 2016|pages=1–4|doi=10.1109/NSSMIC.2016.8116640|isbn=978-1-5090-1642-6|s2cid=31775311}} and are being commercialized by several companies.{{Cite web|url=http://www.capesym.com/sri2.html|title=CapeSym {{!}} SrI2(Eu)|last=Inc.|first=CapeSym|website=www.capesym.com|access-date=2018-02-13}}{{Cite web|url=http://rmdinc.com/strontium-iodide/|title=Strontium Iodide {{!}} RMD|website=rmdinc.com|language=en-US|access-date=2018-02-13|archive-date=2018-02-14|archive-url=https://web.archive.org/web/20180214051051/http://rmdinc.com/strontium-iodide/|url-status=dead}}
Reactions
Strontium iodide can be prepared by reacting strontium carbonate with hydroiodic acid:
:{{chem2|SrCO3 + 2 HI(aq) → SrI2 + H2O + CO2}}
Strontium iodide forms a white powder that slowly changes to a yellowish colour when exposed to air. At high temperatures (in the presence of air) strontium iodide completely decomposes to form strontium oxide and free iodine.
{{Citation|last =Bartley| first =Elias H.|year =1898|title =Text-book of Medical and Pharmaceutical Chemistry| edition =5th|location =Philadelphia|publisher =P. Blakiston|pages = 267–268| url =https://books.google.com/books?id=qdwUkA_aHWsC&pg=PA267|access-date = 2007-12-10}}
References
{{Strontium compounds}}
{{Iodides}}