tin(II) iodide

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| Verifiedfields = changed

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| verifiedrevid = 439623407

| ImageFile =

{{chem2|Sn^{2+} (I^{-})2}}

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| IUPACName = tin(II) iodide

| OtherNames = stannous iodide

|Section1={{Chembox Identifiers

| CASNo_Ref = {{cascite|correct|CAS}}

| CASNo = 10294-70-9

| UNII_Ref = {{fdacite|correct|FDA}}

| UNII = OSH64454WG

| EINECS = 233-667-3

| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}

| ChemSpiderID = 23483

| PubChem = 9951390

| SMILES = [Sn](I)I

| InChI = 1/2HI.Sn/h2*1H;/q;;+2/p-2

| InChIKey = JTDNNCYXCFHBGG-NUQVWONBAK

| StdInChI_Ref = {{stdinchicite|changed|chemspider}}

| StdInChI = 1S/2HI.Sn/h2*1H;/q;;+2/p-2

| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}}

| StdInChIKey = JTDNNCYXCFHBGG-UHFFFAOYSA-L

}}

|Section2={{Chembox Properties

| I=2 | Sn=1

| MolarMass =

| Appearance = red to red-orange solid

| Density = 5.28 g/cm3

| MeltingPtC = 320

| BoilingPtC = 714

| Solubility = 0.98 g/100 g

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|Section3={{Chembox Hazards

| MainHazards =

| FlashPt =

| AutoignitionPt =

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|Section4={{Chembox Related

| OtherAnions = tin dichloride, tin(II) bromide

| OtherCations = lead(II) iodide

| OtherCompounds = tin tetraiodide

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Tin(II) iodide, also known as stannous iodide, is the inorganic compound with the formula SnI2. It is a red-orange solid. It reacts with iodine to give tin(IV) iodide.

Tin(II) iodide can be synthesised by heating metallic tin with a mixture iodine in 2 M hydrochloric acid.{{Greenwood&Earnshaw2nd|pages=380-381}}{{cite book |doi=10.1002/9781118744994.ch44 |chapter=Tin(II) Iodide |year=2014 |last1=Stolzenberg |first1=Alan M. |title=Inorganic Syntheses: Volume 36 |volume=36 |page=240|isbn=978-1-118-74487-1 }}

:Sn + I2 → SnI2

Structure

image:SnI2.png

It crystallizes in a unique motif. According to X-ray crystallography, some Sn(II) centers are bound to six iodide ligands others Sn(II) sites are distorted.{{cite journal |doi=10.1107/S0567740872007290 |title=The Crystal Structure of Tin(II) Iodide |date=1972 |last1=Howie |first1=R. A. |last2=Moser |first2=W. |last3=Trevena |first3=I. C. |journal=Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry |volume=28 |issue=10 |pages=2965–2971 |bibcode=1972AcCrB..28.2965H }}

References