titanium(II) bromide

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| ImageFile = Cadmium-iodide-3D-layers.png

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|Section1={{Chembox Identifiers

| CASNo = 13783-04-5

| PubChem = 11390146

| ChemSpiderID = 109721

| StdInChI=1S/2BrH.Ti/h2*1H;/q;;+2/p-2

| StdInChIKey = AUZMWGNTACEWDV-UHFFFAOYSA-L

| SMILES = [Ti+2].[Br-].[Br-]

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|Section2={{Chembox Properties

| Formula = TiBr₂

| MolarMass = 207.68

| Appearance = black solid

| Density = 4.41 g/cm³

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Titanium(II) bromide is the inorganic compound with the formula TiBr₂. It is a black micaceous solid. It adopts the cadmium iodide structure, featuring octahedral Ti(II) centers. It arises via the reaction of the elements:{{cite journal |doi=10.1002/zaac.19422490204|title=Zur Kenntnis der Dihalogenide des Titans und Vanadins|year=1942|last1=Klemm|first1=Wilhelm|last2=Grimm|first2=Ludwig|journal=Zeitschrift für Anorganische und Allgemeine Chemie|volume=249|issue=2|pages=198–208}}

:Ti + Br₂ → TiBr₂

The compound reacts with caesium bromide to give the linear chain compound CsTiBr₃.{{cite journal |doi=10.1524/zkri.1993.208.Part-2.370|title=Crystal structure of caesium titanium tribromide, CsTiBr3|year=1993|last1=Meyer|first1=G.|last2=Hinz|first2=D. J.|last3=Flörke|first3=U.|journal=Zeitschrift für Kristallographie - Crystalline Materials|volume=208|issue=2|pages=370|bibcode=1993ZK....208..370M|s2cid=93474968 }}