trifluoromethylisocyanide

{{chembox

| Verifiedfields = changed

| verifiedrevid = 470614562

| ImageFile = Trifluoromethyl isocyanide.svg

| ImageSize = 160

| ImageAlt = Skeletal formula

| ImageFile1 = Trifluoromethyl-isocyanide-3D-spacefill.png

| ImageSize1 = 150

| ImageAlt1 = Space-filling model

| IUPACName = trifluoro(isocyano)methane

| OtherNames = trifluoro-methyl-azaniumylidyne methane

|Section1={{Chembox Identifiers

| InChI = 1/C2F3N/c1-6-2(3,4)5

| InChIKey = LKHQVUSYAMWNQZ-UHFFFAOYAU

| StdInChI_Ref = {{stdinchicite|correct|chemspider}}

| StdInChI = 1S/C2F3N/c1-6-2(3,4)5

| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}

| StdInChIKey = LKHQVUSYAMWNQZ-UHFFFAOYSA-N

| CASNo_Ref = {{cascite|correct|CAS}}

| CASNo = 19480-01-4

| UNII_Ref = {{fdacite|correct|FDA}}

| UNII = R3NG676YU8

| PubChem = 145434

| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}

| ChemSpiderID = 128288

| SMILES = [C-]#[N+]C(F)(F)F

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|Section2={{Chembox Properties

| Formula = CF3NC

| MolarMass = 95.023

| Appearance =

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|Section3={{Chembox Hazards

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Trifluoromethylisocyanide is the chemical compound with the formula CF3NC. It is an isocyanide and a fluorocarbon. Polymerisation occurs even at temperatures below its boiling point of −80 °C. As a ligand in coordination chemistry, this species behaves similarly to carbon monoxide.{{cite journal| author=D. Lentz|title= Fluorinated Isocyanides - More than Ligands with Unusual Properties |journal= Angewandte Chemie International Edition in English|year= 1994|volume= 33| issue=13|pages= 1315–1331| doi=10.1002/anie.199413151}}

The compound trifluoracetonitrile (CF3CN) is an isomer to trifluoromethylisocyanide. The nitrile is more stable, as is the usual case.

References