zinnwaldite
{{Short description|Phyllosilicate mineral series in the mica group}}
{{Infobox mineral
| name = Zinnwaldite
| category = Phyllosilicate minerals, mica group
| boxwidth =
| boxbgcolor =
| image = Fluorapatite-Quartz-Topaz-gha5a.jpg
| imagesize = 260px
| caption = Fluorapatite with topaz on zinnwaldite and quartz
| formula = KLiFeAl(AlSi3)O10(OH,F)2
| molweight =
| system = Monoclinic
| class = Prismatic (2/m)
(same H-M symbol)
| symmetry = Cc (no. 9)
| unit cell = a = 5.29, b = 9.14
c = 10.09 [Å]; β = 100.83°
| color = Gray-brown, yellow-brown, pale violet, dark green, color zoning common
| habit = Well-formed short prismatic or tabular crystals, pseudohexagonal, in rosettes or fan-shaped groups; lamellar or scaly aggregates; disseminated.
| twinning = On composition plane {001}, twin axis [310]
| cleavage = Perfect basal {001}
| fracture = Uneven
| tenacity = Laminae °exible, elastic
| mohs = 3.5 - 4.0
| luster = Pearly to vitreous
| refractive = nα = 1.565 - 1.625 nβ = 1.605 - 1.675 nγ = 1.605 - 1.675
| opticalprop = Biaxial (-)
| birefringence = 0.040 - 0.050
| pleochroism = Distinct, X = colorless to yellow-brown; Y = gray-brown; Z = colorless to gray-brown
| 2V = 0 - 40°
| streak = White
| gravity = 2.9 - 3.1
| density =
| melt =
| fusibility =
| diagnostic =
| solubility =
| diaphaneity = Transparent to translucent
| references = [http://webmineral.com/data/Zinnwaldite.shtml Webmineral data]{{cite journal |last1=Rieder |first1=M. |last2=Hybler |first2=J. |last3=Smrcok |first3=L. |last4=Weiss |first4=Z. |journal=European Journal of Mineralogy |volume=8 |year=1996 |pages=1241–1248 |title=Refinement of the crystal structure of zinnwaldite 2M_1 |issue=6 |doi=10.1127/ejm/8/6/1241}}
}}
Zinnwaldite, KLiFeAl(AlSi3)O10(OH,F)2, potassium lithium iron aluminium silicate hydroxide fluoride, is a silicate mineral in the mica group. The IMA status is as a series between siderophyllite (KFe2Al(Al2Si2)O10(F,OH)2) and polylithionite (KLi2AlSi4O10(F,OH)2) and not considered a valid mineral species.
Name and discovery
It was first described in 1845 in Zinnwald/Cinvald (today Cínovec) on the German-Czech Republic border.[http://mindat.org/min-4419.html Mindat]
Occurrence
It occurs in greisens, pegmatite, and quartz veins often associated with tin ore deposits. It is commonly associated with topaz, cassiterite, wolframite, lepidolite, spodumene, beryl, tourmaline, and fluorite.[http://rruff.geo.arizona.edu/doclib/hom/zinnwaldite.pdf Handbook of Mineralogy]