zirsilite-(Ce)
{{Short description|Rare mineral of the eudialyte group}}
{{infobox mineral
| name = Zirsilite-(Ce)
| category = Cyclosilicate
| image = Zirsilite-(Ce)-830936.jpg
| imagesize =
| alt =
| caption =
| formula = {{chem2|(Na,□)12(Ce,Na)3Ca6Mn3Zr3Nb(Si25O73)(OH)3(CO3)*H2O}} (original form)
| strunz = 9.CO.10
| dana = 64.1.5
| system = Trigonal
| class = Ditrigonal pyramidal (3m)
H-M symbol: (3m)
| symmetry = R3m
| unit cell = a = 14.25, c = 30.08 [Å] (approximated); Z = 3
| color = Creamy white
| colour =
| habit = rhombohedra (rims of zoned crystals)
| twinning =
| cleavage = None
| fracture = Conchoidal
| tenacity = Brittle
| mohs = 5
| luster = Vitreous
| streak = White
| diaphaneity = Transparent
| gravity =
| density = 3.15 (measured)
| polish =
| opticalprop = Uniaxial (−)
| refractive = nω = 1.65, nε = 1.64 (approximated)
| birefringence =
| pleochroism = None
| 2V =
| dispersion =
| extinction =
| length fast/slow =
| fluorescence = No
| absorption =
| melt =
| fusibility =
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}}
Zirsilite-(Ce) is a very rare mineral of the eudialyte group, with formula {{chem2|(Na,□)12(Ce,Na)3Ca6Mn3Zr3NbSi(Si9O27)2(Si3O9)2O(OH)3(CO3)*H2O}}.Mindat, Zirsilite-(Ce), http://www.mindat.org/min-25674.htmlKhomyakov, A.P., Dusmatov, V.D., Ferraris, G., Gula, A., Ivaldi, G., and Nechelyustov, G.N., 2003: Zirsilite-(Ce), {{chem2|(Na,□)12(Ce,Na)3Ca6Mn3Zr3Nb(Si25O73)(OH)3(CO3)*H2O}}, and carbokentbrooksite {{chem2|(Na,□)12(Na,Ce)3Ca6Mn3Zr3Nb(Si25O73)(OH)3(CO3)*H2O}} – two new eudialyte-group minerals from the Dara-i-Pioz alkaline massif, Tajikistan. Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva 132(5), 40–51 (in Russian, with English abstract); in: Jambor, J.I, and Roberts, A.C., 2004: New mineral names. American Mineralogist 89(11–12), 1826–1834 The original formula was extended to show the presence of cyclic silicate groups and the presence of silicon at the M4 site, according to the nomenclature of the eudialyte group.Johnsen, O., Ferraris, G., Gault, R.A., Grice, D.G., Kampf, A.R., and Pekov, I.V., 2003. The nomenclature of eudialyte-group minerals. The Canadian Mineralogist 41, 785–794 Zirsilite-(Ce) differs from carbokentbrooksite in cerium-dominance over sodium only. Both minerals are intimately associated. The only other currently known representative of the eudialyte group having rare earth elements (in particular cerium, as suggested by the "-Ce)" Levinson suffix in the nameHatert, F., Mills, S.J., Pasero, M., and Williams, P.A., 2013. CNMNC guidelines for the use of suffixes and prefixes in mineral nomenclature, and for the preservation of historical names. European Journal of Mineralogy 25, 113–115) in dominance is johnsenite-(Ce).
Occurrence and association
Zirsilite-(Ce) and carbokentbrooksite occur in pegmatites of Darai-Pioz alkaline massif, Tajikistan – a locality known for many rare minerals.{{cite web |url=http://www.mindat.org/loc-3241.html |title=Darai-Pioz Glacier (Dara-i-Pioz; Dara-Pioz), Alai Range (Alayskiy), Tien Shan Mtn, Region of Republican Subordination, Tajikistan - Mindat.org |website=Mindat.org |access-date=2016-03-11}} They are found as replacements of grains and crystals of eudialyte. The minerals are associated with aegirine, ekanite, microcline, polylithionite, quartz, stillwellite-(Ce) (silicates), pyrochlore-group mineral, fluorite, calcite, and galena.