:Cadmium nitrate

{{chembox

| Verifiedfields = changed

| Watchedfields = changed

| verifiedrevid = 413213491

| ImageFile = cadmium nitrate.png

| ImageSize = 160px

| ImageName = Skeletal formula of cadmium chloride

| ImageFile1 = Dusičnan kademnatý.JPG

| ImageSize1 = 200px

| ImageName1 = Crystal of cadmium chloride

| IUPACName = Cadmium(II) nitrate

| OtherNames = Nitric acid, cadmium salt

|Section1={{Chembox Identifiers

| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}

| ChemSpiderID = 23498

| ChEBI_Ref = {{ebicite|changed|EBI}}

| ChEBI = 77732

| InChI = 1/Cd.2NO3/c;2*2-1(3)4/q+2;2*-1

| SMILES = [Cd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O

| InChIKey = XIEPJMXMMWZAAV-UHFFFAOYAP

| StdInChI_Ref = {{stdinchicite|correct|chemspider}}

| StdInChI = 1S/Cd.2NO3/c;2*2-1(3)4/q+2;2*-1

| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}

| StdInChIKey = XIEPJMXMMWZAAV-UHFFFAOYSA-N

| CASNo = 10325-94-7

| CASNo_Ref = {{cascite|correct|CAS}}

| CASNo1_Ref = {{cascite|correct|CAS}}

| CASNo1 = 10022-68-1

| CASNo1_Comment = (tetrahydrate)

| PubChem = 25154

| PubChem_Comment = (anhydrous)

| PubChem1 = 56924536

| PubChem1_Comment = (tetrahydrate)

| UNNumber = 3087, 2570

| UNII_Ref = {{fdacite|correct|FDA}}

| UNII = VF9RQV8VXV

| UNII1_Ref = {{fdacite|correct|FDA}}

| UNII1 = 4VEL5V5LC0

| UNII1_Comment = (tetrahydrate)

| EINECS = 233-710-6

}}

|Section2={{Chembox Properties

| Formula = Cd(NO3)2

| MolarMass = 236.42 g/mol (anhydrous)
308.48 g/mol (tetrahydrate)

| Appearance = White crystals, hygroscopic

| Odor = Odorless

| Density = 3.6 g/cm3 (anhydrous)
2.45 g/cm3 (tetrahdyrate)

| Solubility = 109.7 g/100 mL (0 °C)
126.6 g/100 mL (18 °C)
139.8 g/100 mL (30 °C)
320.9 g/100 mL (59.5 °C){{cite book|last1 = Seidell|first1 = Atherton|last2 = Linke|first2 = William F.|year = 1919|title = Solubilities of Inorganic and Organic Compounds|publisher = D. Van Nostrand Company|place = New York|edition = 2nd|page = 178}}

| SolubleOther = Soluble in acids, ammonia, alcohols, ether, acetone
5 g/L in methanol

| MeltingPtC = 360

| MeltingPt_notes =
at 760 mmHg (anhydrous)
{{convert|59.5|C|F K}}
at 760 mmHg (tetrahydrate){{CRC90}}

| BoilingPtC = 132

| BoilingPt_notes =
at 760 mmHg (tetrahydrate){{cite web|url = https://www.fishersci.ca/viewmsds.do?catNo=C13100|title = MSDS of Cadmium nitrate tetrahydrate|website = www.fishersci.ca|accessdate = 2014-06-25|publisher = Fisher Scientific}}

| MagSus = −5.51·10−5 cm3/mol (anhydrous)
−1.4·10−4 cm3/mol (tetrahydrate)

}}

|Section3={{Chembox Structure

| CrystalStruct = Cubic (anhydrous)
Orthorhombic (tetrahydrate)

| SpaceGroup = Fdd2, No. 43 (tetrahydrate){{Cite journal |doi= 10.1071/CH9781189 |title=Raman spectrum of cadmium nitrate |journal= Australian Journal of Chemistry |volume= 31 |issue = 6 |pages = 1189 |year = 1978 |last1 = James | first1 = D. W. | last2 = Carrick | first2 = M. T. | last3 = Leong | first3 = W. H. }}

| PointGroup = mm2 (tetrahydrate)

| LattConst_alpha = 90

| LattConst_beta = 90

| LattConst_gamma = 90

}}

|Section7={{Chembox Hazards

| GHSPictograms = {{GHS06}}{{GHS08}}{{GHS09}}{{Sigma-Aldrich|id=229520|name=Cadmium nitrate tetrahydrate|accessdate=2014-06-25}}

| GHSSignalWord = Danger

| HPhrases = {{H-phrases|301|330|340|350|360|372|410}}

| PPhrases = {{P-phrases|201|260|273|284|301+310|310}}

| NFPA-H = 4

| NFPA-F = 0

| NFPA-R = 0

| NFPA-S = OX

| NFPA_ref = {{Sigma-Aldrich|id=229520|name=Cadmium nitrate tetrahydrate|accessdate=2014-06-25}}

| LD50 = 300 mg/kg (rats, oral)

| REL = Ca{{PGCH|0087}}

| PEL = [1910.1027] TWA 0.005 mg/m3 (as Cd)

| IDLH = Ca [9 mg/m3 (as Cd)]

}}

|Section8={{Chembox Related

| OtherAnions = Cadmium acetate
Cadmium chloride
Cadmium sulfate

| OtherCations = Zinc nitrate
Calcium nitrate
Magnesium nitrate

}}

}}

Cadmium nitrate describes any of the related members of a family of inorganic compounds with the general formula {{chem2|Cd(NO3)2*xH2O}}. The most commonly encountered form being the tetrahydrate.The anhydrous form is volatile, but the others are colourless crystalline solids that are deliquescent, tending to absorb enough moisture from the air to form an aqueous solution. Like other cadmium compounds, cadmium nitrate is known to be carcinogenic. According to X-ray crystallography, the tetrahydrate features octahedral Cd2+ centers bound to six oxygen ligands.{{cite journal |doi=10.1107/S0365110X66003773 |title=Refinement of the Structure of Cd(NO3)2.4H2O |date=1966 |last1=Matković |first1=B. |last2=Ribar |first2=B. |last3=Zelenko |first3=B. |last4=Peterson |first4=S. W. |journal=Acta Crystallographica |volume=21 |issue=5 |pages=719–725 |bibcode=1966AcCry..21..719M }}

Uses

Cadmium nitrate is used for coloring glass and porcelainKarl-Heinz Schulte-Schrepping, Magnus Piscator "Cadmium and Cadmium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2007 Wiley-VCH, Weinheim. {{doi|10.1002/14356007.a04_499}}. and as a flash powder in photography.

Preparation

Cadmium nitrate is prepared by dissolving cadmium metal or its oxide, hydroxide, or carbonate, in nitric acid followed by crystallization:

:{{chem2|CdO + 2HNO3 -> Cd(NO3)2 + H2O}}

:{{chem2|CdCO3 + 2 HNO3 -> Cd(NO3)2 + CO2 + H2O}}

: {{chem2|Cd + 4HNO3 -> 2NO2 + 2 H2O + Cd(NO3)2}}

Reactions

Thermal dissociation at elevated temperatures produces cadmium oxide and oxides of nitrogen. When hydrogen sulfide is passed through an acidified solution of cadmium nitrate, yellow cadmium sulfide is formed. A red modification of the sulfide is formed under boiling conditions.

When treated with sodium hydroxide, solutions of cadmium nitrate yield a solid precipitate of cadmium hydroxide. Many insoluble cadmium salts are obtained by such precipitation reactions.

References

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