:Indium arsenide
{{chembox
| Watchedfields = changed
| verifiedrevid = 477313298
| ImageFile =Sphalerite-unit-cell-3D-balls.png
| ImageSize =
| ImageFile1 = Indium arsenide.jpg
| IUPACName = Indium(III) arsenide
| OtherNames = Indium monoarsenide
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 82621
| InChI = 1/As.In/rAsIn/c1-2
| SMILES1 = [In+3].[As-3]
| SMILES2 = [In]#[As]
| InChIKey = RPQDHPTXJYYUPQ-FVESRWMKAB
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/As.In
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = RPQDHPTXJYYUPQ-UHFFFAOYSA-N
| CASNo = 1303-11-3
| CASNo_Ref = {{cascite|correct|CAS}}
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = J1A23S0911
| PubChem = 91500
}}
|Section2={{Chembox Properties
| Formula = InAs
| MolarMass = 189.740 g/mol
| Density = 5.67 g/cm3Haynes, p. 4.66
| Solvent =
| SolubleOther =
| MeltingPtC = 942
| BoilingPt =
| BandGap = 0.354 eV (300 K)
| ElectronMobility = 40000 cm2/(V*s)
| SpecRotation =
| MagSus =
| ThermalConductivity = 0.27 W/(cm*K) (300 K)
| RefractIndex = 4Haynes, pp. 12.157
}}
|Section3={{Chembox Structure
| MolShape =
| CrystalStruct = Zinc blende
| Dipole =
| LattConst_a = 6.0583 Å
}}
|Section4={{Chembox Thermochemistry
| Thermochemistry_ref = Haynes, p. 5.22
| DeltaHf = −58.6 kJ·mol−1
| DeltaGf = −53.6 kJ·mol−1
| Entropy = 75.7 J·mol−1·K−1
| HeatCapacity = 47.8 J·mol−1·K−1
}}
|Section7={{Chembox Hazards
| ExternalSDS = [https://www.americanelements.com/indium-arsenide-1303-11-3/sds External SDS]
| GHSPictograms = {{GHS06}}{{GHS08}}{{cite web|title = Indium Arsenide|url = https://www.americanelements.com/indium-arsenide-1303-11-3|publisher = American Elements|access-date = October 12, 2018}}
| HPhrases = {{H-phrases|301|331}}
| PPhrases = {{P-phrases|261|301+310|304+340|311|405|501}}
| NFPA-H = 4
| NFPA-R = 0
| NFPA-F = 0
}}
|Section8={{Chembox Related
| OtherAnions = Indium nitride
Indium phosphide
Indium antimonide
| OtherCations = Gallium arsenide
| OtherFunction =
| OtherFunction_label =
| OtherCompounds =
}}
}}
Indium arsenide, InAs, or indium monoarsenide, is a narrow-bandgap semiconductor composed of indium and arsenic. It has the appearance of grey cubic crystals with a melting point of 942 °C. {{cite web | url = http://www.ioffe.rssi.ru/SVA/NSM/Semicond/InAs/thermal.html | title = Thermal properties of Indium Arsenide (InAs) | access-date = 2011-11-22}}
Indium arsenide is similar in properties to gallium arsenide and is a direct bandgap material, with a bandgap of 0.35 eV at room temperature.
Indium arsenide is used for the construction of infrared detectors, for the wavelength range of 1.0–3.8 μm. The detectors are usually photovoltaic photodiodes. Cryogenically cooled detectors have lower noise, but InAs detectors can be used in higher-power applications at room temperature as well. Indium arsenide is also used for making diode lasers.
InAs is well known for its high electron mobility and narrow energy bandgap. It is widely used as a terahertz radiation source as it is a strong photo-Dember emitter.
Quantum dots can be formed in a monolayer of indium arsenide on indium phosphide or gallium arsenide. The mismatches of lattice constants of the materials create tensions in the surface layer, which in turn leads to the formation of the quantum dots. {{cite web | url = http://oemagazine.com/fromTheMagazine/feb02/eyeontech.html | title = oe magazine - eye on technology | access-date = 2011-11-22 | archive-url = https://web.archive.org/web/20061018061927/http://oemagazine.com/fromTheMagazine/feb02/eyeontech.html | archive-date = 2006-10-18}} Quantum dots can also be formed in indium gallium arsenide, as indium arsenide dots sitting in the gallium arsenide matrix.
References
{{reflist}}
Cited sources
- {{cite book |ref=Haynes| editor= Haynes, William M. | date = 2016| title = CRC Handbook of Chemistry and Physics | edition = 97th | publisher = CRC Press | isbn = 9781498754293}}
External links
- [http://www.ioffe.rssi.ru/SVA/NSM/Semicond/InAs/index.html Ioffe institute data archive entry]
- [https://web.archive.org/web/20070107054525/http://www.onr.navy.mil/sci_tech/31/312/ncsr/materials/inas.asp National Compound Semiconductor Roadmap] entry for InAs at ONR web site
{{Indium compounds}}
{{Arsenic compounds}}
{{Arsenides}}
{{Semiconductor laser}}