1-Chlorohexane
{{Chembox
| Name = 1-Chlorohexane
| ImageFile = 1-clorohexano-3D.gif
| ImageCaption =
| IUPACName =
| OtherNames = 1-Hexyl chloride
| Section1 = {{Chembox Identifiers
| CASNo = 544-10-5
| CASNo_Ref = {{Cascite|correct|CAS}}
| PubChem = 10992
| ChemSpiderID = 10526
| EINECS = 208-859-5
| UNII = R5L7I6O9NW
| UNNumber = 1993
| ChEMBL = 156095
| DTXSID = DTXSID1060265
| StdInChI = 1S/C6H13Cl/c1-2-3-4-5-6-7/h2-6H2,1H3
| StdInChIKey = MLRVZFYXUZQSRU-UHFFFAOYSA-N
| SMILES = CCCCCCCl
}}
| Section2 = {{Chembox Properties
|C=6| H=13 | Cl=1
| Appearance = Liquid
| Density = 0.88 g/cm3
| Solubility = sparingly soluble
| MeltingPtC = −94.0
| BoilingPtC = 135
}}
| Section4 = {{Chembox Structure
| CrystalStruct =
}}
| Section7 = {{Chembox Hazards
| MainHazards =
| GHSPictograms = {{GHS02}}
| GHSSignalWord = Warning
| HPhrases = {{H-phrases|226|412}}
| PPhrases = {{P-phrases|210|233|240|241|242|243|273|280|303+361+353|370+378|403+235|501}}
}}
| Section6 = {{Chembox Related
| OtherCompounds =
}}
}}
1-Chlorohexane is a chemical compound from the group of aliphatic saturated halogenated hydrocarbons. The chemical formula is {{chem2|CH3(CH2)5Cl}}.{{cite web |title=1-Chlorohexane |url=https://www.sigmaaldrich.com/RU/en/product/aldrich/238465 |publisher=Sigma Aldrich |access-date=7 August 2024}}{{cite web |title=Hexane, 1-chloro- |url=https://webbook.nist.gov/cgi/cbook.cgi?ID=C544105&Units=SI&Mask=200 |publisher=NIST |access-date=7 August 2024}}
Synthesis
1-Chlorohexane can be obtained by reacting hexyl alcohol with hydrochloric acid or thionyl chloride.
Physical properties
1-Chlorohexane is a colorless liquid with an aromatic odor that is very sparingly soluble in water.{{cite book |last1=Lide |first1=David R. |title=CRC Handbook of Chemistry and Physics/Special Student Edition 1993-1994 |date=1993 |publisher=CRC Press |isbn=978-0849305955 |page=3-112 |url=https://books.google.com/books?id=q2qJId5TKOkC&pg=RA3-PA112 |access-date=7 August 2024}}
Chemical properties
1-Fluorohexane can be prepared by reacting 1-chlorohexane with potassium fluoride in ethylene glycol.
2-Phenylhexane can be prepared by reacting the compound with benzene and aluminum trichloride.{{cite book |last1=Fox |first1=Scott |title=Organic Chemistry |date=2004 |publisher=Jones and Bartlett Publishers |isbn=978-0763721978 |page=530 |url=https://books.google.com/books?id=xx_uIP5LgO8C&pg=PA530 |access-date=7 August 2024}}