Beryllium oxalate
{{Chembox
| ImageFile = Beryllium oxalate.svg
| ImageSize = 200px
| ImageAlt =
| PIN =
| OtherNames =
|Section1={{Chembox Identifiers
| CASNo = 3173-18-0
| CASNo_Ref = {{cascite|correct|CAS}}
| UNII_Ref = {{fdacite|changed|FDA}}
| UNII =
| EINECS =
| PubChem = 6451522
| ChemSpiderID = 4953986
| SMILES = [Be+2].C(=O)(C(=O)[O-])[O-]
| InChI = 1S/C2H2O4.Be/c3-1(4)2(5)6;/h(H,3,4)(H,5,6);/q;+2/p-2
| InChIKey = XQZGLPVUHKSNBQ-UHFFFAOYSA-L
}}
|Section2={{Chembox Properties
| Formula = {{chem|C|2|Be|O|4}}
| MolarMass = 97.03{{cite web |title=BERYLLIUM OXALATE |url=https://www.chemicalbook.com/ChemicalProductProperty_EN_CB2393953.htm |publisher=chemicalbook.com |access-date=15 June 2021}}
| Appearance = Transparent crystals
| Density =
| MeltingPtC =
| BoilingPtC = 365.1
| Solubility = Soluble}}
|Section3={{Chembox Hazards
| MainHazards =
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| FlashPtC = 188.8{{cite web |title=beryllium,oxalate |url=https://www.chemsrc.com/en/cas/3173-18-0_429704.html |publisher=chemsrc.com |access-date=15 June 2021 |language=en}}
| AutoignitionPt = }}
|Section6={{Chembox Related
| OtherCompounds = Calcium oxalate
Sodium oxalate
Magnesium oxalate
Strontium oxalate
Barium oxalate
Iron(II) oxalate
Iron(III) oxalate
Lithium oxalate
Praseodymium oxalate
}}
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Beryllium oxalate is an inorganic compound, a salt of beryllium metal and oxalic acid with the chemical formula {{chem|C|2|Be|O|4}}.{{cite book |last1=Novoselova |first1=Aleksandra Vasilʹevna |last2=Bat︠s︡anova |first2=Li︠u︡dmila Rafailovna |title=Analytical Chemistry of Beryllium |date=1969 |publisher=Ann Arbor-Humphrey Science Publishers |page=25 |url=https://books.google.com/books?id=2mBNAAAAMAAJ&q=beryllium+oxalate |access-date=15 June 2021 |language=en}} It forms colorless crystals, dissolves in water, and also forms crystalline hydrates. The compound is used to prepare ultra-pure beryllium oxide{{cite journal |last1=Dollimore |first1=David |last2=Konieczay |first2=Julie L. |title=The thermal decomposition of beryllium oxalate and related materials |url=https://www.sciencedirect.com/science/article/abs/pii/S0040603198003402 |journal=Thermochimica Acta |access-date=15 June 2021 |pages=155–163 |language=en |doi=10.1016/S0040-6031(98)00340-2 |date=1998-09-07|volume=318 |issue=1–2 |url-access=subscription }} by thermal decomposition.{{cite book |last1=Walsh |first1=Kenneth A. |title=Beryllium Chemistry and Processing |date=2009-01-01 |publisher=ASM International |isbn=978-0-87170-721-5 |page=125 |url=https://books.google.com/books?id=3-GbhmSfyeYC&dq=beryllium+oxalate&pg=PA125 |access-date=15 June 2021 |language=en}}
Synthesis
The action of oxalic acid on beryllium hydroxide:{{cite book |last1=Moore |first1=Raymond E. |title=Purification of Beryllium Compounds: A Literature Survey |date=1960 |publisher=Oak Ridge National Laboratory |page=6 |url=https://books.google.com/books?id=kR34mCmtPw0C&q=beryllium+oxalate |access-date=15 June 2021 |language=en}}
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Chemical properties
Crystalline hydrates lose water when heated:
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References
{{Reflist}}
{{Beryllium compounds}}
{{Oxalates}}