Ethanol (data page)

{{Short description|Chemical data page for ethanol}}

{{Use dmy dates|date=March 2024}}

This page provides supplementary chemical data on ethanol.

== Material Safety Data Sheet ==

[http://www.distill.com/materialsafety/msds-eu.html External MSDS]

File:Ethanol-structure.svg

== Structure and properties ==

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! {{chembox header}} | Structure and properties

Index of refraction, n25

| 1.361

Dielectric constant, εr

| 24.3 ε0 at 20 °C

Bond strength

| ?

Bond length

| ?

Bond angle

| ?

Magnetic susceptibility[http://nmr.chem.umn.edu/ResReports/NMR002.html NMR-002: Sample Devices and Magnetic Susceptibility]

| {{val|5.8e−7}} (cgs units, volume)

Surface tension

| 22.39 dyn/cm at 25 °C

Thermal conductivityTouloukian, Y.S., Liley, P.E., and Saxena, S.C. Thermophysical properties of matter – the TPRC data series. Volume 3. Thermal conductivity – nonmetallic liquids and gases. Data book. 1970.

|0.1660 W m−1 K−1 (saturated liquid at 300 K)

Viscosity{{Cite web|url=http://www.cheric.org/research/kdb/hcprop/cmpsrch.php|title=Pure Component Properties|format=Queriable database|publisher=Chemical Engineering Research Information Center|access-date=12 May 2007}}

|

{|

6.285 mPa·sat −50 °C
4.656 mPa·sat −40 °C
3.530 mPa·sat −30 °C
2.731 mPa·sat −20 °C
2.419 mPa·sat −15 °C
2.151 mPa·sat −10 °C
1.920 mPa·sat −5 °C
1.720 mPa·sat 0 °C
1.546 mPa·sat 5 °C
1.394 mPa·sat 10 °C
1.261 mPa·sat 15 °C
1.144 mPa·sat 20 °C
1.040 mPa·sat 25 °C
0.948 mPa·sat 30 °C
0.794 mPa·sat 40 °C
0.670 mPa·sat 50 °C
0.570 mPa·sat 60 °C
0.487 mPa·sat 70 °C
0.452 mPa·sat 75 °C

|}

== Thermodynamic properties ==

border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"

! {{chembox header}} | Phase behavior

Triple point

| 150 K (−123 °C), 0.00043 Pa

Critical point

| 514 K (241 °C), 63 bar

Std enthalpy change
of fusion
, ΔfusHo

| +4.9 kJ/mol

Std entropy change
of fusion
, ΔfusSo

| +31 J/(mol·K)

Std enthalpy change
of vaporization
, ΔvapHo

| {{val|+42.3|0.4}} kJ/mol{{Cite web|title=Ethanol|url=https://webbook.nist.gov/cgi/cbook.cgi?ID=C64175&Mask=7|access-date=2021-12-07|website=webbook.nist.gov|language=en}}

Std entropy change
of vaporization
, ΔvapSo

| 109.67 J/(mol·K)

Molal freezing point constant

| −1.99 °C kg/mol

{{chembox header}} | Solid properties
Std enthalpy change
of formation
, ΔfHosolid

| −277.7 kJ/mol

Standard molar entropy,
Sosolid

| 160.7 J/(mol K){{cite book|last1=Atkins|first1=Peter |last2=de Paula|first2=Julio |title=Atkins' Physical Chemistry|url=https://books.google.com/books?id=BV6cAQAAQBAJ&pg=PA913|edition=9th|year=2010|publisher=OUP |location=Oxford|isbn=978-0-19-954337-3|pages=913–947}}

Heat capacity, cp

| 111.46 J/(mol K)

{{chembox header}} | Liquid properties
Std enthalpy change
of formation
, ΔfHoliquid

| −277.38 kJ/mol

Standard molar entropy,
Soliquid

| 159.9 J/(mol K)

Enthalpy of combustion, ΔcHo

| −1370.7 kJ/mol

Heat capacity, cp

| 112.4 J/(mol K)

{{chembox header}} | Gas properties
Std enthalpy change
of formation
, ΔfHogas

| −235.3 kJ/mol

Standard molar entropy,
Sogas

| 283 J/(mol K)

Heat capacity,{{sfn|Lange|1967|pp= 1525–1528}}{{cite book|last1=Hodgman|first1=Charles D|last2=Weast|first2=Robert C|last3=Shankland|first3=Robert S|first4=Samuel M |last4=Selby|title=CRC Handbook of chemistry and physics : a ready-reference book of chemical and physical data|edition=44th|year=1963|publisher=The Chemical Rubber Publishing|location=Cleveland Ohio|pages=2582–2584}} cp

| 78.28 J/(mol K) at 90 °C
87.53 J/(mol K) at 110-220 °C

Heat capacity ratio,{{sfn|Lange|1967|pp= 1525–1528}}
γ = cp/cv

| 1.13 at 90 °C

van der Waals' constants{{sfn|Lange|1967|pp= 1522–1524}}

| a = 1217.9 L2 kPa/mol2
b = 0.08407 L/mol

== Spectral data ==

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! {{chembox header}} | UV-Vis

λmax

| ? nm

Extinction coefficient, ε

| ?

{{chembox header}} | IR
Major absorption bands{{Cite web|url=http://riodb01.ibase.aist.go.jp/sdbs/cgi-bin/cre_index.cgi?lang=eng|title=Spectral Database for Organic Compounds|publisher=Advanced Industrial Science and Technology|format=Queriable database|access-date=9 June 2007}}

|

{|

colspan ="2" align="center" | (liquid film)
Wave numbertransmittance
880 cm−122%
1048 cm−16%
1089 cm−119%
1275 cm−152%
1329 cm−144%
1384 cm−132%
1418 cm−133%
1650 cm−126%
1926 cm−162%
2899 cm−112%
2930 cm−113%
2977 cm−14%

|-

! {{chembox header}} | NMR

|-

| Proton NMR

|  

|-

| Carbon-13 NMR

| http://riodb01.ibase.aist.go.jp/sdbs/cgi-bin/IMG.cgi?fname=CDS00245&imgdir=cdsW;

|-

| Other NMR data

|  

|-

! {{chembox header}} | MS

|-

| Masses of
main fragments

|  

|-

|}

Vapor pressure of liquid

class="wikitable" style="text-align: center"
P in mm Hg

| 1 || 10 || 40 || 100 || 400 || 760 || 1,520 || 3,800 || 7,600 || 15,200 || 30,400 || 45,600

P in Pa

| 133.3 || 1,333 || 5,333 || 13,332 || 53,329 || 101,325 || 202,650 || 506,625 || 1,013,250 || 2,026,500 || 4,053,000 || 6,079,501

T in °C

| −31.3 || −2.3 || 19.0 || 34.9 || 63.5 || 78.4 || 97.5 || 126.0 || 151.8 || 183.0 || 218.0 || 242.0

T in K

| 241.85 || 270.85 || 292.15 || 308.05 || 336.65 || 351.55 || 370.65 || 399.15 || 424.95 || 456.15 || 491.15 || 515.15

Image:EtOHvaporpressureL.png vs. temperature. Uses formula P_\text{mm Hg} = 10^{8.04494 - \frac{1554.3}{222.65 + T}} {{sfn|Lange|1967|pp= }}]]

|

Image:EtOHlogVaporPressureL.png

{{Clear}}

Density of ethanol at various temperatures

Data obtained from {{harvnb|Lange|1967|pp=}}

class="wikitable"

! T °C !! ρ, g/cm3 !! T °C !! ρ, g/cm3 !! T °C !! ρ, g/cm3

30.80374160.79283290.78182
40.80290170.79198300.78097
50.80207180.79114310.78012
60.80123190.79029320.77927
70.80039200.78945330.77841
80.79956210.78860340.77756
90.79872220.78775350.77671
100.79788230.78691360.77585
110.79704240.78606370.77500
120.79620250.78522380.77414
390.77329400.77244

These data correlate as ρ [g/cm3] = −8.461834{{e|-4}} T [°C] + 0.8063372 with an R2 = 0.99999.

Properties of aqueous ethanol solutions

Data obtained from {{harvnb|Lange|1967|pp=}}

class="wikitable"

!rowspan=2| Mass fraction,
%

!rowspan=2| Volume concentration,
%

!rowspan=2| Mass concentration, g/(100 ml) at 15.56 °C

!colspan=4| Density relative to 4 °C water {{Citation needed|reason='Not included in Lange 1967'|date=June 2023}}

!rowspan=2| Density at 20 °C relative to 20 °C water

!rowspan=2| Density at 25 °C relative to 25 °C water

!rowspan=2| Freezing temperature,
°C

10 °C || 20 °C || 25 °C || 30 °C
0.00.00.00.999730.998230.997080.995681.000001.000000
1.00.997850.996360.995200.993790.998130.99811
2.00.996020.994530.993360.991940.996290.99627
2.53.130.99363−1
3.00.994260.992750.991570.990140.994510.99447
4.05.003.970.992580.991030.989840.988390.992790.99274
4.86.004.760.98971−2
5.00.990980.989380.988170.986700.991130.99106
5.056.305.000.98930
6.00.989460.987800.986560.985070.989550.98945
6.88.470.98658−3
7.00.988010.986270.985000.983470.988020.98788
8.00.986600.984780.983460.981890.986530.98634
9.00.985240.983310.981930.980310.985050.98481
10.012.409.840.983930.981870.980430.978750.983610.98330
11.00.982670.980470.978970.977230.982210.98184
11.314.011.110.98006−5
12.015.00.981450.979100.977530.975730.980840.98039
13.00.980260.977750.976110.974240.979480.97897
13.7817.0013.49−6.1
14.00.979110.976430.974720.972780.978160.97757
15.00.978000.975140.973340.971330.976870.97619
15.0218.5014.680.97511
16.00.976920.973870.971990.969900.975600.97484
16.420.20.97336−7.5
17.00.975830.972590.970620.968440.974310.97346
17.521.50.97194−8.7
18.022.1017.540.974730.971290.969230.966970.973010.97207
18.823.10.97024−9.4
19.00.973630.969970.967820.965470.971690.97065
20.00.972520.968640.966390.963950.970360.96922
20.0124.5019.440.96863
20.324.80.96823−10.6
21.00.971390.967290.964950.962420.969010.96778
22.00.970240.965920.963480.960870.967630.96630
22.1127.0021.430.96578−12.2
23.00.969070.964530.961990.959290.966240.96481
24.00.967870.963120.960480.957690.964830.96329
24.229.50.96283−14.0
25.030.4024.120.966650.961680.958950.956070.963390.96176
26.00.965390.960200.957380.954220.961900.96018
26.732.40.95914−16.0
27.00.964060.958670.955760.952720.960370.95856
28.033.9026.900.962680.957100.954100.950980.958800.95689
29.00.961250.955480.952410.949220.957170.95520
29.936.10.95400−18.9
30.036.2028.730.959770.953820.950670.947410.955510.95345
31.00.958230.952120.948900.945570.953810.95168
32.00.956650.950380.947090.943700.952070.94986
33.00.955020.948600.945250.941800.950280.94802
33.840.50.94715−23.6
34.00.953340.946790.943370.939860.948470.94613
35.00.951620.944940.941460.937900.946620.94422
35.0441.9033.250.94486
36.00.949860.943060.939520.935910.944730.94227
37.00.948050.941140.937560.933900.942810.94031
38.00.946200.939190.935560.931860.940860.93830
39.046.30.944310.937200.933530.929790.938860.93626−28.7
40.00.942380.935180.931480.927700.936840.93421
40.0447.4037.610.93510
41.00.940420.933140.929400.925580.934790.93212
42.00.938420.931070.927290.923440.932720.93001
43.00.936390.928970.925160.921280.930620.92787
44.00.934330.926850.923010.919100.928490.92571
45.00.932260.924720.920850.916920.926360.92355
45.3153.0042.070.92406
46.00.930170.922570.918680.914720.924210.92137
46.353.80.92193−33.9
47.00.928060.920410.916490.912500.922040.91917
48.00.925930.918230.914290.910280.919860.91697
49.00.923790.916040.912080.908050.917660.91475
50.00.921620.913840.909850.905800.915460.91251
50.1658.046.040.91349
51.00.919430.911600.907600.903530.913220.91026
52.00.917230.909360.905240.901250.910970.90799
53.00.915020.907110.903070.898960.908720.90571
54.00.912790.904850.900790.896670.906450.90343
55.00.910550.902580.898500.894370.904180.90113
55.1663.050.000.90220
56.00.908310.900310.896210.892060.901910.89833
56.163.60.90008−41.0
57.00.906070.898030.893920.889750.899620.89654
58.00.903810.895740.891620.887440.897330.89423
59.00.901540.893440.889310.885120.895020.89191
60.00.899270.891130.886990.882780.892710.88959
60.3368.053.980.89038
61.00.896980.888820.884660.880440.890400.88725
62.00.894680.886500.882330.878090.888070.88491
63.00.892370.884170.879980.875740.885740.88256
64.00.890060.881830.877630.873370.883390.88020
65.00.887740.879480.875270.871000.881040.87783
66.00.885410.877130.872910.868630.878690.87547
67.00.883080.874770.870540.866250.876320.87309
68.00.880710.872410.868170.863870.873960.87071
69.00.878390.870040.865790.861480.871580.86833
70.00.876020.867660.863400.859080.869200.86593
71.00.873650.865270.861000.856670.866800.86352
71.978.30.86311−51.3
72.00.871270.862870.858590.854260.864400.86110
73.00.868880.860470.856180.851840.862000.85869
74.00.866480.858060.853760.849410.859580.85626
75.00.864080.855640.851350.846980.857160.85383
76.00.861680.853220.848910.844550.854730.85140
77.00.859270.850790.846470.842110.852300.84895
78.00.856850.848350.844030.839660.849850.84650
79.00.854220.845900.841580.837200.847400.84404
80.00.851970.843440.839110.834730.844940.84157
81.00.849500.840960.836640.832240.842450.83909
82.00.847020.838480.834150.829740.839970.83659
83.00.844530.835990.831640.827240.837470.83408
84.00.842030.833480.829130.824730.834960.83156
85.00.839510.830950.826600.822200.832420.82902
86.00.836970.828400.824050.819650.829870.82646
87.00.834410.825830.821480.817080.827290.82389
88.00.831810.823230.818880.814480.824690.82128
89.00.829190.820620.816260.811860.822070.81865
90.00.826540.817970.813620.809220.819420.81600
91.0094.0074.620.823860.815290.810940.806550.816740.81331
92.00.821140.812570.808230.803840.814010.81060
93.00.818390.809830.805490.801110.811270.80785
94.00.815610.807050.802720.798350.808480.80507
95.00.812780.804240.799910.795550.805670.80225
96.00.809910.801380.797060.792710.802800.79939
97.00.806980.798460.794150.789810.799880.79648
98.00.803990.795470.791170.786840.796880.79349
99.00.800940.792430.788140.783820.793830.79045
100.0100.079.390.797840.789340.785060.780750.790740.78736−114.3
rowspan=2| Mass fraction,
%

!rowspan=2| Volume concentration,
%

!rowspan=2| Mass concentration, g/(100 ml) at 15.56 °C

!colspan=4| Density relative to 4 °C water

!rowspan=2| Density at 20 °C relative to 20 °C water

!rowspan=2| Density at 25 °C relative to 25 °C water

!rowspan=2| Freezing temperature,
°C

10 °C || 20 °C || 25 °C || 30 °C

==Boiling points of aqueous solutions==

Data obtained from CRC Handbook of Chemistry (Page 2117){{rp|2391}}

border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
{{chembox header}}

| rowspan ="2" | BP °C

| colspan ="2" | Weight % ethanol

| rowspan ="2" |    

| rowspan ="2" | BP °C

| colspan ="2" | Weight % ethanol

{{chembox header}}

| liquid

vaporliquidvapor
78.195.595.5

| rowspan ="29" |    

|

78.2919286.51871
78.4858987.01770
78.6828887.51669
78.8808788.01568
79.0788688.51367
79.2768589.01265
79.4748589.51163
79.6728490.01061
79.8698490.51059
80.0678391.0957
80.2648391.5855
80.4628292.0853
80.6598292.5751
80.8568193.0649
81.0538193.5646
81.2508094.0544
81.4478094.5542
81.6458095.0439
81.8437995.5436
82.0417996.0333
82.5367896.5330
83.0337897.0227
83.5307797.5223
84.0277798.0119
84.5257598.5115
85.0237499.0< 110
85.5217399.5< 15
86.02072100.000

Azeotropic mixture

Charts

class="wikitable" style="text-align:center"

|+Thermophysical properties of mixtures of ethanol with water and dodecane

| style="width:33%;" |275px

| style="width:33%;" |275px

| style="width:33%;" |275px

Excess volume of the mixture of ethanol and water (volume contraction)

| Heat of mixing of the mixture of ethanol and water

| Vapor–liquid equilibrium of the mixture of ethanol and water (including azeotrope)

style="width:33%;" |275px

| style="width:33%;" |275px

|

Solid–liquid equilibrium of the mixture of ethanol and water (including eutecticum)

| Miscibility gap in the mixture of dodecane and ethanol

{{Chemical data page general note}}

References

{{reflist}}

{{refbegin}}

  • {{cite book|last=Lange|first=Norbert Adolph|editor=John Aurie Dean|title=Lange's Handbook of Chemistry|url=https://books.google.com/books?id=4YlqAAAAMAAJ|edition=10th|year=1967|publisher=McGraw-Hill}}
  • {{nist}}

{{refend}}

{{DEFAULTSORT:Ethanol (data page)}}

Category:Chemical data pages

Data page

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