Gold chalcogenides

{{Short description|Class of chemical compound}}

Gold chalcogenides are compounds formed between gold and one of the chalcogens, elements from group 16 of the periodic table: oxygen, sulfur, selenium, or tellurium.

  • Gold(III) oxide, Au2O3. Decomposes into gold and oxygen above 160 °C, and dissolves in concentrated alkalis to form solutions which probably contain the [Au(OH)4] ion
  • Gold(I) sulfide, Au2S. Formed by reaction of hydrogen sulfide with gold(I) compounds.
  • Gold(III) sulfide, Au2S3, claimed material but unsubstantiated.
  • Gold tellurides: Au2Te3, Au3Te5, and AuTe2 (approximate formulas) are known as non-stoichiometric compounds. They show metallic conductivity. Au3Te5 is a superconductor at 1.62 K.{{cite journal|last1=Luo|first1=H.L.|last2=Merriam|first2=M.F.|last3=Hamilton|first3=D.C.|title=Superconducting Metastable Compounds|journal=Science|date=1964|volume=145|issue=3632|pages=581–583|doi=10.1126/science.145.3632.581|pmid=17735806|bibcode=1964Sci...145..581L|s2cid=41529555}}

Gold telluride minerals, such as calaverite and krennerite (AuTe2), petzite (Ag3AuTe2), and sylvanite (AgAuTe2), are minor ores of gold (and tellurium). See telluride minerals for more information.

References

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  • {{Greenwood&Earnshaw}}

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Category:Gold compounds

Category:Non-stoichiometric compounds

Category:Sulfides

Category:Tellurides

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Category:Transition metal oxides