Iron disilicide
{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid =
| ImageFile =
| ImageSize =
| IUPACName = Iron disilicide
| OtherNames = Iron(VIII) silicide
|Section1={{Chembox Identifiers
| CASNo = 12022-99-0
| CASNo_Ref = {{cascite|correct|CAS}}
| PubChem = 6336880
| EINECS = 234-671-8
| InChI =1S/Fe.2Si
| InChIKey =JRACIMOSEUMYIP-UHFFFAOYSA-N
| SMILES =[Si]=[Fe]=[Si]
| ChemSpiderID = 4891873
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
}}
|Section2={{Chembox Properties
| Formula = FeSi2
| MolarMass = 112.016 g/mol
| Appearance = gray tetragonal crystals{{cite book | editor= Haynes, William M. | date = 2016| title = CRC Handbook of Chemistry and Physics | edition = 97th | publisher = CRC Press | isbn = 9781498754293|page=4.67}}
| MeltingPtC = 1220
| BoilingPt =
| Solubility =
| ElectronMobility = 1200 cm2/(V·s)
| BandGap = 0.87 eV (ind.){{cite journal|last1=Rizzi|first1=A.|last2=Rösen|first2=B. N. E.|last3=Freundt|first3=D.|last4=Dieker|first4=Ch.|last5=Lüth|first5=H.|last6=Gerthsen|first6=D.|title=Heteroepitaxy of β-FeSi2 on Si by gas-source MBE|journal=Physical Review B|volume=51|issue=24|year=1995|pages=17780–17794|doi=10.1103/PhysRevB.51.17780|pmid=9978811|bibcode=1995PhRvB..5117780R}}
}}
|Section3={{Chembox Structure
| CrystalStruct = Orthorhombic{{cite journal|last1=Dusausoy|first1=Y.|last2=Protas|first2=J.|last3=Wandji|first3=R.|last4=Roques|first4=B.|title=Structure cristalline du disiliciure de fer, FeSi2-β|journal=Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry|volume=27|issue=6|year=1971|pages=1209–1218|doi=10.1107/S0567740871003765}}
| SpaceGroup = Cmca (No. 64), oS48
| LattConst_a = 0.9863 nm
| LattConst_b = 0.7791 nm
| LattConst_c = 0.7833 nm
| UnitCellFormulas = 16
}}
|Section7={{Chembox Hazards
| GHSPictograms = {{GHS07}}
| GHSSignalWord = Warning
| HPhrases = {{H-phrases|315|319|335}}
| PPhrases = {{P-phrases|}}
| ExternalSDS =
| MainHazards =
| FlashPt = Non-flammable
}}
|Section8={{Chembox Related
| OtherAnions =
| OtherCations =Cobalt disilicide
Manganese disilicide
Titanium disilicide
}}
}}
Iron disilicide (FeSi2) is an intermetallic compound, a silicide of iron that occurs in nature as the rare mineral linzhiite. At room temperature it forms orthorhombic crystals (β phase), which convert into a tetragonal α phase upon heating to 970 °C.
See also
References
{{reflist}}
{{Iron compounds}}
{{Silicides}}