Isotopes of americium#Americium-237
{{Short description|none}}
{{Infobox americium isotopes}}
Americium (95Am) is an artificial element, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no known stable isotopes. The first isotope to be synthesized was 241Am in 1944. The artificial element decays by ejecting alpha particles. Americium has an atomic number of 95 (the number of protons in the nucleus of the americium atom). Despite {{chem|243|Am}} being an order of magnitude longer lived than {{chem|241|Am}}, the former is harder to obtain than the latter as more of it is present in spent nuclear fuel.
Eighteen radioisotopes of americium, ranging from 229Am to 247Am with the exception of 231Am, have been characterized; another isotope, 223Am, has also been reported but is unconfirmed. The most stable isotopes are 243Am with a half-life of 7,370 years and 241Am with a half-life of 432.2 years. All of the remaining radioactive isotopes have half-lives that are less than seven days, the majority of which are shorter than two hours. This element also has eight meta states, with the most stable being 242m1Am (half-life 141 years). This isomer is unusual in that its half-life is far longer than that of the ground state of the same isotope.
List of isotopes
{{Anchor|Americium-224|Americium-225|Americium-226|Americium-227|Americium-228|Americium-231|Americium-248|Americium-249}}
{{Isotopes table
| symbol = Am
| refs = NUBASE2020
| notes = m, unc(), mass#, exen#, spin(), spin#, CD, EC, IT, SF
}}
|-id=Americium-223
| 223Am{{refn|group=n|The discovery of this isotope is uncertain due to disagreements between theoretical predictions and reported experimental data.{{cite journal |title=New short-lived isotope 223Np and the absence of the Z = 92 subshell closure near N = 126
|first=M. D. |last=Sun |display-authors=et al. |journal=Physics Letters B |volume=771 |date=2017 |pages=303–308 |doi=10.1016/j.physletb.2017.03.074 |url=https://www.researchgate.net/publication/317142406|doi-access=free |bibcode=2017PhLB..771..303S }}}}
| style="text-align:right" | 95
| style="text-align:right" | 128
| 223.04584(32)#
| 10(9) ms
| α
| 219Np
| 9/2–#
|-id=Americium-229
| 229Am
| style="text-align:right" | 95
| style="text-align:right" | 134
| 229.04528(11)
| 1.8(15) s
| α
| 225Np
| 5/2–#
|-id=Americium-230
| rowspan=2 | 230Am
| rowspan=2 style="text-align:right" | 95
| rowspan=2 style="text-align:right" | 135
| rowspan=2 | 230.04603(15)#
| rowspan=2 | 40(9) s
| β+ (<70%)
| 230Pu
| rowspan=2 | 1–#
|-
| β+SF (>30%)
| (various)
|-id=Americium-232
| rowspan=3 | 232Am
| rowspan=3 style="text-align:right" | 95
| rowspan=3 style="text-align:right" | 137
| rowspan=3 | 232.04661(32)#
| rowspan=3 | 1.31(4) min
| β+ (97%)
| 232Pu
| rowspan=3 | 1–#
|-
| α (3%)
| 228Np
|-
| β+SF (0.069%)
| (various)
|-id=Americium-233
| rowspan=2 | 233Am
| rowspan=2 style="text-align:right" | 95
| rowspan=2 style="text-align:right" | 138
| rowspan=2 | 233.04647(12)#
| rowspan=2 | 3.2(8) min
| β+ (95.5%)
| 233Pu
| rowspan=2 | 5/2–#
|-
| α (4.5%)
| 229Np
|-id=Americium-234
| rowspan=3 | 234Am
| rowspan=3 style="text-align:right" | 95
| rowspan=3 style="text-align:right" | 139
| rowspan=3 | 234.04773(17)#
| rowspan=3 | 2.32(8) min
| β+ (99.95%)
| 234Pu
| rowspan=3 | 0–#
|-
| α (0.039%)
| 230Np
|-
| β+, SF (0.0066%)
| (various)
|-id=Americium-235
| rowspan=2 | 235Am
| rowspan=2 style="text-align:right" | 95
| rowspan=2 style="text-align:right" | 140
| rowspan=2 | 235.047906(57)
| rowspan=2 | 10.3(6) min
| β+ (99.60%)
| 235Pu
| rowspan=2 | 5/2−#
|-
| α (0.40%)
| 231Np
|-id=Americium-236
| rowspan=2 | 236Am
| rowspan=2 style="text-align:right" | 95
| rowspan=2 style="text-align:right" | 141
| rowspan=2 | 236.04943(13)#
| rowspan=2 | 3.6(1) min
| β+
| 236Pu
| rowspan=2 | 5−
|-
| α (4×10−3%)
| 232Np
|-id=Americium-236m
| rowspan=2 style="text-indent:1em" | 236mAm
| rowspan=2 colspan=3 style="text-indent:2em" | 50(50)# keV
| rowspan=2 | 2.9(2) min
| β+
| 236Pu
| rowspan=2 | (1−)
|-
| α ?
| 232Np
|-id=Americium-237
| rowspan=2 | 237Am
| rowspan=2 style="text-align:right" | 95
| rowspan=2 style="text-align:right" | 142
| rowspan=2 | 237.049995(64)#
| rowspan=2 | 73.6(8) min
| β+ (99.975%)
| 237Pu
| rowspan=2 | 5/2−
|-
| α (.025%)
| 233Np
|-id=Americium-238
| rowspan=2 | 238Am
| rowspan=2 style="text-align:right" | 95
| rowspan=2 style="text-align:right" | 143
| rowspan=2 | 238.051983(63)
| rowspan=2 | 98(3) min
| β+
| 238Pu
| rowspan=2 | 1+
|-
| α (1.0×10−4%)
| 234Np
|-id=Americium-238m
| rowspan=2 style="text-indent:1em" | 238mAm
| rowspan=2 colspan="3" style="text-indent:2em" | 2500(200)# keV
| rowspan=2 | 35(18) μs
| SF
| (various)
| rowspan=2 |
|-
| IT ?
| 238Am
|-id=Americium-239
| rowspan=2 | 239Am
| rowspan=2 style="text-align:right" | 95
| rowspan=2 style="text-align:right" | 144
| rowspan=2 | 239.0530227(21)
| rowspan=2 | 11.9(1) h
| EC (99.99%)
| 239Pu
| rowspan=2 | 5/2−
|-
| α (0.01%)
| 235Np
|-id=Americium-239m
| rowspan=2 style="text-indent:1em" | 239mAm
| rowspan=2 colspan="3" style="text-indent:2em" | 2500(200) keV
| rowspan=2 | 163(12) ns
| SF
| (various)
| rowspan=2 | (7/2+)
|-
| IT ?
| 239Am
|-id=Americium-240
| rowspan=2 | 240Am
| rowspan=2 style="text-align:right" | 95
| rowspan=2 style="text-align:right" | 145
| rowspan=2 | 240.055298(15)
| rowspan=2 | 50.8(3) h
| β+
| 240Pu
| rowspan=2 | (3−)
|-
| α (1.9×10−4%)
| 236Np
|-id=Americium-240m
| rowspan=2 style="text-indent:1em" | 240mAm
| rowspan=2 colspan="3" style="text-indent:2em" | 3000(200) keV
| rowspan=2 | 940(40) μs
| SF
| (various)
| rowspan=2 |
|-
| IT ?
| 240Am
|-
| rowspan=2 | 241Am
| rowspan=2 style="text-align:right" | 95
| rowspan=2 style="text-align:right" | 146
| rowspan=2 | 241.0568273(12)
| rowspan=2 | 432.6(6) y
| α
| 237Np
| rowspan=2 | 5/2−
|-
| SF (3.6×10−10%)
| (various)
|-id=Americium-241m
| style="text-indent:1em" | 241mAm
| colspan="3" style="text-indent:2em" | 2200(200) keV
| 1.2(3) μs
| SF
| (various)
|
|-id=Americium-242
| rowspan=2 | 242Am
| rowspan=2 style="text-align:right" | 95
| rowspan=2 style="text-align:right" | 147
| rowspan=2 | 242.0595474(12)
| rowspan=2 | 16.02(2) h
| β− (82.7%)
| 242Cm
| rowspan=2 | 1−
|-
| EC (17.3%)
| 242Pu
|-id=Americium-242m1
| rowspan=3 style="text-indent:1em" | 242m1Am
| rowspan=3 colspan="3" style="text-indent:2em" | 48.60(5) keV
| rowspan=3 | 141(2) y
| IT (99.54%)
| 242Am
| rowspan=3 | 5−
|-
| α (.46%)
| 238Np
|-
| SF ?
| (various)
|-id=Americium-242m2
| rowspan=2 style="text-indent:1em" | 242m2Am
| rowspan=2 colspan="3" style="text-indent:2em" | 2200(80) keV
| rowspan=2 | 14.0(10) ms
| SF
| (various)
| rowspan=2 | (2+, 3−)
|-
| IT ?
| 242Am
|-
| rowspan=2 | 243Am
| rowspan=2 style="text-align:right" | 95
| rowspan=2 style="text-align:right" | 148
| rowspan=2 | 243.0613799(15)
| rowspan=2 | 7,350(9) y
| α
| 239Np
| rowspan=2 | 5/2−
|-
| SF (3.7×10−9%)
| (various)
|-id=Americium-243m
| rowspan=2 style="text-indent:1em" | 243mAm
| rowspan=2 colspan="3" style="text-indent:2em" | 2300(200) keV
| rowspan=2 | 5.5(5) μs
| SF
| (various)
| rowspan=2 |
|-
| IT ?
| 243Am
|-id=Americium-244
| 244Am
| style="text-align:right" | 95
| style="text-align:right" | 149
| 244.0642829(16)
| 10.01(3) h
| β−
| 244Cm
| (6−)
|-id=Americium-244m1
| rowspan=2 style="text-indent:1em" | 244m1Am
| rowspan=2 colspan="3" style="text-indent:2em" | 89.3(16) keV
| rowspan=2 | 26.13(43) min
| β− (99.96%)
| 244Cm
| rowspan=2 | 1+
|-
| EC (0.0364%)
| 244Pu
|-id=Americium-244m2
| rowspan=2 style="text-indent:1em" | 244m2Am
| rowspan=2 colspan="3" style="text-indent:2em" | 2000(200)# keV
| rowspan=2 | 900(150) μs
| SF
| (various)
| rowspan=2 |
|-
| IT ?
| 244Am
|-id=Americium-244m3
| rowspan=2 style="text-indent:1em" | 244m3Am
| rowspan=2 colspan="3" style="text-indent:2em" | 2200(200)# keV
| rowspan=2 | ~6.5 μs
| SF
| (various)
| rowspan=2 |
|-
| IT ?
| 244Am
|-id=Americium-245
| 245Am
| style="text-align:right" | 95
| style="text-align:right" | 150
| 245.0664528(20)
| 2.05(1) h
| β−
| 245Cm
| 5/2+
|-id=Americium-245m
| rowspan=2 style="text-indent:1em" | 245mAm
| rowspan=2 colspan="3" style="text-indent:2em" | 2400(400)# keV
| rowspan=2 | 640(60) ns
| SF
| (various)
| rowspan=2 |
|-
| IT ?
| 245Am
|-id=Americium-246
| 246Am
| style="text-align:right" | 95
| style="text-align:right" | 151
| 246.069774(19)#
| 39(3) min
| β−
| 246Cm
| (7−)
|-id=Americium-246m1
| rowspan=2 style="text-indent:1em" | 246m1Am
| rowspan=2 colspan="3" style="text-indent:2em" | 30(10)# keV
| rowspan=2 | 25.0(2) min
| β−
| 246Cm
| rowspan=2 | 2(−)
|-
| IT ?
| 246Am
|-id=Americium-246m2
| rowspan=2 style="text-indent:1em" | 246m2Am
| rowspan=2 colspan="3" style="text-indent:2em" | 2000(800)# keV
| rowspan=2 | 73(10) μs
| SF
| (various)
| rowspan=2 |
|-
| IT ?
| 246Am
|-id=Americium-247
| 247Am
| style="text-align:right" | 95
| style="text-align:right" | 152
| 247.07209(11)#
| 23.0(13) min
| β−
| 247Cm
| 5/2#
{{Isotopes table/footer}}
Actinides vs fission products
{{Actinidesvsfissionproducts}}
{{clear}}
Notable isotopes
= Americium-241 =
File:Americium button hd.jpgs.]]
{{main|Americium-241}}
Americium-241 is the most common isotope of americium in nuclear waste.[http://www.ead.anl.gov/pub/doc/Americium.pdf "Americium"] {{webarchive|url=https://web.archive.org/web/20120730003822/http://www.ead.anl.gov/pub/doc/americium.pdf |date=2012-07-30 }}. Argonne National Laboratory, EVS. Retrieved 25 December 2009. It is the isotope used in an americium smoke detector based on an ionization chamber. It is a potential fuel for long-lifetime radioisotope thermoelectric generators.
class="wikitable" | |
Parameter | Value |
---|---|
Atomic mass
| align=right | 241.056829 u | |
Mass excess
| align=right | 52930 keV | |
Beta decay energy
| align=right | −767 keV | |
Spin
| align=right | 5/2− | |
Half-life
| align=right | 432.6 years | |
Spontaneous fissions
| align=right | 1200 per kg s | |
Decay heat
| align=right | 114 watts/kg |
Possible parent nuclides: beta from Plutonium-241, electron capture from {{sup|241}}Cm, alpha from {{sup|245}}Bk.
{{sup|241}}Am alpha decays, with a by-product of gamma rays. Its presence in plutonium is determined by the original concentration of {{sup|241}}Pu and the sample age. Due to the low penetration of alpha radiation, {{sup|241}}Am only poses a health risk when ingested or inhaled. Older samples of plutonium containing plutonium-241 contain a buildup of {{sup|241}}Am. A chemical removal of americium from reworked plutonium (e.g. during reworking of plutonium pits) may be required.
=Americium-242m=
class="wikitable"
|+{{sup|242m}}Am decay modes (half-life: 141 years) !Probability!!Decay mode!!Decay energy!!Decay product | |||
99.54% | isomeric transition | 0.05 MeV | {{sup|242}}Am |
0.46% | alpha decay | 5.64 MeV | {{sup|238}}Np |
(1.5±0.6) × 10{{sup|−10}}{{tsp}}{{cite journal |journal=Physical Review |volume=155 |issue = 4|date=March 1967 |author=J. T. Caldwell |author2=S. C. Fultz |author3=C. D. Bowman |author4=R. W. Hoff |title=Spontaneous Fission Half-Life of Am{{sup|242m}} |doi=10.1103/PhysRev.155.1309 |pages=1309–1313|bibcode=1967PhRv..155.1309C }} (halflife (9.5±3.5)×10{{sup|11}} years) | spontaneous fission | ~200 MeV | fission products |
Americium-242m has a mass of 242.0595492 g/mol. It is one of the rare cases, like isotopes of silver, isotopes of holmium, isotopes of tantalum#Tantalum-180m, isotopes of rhenium, isotopes of iridium, isotopes of bismuth, isotopes of polonium and others, where a higher-energy nuclear isomer is more stable than the ground state, americium-242.[http://www.matpack.de/Info/Nuclear/Nuclids/A/Am242.html 95-Am-242] {{webarchive|url=https://web.archive.org/web/20110719060944/http://www.matpack.de/Info/Nuclear/Nuclids/A/Am242.html |date=2011-07-19 }}
{{sup|242m}}Am is fissile with a low critical mass, comparable to that of plutonium-239.{{cite web |title=Critical Mass Calculations for {{sup|241}}Am, {{sup|242m}}Am and {{sup|243}}Am |url=http://typhoon.jaea.go.jp/icnc2003/Proceeding/paper/6.5_022.pdf |archive-url=https://web.archive.org/web/20110722105207/http://typhoon.jaea.go.jp/icnc2003/Proceeding/paper/6.5_022.pdf |url-status=dead |archive-date=July 22, 2011 |access-date=February 3, 2011 }} It has a very high fission cross section, and is quickly destroyed if it is produced in a nuclear reactor. It has been investigated whether this isotope could be used for a novel type of nuclear rocket.{{cite press release |url=https://www.sciencedaily.com/releases/2001/01/010103073253.htm |title=Extremely Efficient Nuclear Fuel Could Take Man To Mars In Just Two Weeks |date=December 28, 2000 |publisher=Ben-Gurion University Of The Negev}}{{cite journal|last1=Ronen|first1=Yigal|last2=Shwageraus|first2=E.|title=Ultra-thin 241mAm fuel elements in nuclear reactors|journal=Nuclear Instruments and Methods in Physics Research A|date=2000|volume=455|issue=2|pages=442–451|doi=10.1016/s0168-9002(00)00506-4|bibcode=2000NIMPA.455..442R}}
class="wikitable"
|+{{sup|242}}Am decay modes (half-life: 16 hours) !Probability!!Decay mode!!Decay energy!!Decay product | |||
82.70% | beta decay | 0.665 MeV | {{sup|242}}Cm |
17.30% | electron capture | 0.751 MeV | Plutonium-242 |
=Americium-243=
Americium-243 has a mass of 243.06138 g/mol and a half-life of 7,370 years, the longest lasting of all americium isotopes. It is formed in the nuclear fuel cycle by neutron capture on plutonium-242 followed by beta decay.[http://www.ornl.gov/sci/isotopes/r_am243.html "Americium-243"] {{webarchive|url=https://web.archive.org/web/20110225120159/http://www.ornl.gov/sci/isotopes/r_am243.html |date=2011-02-25 }}. Oak Ridge National Laboratory. Retrieved 25 December 2009. Production increases exponentially with increasing burnup as a total of 5 neutron captures on uranium-238 are required. If MOX-fuel is used, particularly MOX-fuel high in {{chem|241|Pu}} and {{chem|242|Pu}}, more americium overall and more {{chem|243|Am}} will be produced.
It decays by either emitting an alpha particle (with a decay energy of 5.27 MeV) to become {{sup|239}}Np, which then quickly decays to plutonium-239, or rarely, by spontaneous fission.[http://education.jlab.org/itselemental/iso095.html "Isotopes of the Element Americium"]. Jefferson Lab Science Education. Retrieved 25 December 2009.
As for the other americium isotopes, and more generally for all alpha emitters, {{sup|243}}Am is carcinogenic in case of internal contamination after being inhaled or ingested. {{sup|243}}Am also presents a risk of external irradiation associated with the gamma ray emitted by its short-lived decay product neptunium-239. The external irradiation risk for the other two americium isotopes ({{sup|241}}Am and {{sup|242m}}Am) is less than 10% of that for americium-243.
References
{{Reflist|30em}}
Sources
- Isotope masses from:
- {{NNDC}}
- Half-life, spin, and isomer data selected from the following sources.
- {{NNDC}}
- IAEA - Nuclear Data Section. [https://www-nds.iaea.org/relnsd/vcharthtml/VChartHTML.html Live Chart of Nuclides.] Vienna International Centre.
- {{CRC85|chapter=11}}
{{Navbox element isotopes}}