Johnsenite-(Ce)
{{Short description|Mineral of the eudialyte group}}
{{infobox mineral
| name = Johnsenite-(Ce)
| category = Cyclosilicate
| image =
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| formula = {{chem2|Na12(Ce,La,Sr,Ca,[ ])3Ca6Mn3Zr3WSi(Si9O27)2(Si3O9)2(CO3)O(OH,Cl)2}} (original form)
| strunz = 9.CO.10 (10 ed)
8/E.25-57 (8 ed)
| dana = 64.1.2.7
| system = Trigonal
| class = Hexagonal scalenohedral ({{overline|3}}m)
H-M symbol: ({{overline|3}} 2m)
| symmetry = R{{overline|3}}m
| unit cell = a = 14.24, c = 30.03 [Å] (approximated); Z = 3
| color = Pale yellow to bright orange
| colour =
| habit = Skeletal crystals (etched); aggregates
| twinning =
| cleavage = None
| fracture = Uneven
| tenacity = Brittle
| mohs = 5–6
| luster = Vitreous
| streak = White
| diaphaneity = Transparent or translucent
| gravity =
| density = 3.24 (measured)
| polish =
| opticalprop = Uniaxial (−)
| refractive = nω = 1.65, nε = 1.64 (approximated)
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| pleochroism = None
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Johnsenite-(Ce) is a very rare mineral of the eudialyte group,Mindat, Johnsenite-(Ce), http://www.mindat.org/min-27479.html with the chemical formula {{chem2|Na12(Ce,La,Sr,Ca,[ ])3Ca6Mn3Zr3WSi(Si9O27)2(Si3O9)2(CO3)O(OH,Cl)2}}.Grice, J.D., and Gault, R.A., 2006. Johnsenite-(Ce): a new member of the eudialyte group from Mont-Saint Hilaire, Quebec, Canada. The Canadian Mineralogist 44, 105–115 The original formula was extended to show the presence of both the cyclic silicate groups and silicon at the M4 site, according to the nomenclature of the eudialyte group.Johnsen, O., Ferraris, G., Gault, R.A., Grice, D.G., Kampf, A.R., and Pekov, I.V., 2003. The nomenclature of eudialyte-group minerals. The Canadian Mineralogist 41, 785–794 It is the third eudialyte-group mineral with essential tungsten (after khomyakovite and manganokhomyakovite), and second with essential rare earth elements (after zirsilite-(Ce), which is the niobium-analogue of johnsenite-(Ce)). In fact, some niobium substitutes for tungsten in johnsenite-(Ce). Other characteristic feature is the presence of essential carbonate group, shared with carbokentbrooksite, golyshevite, mogovidite and zirsilite-(Ce).
Occurrence and association
Johnsenite-(Ce) was discovered in alkaline rocks of Mont Saint-Hilaire, Quebec, Canada, which is also a type locality for other eudialyte group species: oneillite, khomyakovite and manganokhomyakovite.{{cite web |url=http://www.mindat.org/loc-599.html |title=Poudrette quarry (Demix quarry; Uni-Mix quarry; Desourdy quarry; Carrière Mont Saint-Hilaire), Mont Saint-Hilaire, La Vallée-du-Richelieu RCM, Montérégie, Québec, Canada - Mindat.org |website=Mindat.org |accessdate=2016-03-11}} The association of johnsenite-(Ce) is rich, as it includes aegirine, albite, amphibole-group mineral, burbankite-group mineral, calcite, catapleiite, cerite-(Ce), dawsonite, epididymite, fluorapophyllite, galena, microcline, molybdenite, natrolite, pectolite, pyrite, pyrrhotite, quartz, rhodochrosite, sphalerite, steacyite, stillwellite-(Ce), titanite, tuperssuatsiaite, zakharovite and zirsilite-(Ce).
Notes on chemistry
Notable impurities in johnsenite-(Ce) are iron, titanium, niobium, yttrium, potassium, praseodymium, and neodymium. Traces of gadolinium, samarium, and hafnium are also reported.