Metallization pressure

Metallization pressure is the pressure required for a non-metallic chemical element to become a metal. Every material is predicted to turn into a metal if the pressure is high enough, and temperature low enough. Some of these pressures are beyond the reach of diamond anvil cells, and are thus theoretical predictions. Neon has the highest metallization pressure for any element.

The value for phosphorus refers to pressurizing black phosphorus. The value for arsenic refers to pressurizing metastable black arsenic; grey arsenic, the standard state, is already a metallic conductor at standard conditions. No value is known or theoretically predicted for radon. Astatine is calculated to already be a metal at standard conditions,{{cite journal

|doi=10.1103/PhysRevLett.111.116404|title=Condensed Astatine: Monatomic and Metallic|year=2013|last1=Hermann|first1=A.|last2=Hoffmann|first2=R.|last3=Ashcroft|first3=N. W.|journal=Physical Review Letters|volume=111|issue=11|pages=116404-1–116404-5|bibcode=2013PhRvL.111k6404H|pmid=24074111}} although its extreme radioactivity means that this has never been tested experimentally.

class="wikitable sortable"

! Z

! Element

! p, Mbar

! ref.

! type

1

| Hydrogen

| {{sort|3.9|3.9}}

| {{cite journal|doi=10.1103/PhysRevLett.114.105305|title=Molecular to Atomic Phase Transition in Hydrogen under High Pressure|year=2015|last1=McMinis|first1=Jeremy|last2=Clay|first2=Raymond C.|last3=Lee|first3=Donghwa|last4=Morales|first4=Miguel A.|journal=Physical Review Letters|volume=114|issue=10|page=105305|pmid=25815944|bibcode=2015PhRvL.114j5305M|doi-access=free}}

| theoretical

2

| Helium

| {{sort|329|329}}

| {{cite journal|doi=10.1103/PhysRevLett.112.055504|title=Electron-Phonon Coupling and the Metallization of Solid Helium at Terapascal Pressures|year=2014|last1=Monserrat|first1=Bartomeu|last2=Drummond|first2=N. D.|last3=Pickard|first3=Chris J.|last4=Needs|first4=R. J.|journal=Physical Review Letters|volume=112|issue=5|page=055504|pmid=24580611|arxiv=1311.1005|bibcode=2014PhRvL.112e5504M|s2cid=29848984}}

| theoretical

5

| Boron

| {{sort|1.6|1.6}}

| {{cite journal |last1=Eremets |first1=M. I. |last2=Struzhkin |first2=V. V. |first3=H. |last3=Mao |first4=R. J. |last4=Hemley |date=2001 |title=Superconductivity in boron |url= |journal=Science |volume=293 |issue=5528 |pages=272–274 |doi=10.1126/science.1062286 |access-date=}}{{cite journal|doi=10.1103/PhysRevB.66.092101|title=Pressure-induced metallization in solid boron|year=2002|last1=Zhao|first1=Jijun|last2=Lu|first2=Jian Ping|journal=Physical Review B|volume=66|issue=9|page=092101|arxiv=cond-mat/0109550|bibcode=2002PhRvB..66i2101Z|s2cid=119426107}}

| experimental

6

| Carbon

| {{sort|11|11}}

| {{cite journal|doi=10.1073/pnas.0510489103|year=2006|first1=Alfredo A.|last1=Correa|first2=Stanimir A.|last2=Bonev|first3=Giulia|last3=Galli|title=Carbon under extreme conditions: phase boundaries and electronic properties from first-principles theory|volume=103|issue=5|pages=1204–1208|issn=0027-8424|pmid=16432191|pmc=1345714|journal=Proceedings of the National Academy of Sciences of the United States of America|bibcode=2006PNAS..103.1204C|doi-access=free }}

| theoretical

7

| Nitrogen

| {{sort|5|>> 5}}

| {{cite journal|doi=10.1103/PhysRevLett.102.065501|title=Novel High Pressure Structures of Polymeric Nitrogen|year=2009|last1=Ma|first1=Yanming|last2=Oganov|first2=Artem R.|last3=Li|first3=Zhenwei|last4=Xie|first4=Yu|last5=Kotakoski|first5=Jani|journal=Physical Review Letters|volume=102|issue=6|pages=065501|pmid=19257600|bibcode=2009PhRvL.102f5501M}}

| theoretical

8

| Oxygen

| {{sort|0.960|0.96}}

| {{cite journal

| last1 = Akahama

| first1 = Yuichi

|first2=Haruki |last2=Kawamura |first3=Daniel |last3=Häusermann |first4=Michael |last4=Hanfland |first5=Osamu |last5=Shimomura

|date=June 1995

| title = New High-Pressure Structural Transition of Oxygen at 96 GPa Associated with Metallization in a Molecular Solid

| journal = Physical Review Letters

| volume = 74

| issue = 23

| pages = 4690–4694

| doi = 10.1103/PhysRevLett.74.4690

| pmid=10058574

| bibcode=1995PhRvL..74.4690A}}{{cite journal|doi=10.1039/C9CP05267D|title=Stability and metallization of solid oxygen at high pressure|year=2020|last1=Elatresh|first1=Sabri F.|last2=Bonev|first2=Stanimir A.|journal=Physical Chemistry Chemical Physics|volume=22|issue=22|pages=12577–12583|pmid=32452471|bibcode=2020PCCP...2212577E|osti=1860780 |s2cid=218891958 }}

| experimental

9

| Fluorine

| {{sort|25|25}}

| {{cite journal |last1=Olson |first1=Mark A. |last2=Bhatia |first2=Shefali |last3=Larson |first3=Paul |last4=Militzer |first4=Burkhard |date=2020 |title=Prediction of chlorine and fluorine crystal structures at high pressure using symmetry driven structure search with geometric constraints |url=https://aip.scitation.org/doi/full/10.1063/5.0018402 |journal=The Journal of Chemical Physics |volume=153 |issue=9 |page=094111 |doi=10.1063/5.0018402 |pmid=32891084 |arxiv=2008.04471 |s2cid=221095681 |access-date=13 December 2022}}

| theoretical

10

| Neon

| {{sort|2084|2084}}

| {{cite journal|doi=10.1063/1.5089489|title=Metallization and positive pressure dependency of bandgap in solid neon|year=2019|last1=Tang|first1=Jun|last2=Ao|first2=Bingyun|last3=Huang|first3=Li|last4=Ye|first4=Xiaoqiu|last5=Gu|first5=Yunjun|last6=Chen|first6=Qifeng|journal=The Journal of Chemical Physics|volume=150|issue=11|page=111103|pmid=30901987|bibcode=2019JChPh.150k1103T|doi-access=free}}

| theoretical

14

| Silicon

| {{sort|0.120|0.12}}

| {{cite journal|last1=Hu|first1=Jing Zhu|last2=Merkle|first2=Larry D.|last3=Menoni|first3=Carmen S.|author-link3=Carmen Menoni|last4=Spain|first4=Ian L.|year=1986|title=Crystal data for high-pressure phases of silicon|journal=Physical Review B|volume=34|issue=7|pages=4679–4684|bibcode=1986PhRvB..34.4679H|doi=10.1103/PhysRevB.34.4679|pmid=9940261|hdl=10217/634|hdl-access=free}}

| experimental

15

| Phosphorus

| {{sort|0.048|0.048}}

| {{cite journal|doi=10.1143/JJAP.23.15|title=Electrical Investigation of Phase Transition in Black Phosphorus under High Pressure|year=1984|last1=Okajima|first1=Michio|last2=Endo|first2=Shoichi|last3=Akahama|first3=Yuichi|last4=Narita|first4=Shin-ichiro|journal=Japanese Journal of Applied Physics|volume=23|issue=1|pages=15–19|bibcode=1984JaJAP..23...15O|s2cid=121615032 }}

| experimental

16

| Sulfur

| {{sort|0.830|0.83}}

| {{cite journal|doi=10.1103/PhysRevB.48.6862|title=Pressure-induced structural phase transition in sulfur at 83 GPa|year=1993|last1=Akahama|first1=Y.|last2=Kobayashi|first2=M.|last3=Kawamura|first3=H.|journal=Physical Review B|volume=48|issue=10|pages=6862–6864|pmid=10006849|bibcode=1993PhRvB..48.6862A}}

| experimental

17

| Chlorine

| {{sort|2.0|2.0}}

| {{cite journal |last1=Dalladay-Simpson |first1=Philip |last2=Binns |first2=Jack |last3=Peña-Alvarez |first3=Miriam |last4=Donnelly |first4=Mary-Ellen |last5=Greenberg |first5=Eran |last6=Prakapenka |first6=Vitali |last7=Chen |first7=Xiao-Jia |last8=Gregoryanz |first8=Eugene |last9=Howie |first9=Ross T. |title=Band gap closure, incommensurability and molecular dissociation of dense chlorine |journal=Nature Communications |date=8 March 2019 |volume=10 |issue=1 |page=1134 |doi=10.1038/s41467-019-09108-x |pmid=30850606 |pmc=6408506 |bibcode=2019NatCo..10.1134D |language=en |issn=2041-1723|doi-access=free }}

| experimental

18

| Argon

| {{sort|5.1|5.1}}

| {{cite journal |doi=10.1103/PhysRevB.52.15165|title=First-principles study of solid Ar and Kr under high compression|first1=I.|last1=Kwon|first2=L.A.|last2=Collins|first3=J.D.|last3=Kress|first4=N.|last4=Troullier|journal=Physical Review B|volume=52|issue=21|pages=15165–15169|year=1995|pmid=9980870|bibcode=1995PhRvB..5215165K}}

| theoretical

32

| Germanium

| {{sort|0.110|0.11}}

| {{cite journal|doi=10.1103/PhysRevLett.56.1944|title=Phase-Transition Studies of Germanium to 1.25 Mbar|year=1986|last1=Vohra|first1=Yogesh K.|last2=Brister|first2=Keith E.|last3=Desgreniers|first3=Serge|last4=Ruoff|first4=Arthur L.|last5=Chang|first5=K. J.|last6=Cohen|first6=Marvin L.|journal=Physical Review Letters|volume=56|issue=18|pages=1944–1947|pmid=10032817|bibcode=1986PhRvL..56.1944V}}

| experimental

33

| Arsenic

| {{sort|0.022|0.022}}

| {{cite journal|doi=10.1088/1361-648X/ab3f76|title=Pressure-induced metallization of black arsenic|year=2019|last1=Li|first1=Ruiping|last2=Han|first2=Nannan|last3=Cheng|first3=Yingchun|last4=Huang|first4=Wei|journal=Journal of Physics: Condensed Matter|volume=31|issue=50|pages=505501|pmid=31469104|bibcode=2019JPCM...31X5501L|s2cid=201673605 }}

| theoretical

34

| Selenium

| {{sort|0.230|0.23}}

| {{cite journal|doi=10.1103/PhysRevB.47.20|title=Structural studies of pressure-induced phase transitions in selenium up to 150 GPa|year=1993|last1=Akahama|first1=Y.|last2=Kobayashi|first2=M.|last3=Kawamura|first3=H.|journal=Physical Review B|volume=47|issue=1|pages=20–26|pmid=10004412|bibcode=1993PhRvB..47...20A}}

| experimental

35

| Bromine

| {{sort|0.250|0.25}}

| {{cite journal|doi=10.1007/s100510070136|title=Bromine metallization studied by X-ray absorption spectroscopy|year=2000|last1=San Miguel|first1=A.|last2=Libotte|first2=H.|last3=Gaspard|first3=J.P.|last4=Gauthier|first4=M.|last5=Itié|first5=J.P.|last6=Polian|first6=A.|journal=The European Physical Journal B|volume=17|issue=2|pages=227–233|bibcode=2000EPJB...17..227S|s2cid=123571031}}

| experimental

36

| Krypton

| {{sort|3.1|3.1}}

| {{cite journal|doi=10.1016/0375-9601(89)90503-3|title=Equation of state and metallization in compressed solid krypton|year=1989|last1=Hama|first1=Juichiro|last2=Suito|first2=Kaichi|journal=Physics Letters A|volume=140|issue=3|pages=117–121|bibcode=1989PhLA..140..117H}}

| theoretical

52

| Tellurium

| {{sort|0.040|0.04}}

| {{cite journal|doi=10.1103/PhysRevB.86.064103|title=High-pressure phases of crystalline tellurium: A combined Raman and ab initio study|first1=C.|last1=Marini|first2=D.|last2=Chermisi|first3=M.|last3=Lavagnini|first4=D.|last4=Di Castro|first5=C.|last5=Petrillo|first6=L.|last6=Degiorgi|first7=S.|last7=Scandolo|first8=P.|last8=Postorino|journal=Physical Review B|volume=86|issue=6|year=2012|page=064103|bibcode=2012PhRvB..86f4103M}}

| experimental

53

| Iodine

| {{sort|0.160|0.16}}

| {{cite journal|doi=10.1103/physrevlett.58.575|title=Metallization and structural transformation of iodine under pressure: A microscopic view|year=1987|last1=Pasternak|first1=M.|last2=Farrell|first2=J. N.|last3=Taylor|first3=R. D.|journal=Physical Review Letters|volume=58|issue=6|pages=575–578|pmid=10034976|bibcode=1987PhRvL..58..575P}}

| experimental

54

| Xenon

| {{sort|1.3|1.3}}

| {{cite journal|doi=10.1103/PhysRevLett.85.2797|title=Electrical Conductivity of Xenon at Megabar Pressures|year=2000|last1=Eremets|first1=Mikhail|last2=Gregoryanz|first2=Eugene|last3=Struzhkin|first3=Victor|last4=Mao|first4=Ho-Kwang|last5=Hemley|first5=Russell|last6=Mulders|first6=Norbert|last7=Zimmerman|first7=Neil|journal=Physical Review Letters|volume=85|issue=13|pages=2797–2800|pmid=10991236|bibcode=2000PhRvL..85.2797E}}

| experimental

86

| Radon

| {{sort|0|.}}

| .

| .

See also

References