Nonmetallic material

{{Band structure filling diagram}}The original approach to conduction and nonmetals was a band-structure with delocalized electrons (i.e. spread out in space). In this approach a nonmetal has a gap in the energy levels of the electrons at the Fermi level.{{Cite book |last1=Ashcroft |first1=Neil W. |title=Solid state physics |last2=Mermin |first2=N. David |date=1976 |publisher=Saunders college publ |isbn=978-0-03-083993-1 |location=Fort Worth Philadelphia San Diego [etc.]}}{{Rp|location=Chpt 8 & 19}} In contrast, a metal would have at least one partially occupied band at the Fermi level; in a semiconductor or insulator there are no delocalized states at the Fermi level, see for instance Ashcroft and Mermin. These definitions are equivalent to stating that metals conduct electricity at absolute zero, as suggested by Nevill Francis Mott,{{Cite book |last=Yonezawa |first=Fumiko |title=Physics of metal-nonmetal transitions |date=2017 |publisher=IOS Press |isbn=978-1-61499-786-3 |location=Washington, DC |pages= |quote=}}{{Rp|page=257}} and the equivalent definition at other temperatures is also commonly used as in textbooks such as Chemistry of the Non-Metals by Ralf Steudel{{Cite book |last=Steudel |first=Ralf |url=https://www.degruyter.com/document/doi/10.1515/9783110578065/html |title=Chemistry of the Non-Metals: Syntheses - Structures - Bonding - Applications |date=2020 |publisher=De Gruyter |isbn=978-3-11-057806-5 |pages=154 |doi=10.1515/9783110578065}} and work on metal–insulator transitions.

In early work{{Cite journal |date=1931 |title=The theory of electronic semi-conductors |journal=Proceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character |language=en |volume=133 |issue=822 |pages=458–491 |doi=10.1098/rspa.1931.0162 |bibcode=1931RSPSA.133..458W |issn=0950-1207 |last1=Wilson |first1=A. H. |doi-access=free }}{{Cite journal |date=1931 |title=The theory of electronic semi-conductors. - II |journal=Proceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character |language=en |volume=134 |issue=823 |pages=277–287 |doi=10.1098/rspa.1931.0196 |bibcode=1931RSPSA.134..277W |issn=0950-1207 |last1=Wilson |first1=A. H. |doi-access=free }} this band structure interpretation was based upon a single-electron approach with the Fermi level in the band gap as illustrated in the Figure, not including a complete picture of the many-body problem where both exchange and correlation terms can matter, as well as relativistic effects such as spin-orbit coupling. A key addition by Mott and Rudolf Peierls was that these could not be ignored.{{Cite journal |last1=Mott |first1=N F |last2=Peierls |first2=R |date=1937 |title=Discussion of the paper by de Boer and Verwey |url=https://iopscience.iop.org/article/10.1088/0959-5309/49/4S/308 |journal=Proceedings of the Physical Society |volume=49 |issue=4S |pages=72–73 |doi=10.1088/0959-5309/49/4S/308 |bibcode=1937PPS....49...72M |issn=0959-5309}} For instance, nickel oxide would be a metal if a single-electron approach was used, but in fact has quite a large band gap.{{Cite journal |last1=Boer |first1=J H de |last2=Verwey |first2=E J W |date=1937 |title=Semi-conductors with partially and with completely filled 3 d -lattice bands |url=https://iopscience.iop.org/article/10.1088/0959-5309/49/4S/307 |journal=Proceedings of the Physical Society |volume=49 |issue=4S |pages=59–71 |doi=10.1088/0959-5309/49/4S/307 |bibcode=1937PPS....49...59B |issn=0959-5309}} As of 2024 it is more common to use an approach based upon density functional theory where the many-body terms are included.{{Cite web |last=Burke |first=Kieron |date=2007 |title=The ABC of DFT |url=https://dft.uci.edu/doc/g1.pdf}}{{Cite book |last1=Gross |first1=Eberhard K. U. |url=https://books.google.com/books?id=aG4ECAAAQBAJ&q=density+functional+theory |title=Density Functional Theory |last2=Dreizler |first2=Reiner M. |date=2013 |publisher=Springer Science & Business Media |isbn=978-1-4757-9975-0 |language=en}} Rather than single electrons, the filling involves quasiparticles called orbitals, which are the single-particle like solutions for a system with hundreds to thousands of electrons. Although accurate calculations remain a challenge, reasonable results are now available in many cases.{{Cite journal |last1=Ferreira |first1=Luiz G. |last2=Marques |first2=Marcelo |last3=Teles |first3=Lara K. |date=2008 |title=Approximation to density functional theory for the calculation of band gaps of semiconductors |url=https://link.aps.org/doi/10.1103/PhysRevB.78.125116 |journal=Physical Review B |language=en |volume=78 |issue=12 |page=125116 |doi=10.1103/PhysRevB.78.125116 |arxiv=0808.0729 |bibcode=2008PhRvB..78l5116F |issn=1098-0121}}{{Cite journal |last1=Tran |first1=Fabien |last2=Blaha |first2=Peter |date=2017 |title=Importance of the Kinetic Energy Density for Band Gap Calculations in Solids with Density Functional Theory |journal=The Journal of Physical Chemistry A |language=en |volume=121 |issue=17 |pages=3318–3325 |doi=10.1021/acs.jpca.7b02882 |issn=1089-5639 |pmc=5423078 |pmid=28402113|bibcode=2017JPCA..121.3318T }}

File:Room_temperature_electrical_resistivity_of_various_materials.jpg

It is also common to nuance somewhat the early definitions of Alan Herries Wilson and Mott. As discussed by both the chemist Peter Edwards and colleagues,{{Cite journal |last1=Edwards |first1=P. P. |last2=Lodge |first2=M. T. J. |last3=Hensel |first3=F. |last4=Redmer |first4=R. |date=2010 |title='… a metal conducts and a non-metal doesn't' |journal=Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences |language=en |volume=368 |issue=1914 |pages=941–965 |doi=10.1098/rsta.2009.0282 |issn=1364-503X |pmc=3263814 |pmid=20123742|bibcode=2010RSPTA.368..941E }} as well as Fumiko Yonezawa,{{Rp|pages=257–261}}it is also important in practice to consider the temperatures at which both metals and nonmetals are used. Yonezawa provides a general definition:{{Rp|page=260}}

:When a material 'conducts' and at the same time 'the temperature coefficient of the electric conductivity of that material is not positive under a certain environmental condition,' the material is metallic under that environmental condition. A material which does not satisfy these requirements is not metallic under that environmental condition.

Band structure definitions of metallicity are the most widely used, and apply both to single elements such as insulating boron{{Cite journal |last1=Ogitsu |first1=Tadashi |last2=Schwegler |first2=Eric |last3=Galli |first3=Giulia |date=2013 |title=β-Rhombohedral Boron: At the Crossroads of the Chemistry of Boron and the Physics of Frustration |url=https://pubs.acs.org/doi/10.1021/cr300356t |journal=Chemical Reviews |language=en |volume=113 |issue=5 |pages=3425–3449 |doi=10.1021/cr300356t |pmid=23472640 |osti=1227014 |issn=0009-2665}} as well as compounds such as strontium titanate.{{Cite journal |last1=Reihl |first1=B. |last2=Bednorz |first2=J. G. |last3=Müller |first3=K. A. |last4=Jugnet |first4=Y. |last5=Landgren |first5=G. |last6=Morar |first6=J. F. |date=1984 |title=Electronic structure of strontium titanate |url=https://link.aps.org/doi/10.1103/PhysRevB.30.803 |journal=Physical Review B |language=en |volume=30 |issue=2 |pages=803–806 |doi=10.1103/PhysRevB.30.803 |bibcode=1984PhRvB..30..803R |issn=0163-1829}} (There are many compounds which have states at the Fermi level and are metallic, for instance titanium nitride.{{Cite journal |last1=Höchst |first1=H. |last2=Bringans |first2=R. D. |last3=Steiner |first3=P. |last4=Wolf |first4=Th. |date=1982 |title=Photoemission study of the electronic structure of stoichiometric and substoichiometric TiN and ZrN |url=https://link.aps.org/doi/10.1103/PhysRevB.25.7183 |journal=Physical Review B |language=en |volume=25 |issue=12 |pages=7183–7191 |doi=10.1103/PhysRevB.25.7183 |bibcode=1982PhRvB..25.7183H |issn=0163-1829}}) There are many experimental methods of checking for nonmetals by measuring the band gap, or by ab-initio quantum mechanical calculations.{{Cite journal |last1=Kim |first1=Sangtae |last2=Lee |first2=Miso |last3=Hong |first3=Changho |last4=Yoon |first4=Youngchae |last5=An |first5=Hyungmin |last6=Lee |first6=Dongheon |last7=Jeong |first7=Wonseok |last8=Yoo |first8=Dongsun |last9=Kang |first9=Youngho |last10=Youn |first10=Yong |last11=Han |first11=Seungwu |date=2020 |title=A band-gap database for semiconducting inorganic materials calculated with hybrid functional |journal=Scientific Data |language=en |volume=7 |issue=1 |page=387 |doi=10.1038/s41597-020-00723-8 |issn=2052-4463 |pmc=7658987 |pmid=33177500|bibcode=2020NatSD...7..387K }}

File:WomanFactory1940s.jpg

An alternative in metallurgy is to consider various malleable alloys such as steel, aluminium alloys and similar as metals, and other materials as nonmetals;{{Cite book |last=Cottrell |first=Alan |title=An introduction to metallurgy: SI units |date=1985 |publisher=Arnold |isbn=978-0-7131-2510-8 |edition=2. ed., repr |location=London}} fabricating metals is termed metalworking,{{Cite book |title=Materials and processes in manufacturing |date=2003 |publisher=Wiley |isbn=978-0-471-65653-1 |editor-last=DeGarmo |editor-first=E. Paul |edition=9th |location=Hoboken, N.J}} but there is no corresponding term for nonmetals. A loose definition such as this is often the common usage, but can also be inaccurate. For instance, in this usage plastics are nonmetals, but in fact there are (electrically) conducting polymers{{Cite journal |last1=Waltman |first1=R. J. |last2=Bargon |first2=J. |date=1986 |title=Electrically conducting polymers: a review of the electropolymerization reaction, of the effects of chemical structure on polymer film properties, and of applications towards technology |url=http://www.nrcresearchpress.com/doi/10.1139/v86-015 |journal=Canadian Journal of Chemistry |language=en |volume=64 |issue=1 |pages=76–95 |doi=10.1139/v86-015 |bibcode=1986CaJCh..64...76W |issn=0008-4042}}{{Cite journal |last1=Das |first1=Tapan K. |last2=Prusty |first2=Smita |date=2012 |title=Review on Conducting Polymers and Their Applications |url=http://www.tandfonline.com/doi/abs/10.1080/03602559.2012.710697 |journal=Polymer-Plastics Technology and Engineering |language=en |volume=51 |issue=14 |pages=1487–1500 |doi=10.1080/03602559.2012.710697 |issn=0360-2559}} which should formally be described as metals. Similar, but slightly more complex, many materials which are (nonmetal) semiconductors behave like metals when they contain a high concentration of dopants, being called degenerate semiconductors.{{Cite journal |last=Wolff |first=P. A. |date=1962 |title=Theory of the Band Structure of Very Degenerate Semiconductors |url=https://link.aps.org/doi/10.1103/PhysRev.126.405 |journal=Physical Review |language=en |volume=126 |issue=2 |pages=405–412 |doi=10.1103/PhysRev.126.405 |bibcode=1962PhRv..126..405W |issn=0031-899X}} A general introduction to much of this can be found in the 2017 book by Fumiko Yonezawa{{Rp|location=Chpt 1}}

{{See also|Properties of metals, metalloids and nonmetals}}

File:Simple_Periodic_Table_Chart-en.svg

The term nonmetal (chemistry) is also used for those elements which are not metallic in their normal ground state; compounds are sometimes excluded from consideration. Some textbooks use the term nonmetallic elements such as the Chemistry of the Non-Metals by Ralf Steudel,{{Cite book |last=Steudel |first=Ralf |url=https://www.degruyter.com/document/doi/10.1515/9783110578065/html |title=Chemistry of the Non-Metals: Syntheses - Structures - Bonding - Applications |date=2020 |publisher=De Gruyter |isbn=978-3-11-057806-5 |pages=4 |doi=10.1515/9783110578065}}{{Rp|page=4}} which also uses the general definition in terms of conduction and the Fermi level.{{Rp|page=154}} The approach based upon the elements is often used in teaching to help students understand the periodic table of elements,{{Cite web |date=2015 |title=1.8: Introduction to the Periodic Table |url=https://chem.libretexts.org/Bookshelves/General_Chemistry/Book%3A_General_Chemistry%3A_Principles_Patterns_and_Applications_(Averill)/01%3A_Introduction_to_Chemistry/1.08%3A_Introduction_to_the_Periodic_Table |access-date=2024-06-16 |website=Chemistry LibreTexts |language=en}} although it is a teaching oversimplification.{{Cite web |last=Worstall |first=Tim |date=2015 |title='The Scientific Method' Is A Myth, Long Live The Scientific Method |website=Forbes |url=http://www.forbes.com/sites/chadorzel/2015/11/03/the-scientific-method-is-a-myth-long-live-the-scientific-method/ |access-date=2024-06-27 |archive-url=https://web.archive.org/web/20151112005555/http://www.forbes.com/sites/chadorzel/2015/11/03/the-scientific-method-is-a-myth-long-live-the-scientific-method/ |archive-date=2015-11-12 }}{{Cite web |last=Worstall |first=Tim |date=2015 |title=To Prove Econ 101 Is Wrong You Do Need To Understand Econ 101 |url=https://www.forbes.com/sites/timworstall/2015/11/25/to-prove-econ-101-is-wrong-you-do-need-to-understand-econ-101/ |access-date=2024-06-27 |website=Forbes |language=en}} Those elements towards the top right of the periodic table are nonmetals, those towards the center (transition metal and lanthanide) and the left are metallic. An intermediate designation metalloid is used for some elements.

The term is sometimes also used when describing dopants of specific elements types in compounds, alloys or combinations of materials, using the periodic table classification. For instance metalloids are often used in high-temperature alloys,{{Cite journal |last=Perepezko |first=John H. |date=2009 |title=The Hotter the Engine, the Better |url=https://www.science.org/doi/10.1126/science.1179327 |journal=Science |language=en |volume=326 |issue=5956 |pages=1068–1069 |doi=10.1126/science.1179327 |pmid=19965415 |bibcode=2009Sci...326.1068P |issn=0036-8075}} and nonmetals in precipitation hardening in steels and other alloys.{{Cite journal |last=Ardell |first=A. J. |date=1985 |title=Precipitation hardening |url=https://link.springer.com/10.1007/BF02670416 |journal=Metallurgical Transactions A |language=en |volume=16 |issue=12 |pages=2131–2165 |doi=10.1007/BF02670416 |bibcode=1985MTA....16.2131A |issn=0360-2133}} Here the description implicitly includes information on whether the dopants tend to be electron acceptors that lead to covalently bonded compounds rather than metallic bonding or electron acceptors.

Image:Fraunhofer lines.svg

{{Main|Metallicity}}

A quite different approach is used in astronomy where the term metallicity is used for all elements heavier than helium, so the only nonmetals are hydrogen and helium. This is a historical anomaly. In 1802, William Hyde WollastonMelvyn C. Usselman: [http://www.britannica.com/EBchecked/topic/646649/William-Hyde-Wollaston William Hyde Wollaston] Encyclopædia Britannica, retrieved 31 March 2013 noted the appearance of a number of dark features in the solar spectrum.William Hyde Wollaston (1802) [http://rstl.royalsocietypublishing.org/content/92/365.full.pdf+html "A method of examining refractive and dispersive powers, by prismatic reflection,"] Philosophical Transactions of the Royal Society, 92: 365–380; see especially p. 378. In 1814, Joseph von Fraunhofer independently rediscovered the lines and began to systematically study and measure their wavelengths, and they are now called Fraunhofer lines. He mapped over 570 lines, designating the most prominent with the letters A through K and weaker lines with other letters.{{cite book|last=Hearnshaw|first=J.B.|title=The analysis of starlight|date=1986|publisher=Cambridge University Press|location=Cambridge|isbn=978-0-521-39916-6|page=27}}Joseph Fraunhofer (1814 - 1815) [https://books.google.com/books?id=2-AAAAAAYAAJ&pg=PA203 "Bestimmung des Brechungs- und des Farben-Zerstreuungs - Vermögens verschiedener Glasarten, in Bezug auf die Vervollkommnung achromatischer Fernröhre"] (Determination of the refractive and color-dispersing power of different types of glass, in relation to the improvement of achromatic telescopes), Denkschriften der Königlichen Akademie der Wissenschaften zu München (Memoirs of the Royal Academy of Sciences in Munich), 5: 193–226; see especially pages 202–205 and the plate following page 226.{{Cite book

| last1 = Jenkins | first1 = Francis A.

| last2 = White | first2 = Harvey E.

| title = Fundamentals of Optics

| url = https://archive.org/details/fundamentalsopti00jenk | url-access = limited | edition = 4th

| publisher = McGraw-Hill

| date = 1981

| page = [https://archive.org/details/fundamentalsopti00jenk/page/n37 18]

| isbn = 978-0-07-256191-3

}}

About 45 years later, Gustav Kirchhoff and Robert BunsenSee:

• Gustav Kirchhoff (1859) [https://books.google.com/books?id=CMgAAAAAYAAJ&pg=PA662"Ueber die Fraunhofer'schen Linien"] (On Fraunhofer's lines), Monatsbericht der Königlichen Preussische Akademie der Wissenschaften zu Berlin (Monthly report of the Royal Prussian Academy of Sciences in Berlin), 662–665.
• Gustav Kirchhoff (1859) [https://books.google.com/books?id=uksDAAAAYAAJ&pg=RA1-PA251 "Ueber das Sonnenspektrum"] (On the sun's spectrum), Verhandlungen des naturhistorisch-medizinischen Vereins zu Heidelberg (Proceedings of the Natural History / Medical Association in Heidelberg), 1 (7) : 251–255. noticed that several Fraunhofer lines coincide with characteristic emission lines identifies in the spectra of heated chemical elements.{{cite journal

|author= G. Kirchhoff

|title=Ueber die Fraunhofer'schen Linien

|journal=Annalen der Physik

|volume=185 |issue=1 |pages=148–150 |date=1860

|doi=10.1002/andp.18601850115|bibcode = 1860AnP...185..148K |url=https://zenodo.org/record/1423666

}} They inferred that dark lines in the solar spectrum are caused by absorption by chemical elements in the solar atmosphere.{{cite journal

|author= G. Kirchhoff

|title=Ueber das Verhältniss zwischen dem Emissionsvermögen und dem Absorptionsvermögen der Körper für Wärme und Licht

|trans-title=On the relation between the emissive power and the absorptive power of bodies towards heat and light

|journal=Annalen der Physik

|volume=185 |issue=2 |pages=275–301 |date=1860

|doi=10.1002/andp.18601850205|bibcode = 1860AnP...185..275K |url=https://zenodo.org/record/1423668|doi-access=free}} Their observations{{Cite web |title=Kirchhoff and Bunsen on Spectroscopy |url=https://www.chemteam.info/Chem-History/Kirchhoff-Bunsen-1860.html |access-date=2024-07-02 |website=www.chemteam.info}} were in the visible range where the strongest lines come from metals such as Na, K, Fe.{{Cite web |title=Spectrum analysis in its aqplication to terrestrial substances and the physical constitution of the heavenly bodies : familiarly explained / by H. Schellen ... |url=https://hdl.handle.net/2027/hvd.hn3317?urlappend=%3Bseq=211 |access-date=2024-07-02 |website=HathiTrust | hdl=2027/hvd.hn3317?urlappend=%3Bseq=211 |language=en}} In the early work on the chemical composition of the sun the only elements that were detected in spectra were hydrogen and various metals,{{Cite book |last=Meadows |first=A. J. (Arthur Jack) |url=http://archive.org/details/earlysolarphysic0000mead |title=Early solar physics |date=1970 |publisher=Oxford, New York, Pergamon Press |others=Internet Archive |isbn=978-0-08-006653-0}}{{Rp|pages=23–24}} with the term metallic frequently used when describing them.{{Rp|location=Part 2}} In contemporary usage all the extra elements beyond just hydrogen and helium are termed metallic.

The astrophysicst Carlos Jaschek, and the stellar astronomer and spectroscopist Mercedes Jaschek, in their book The Classification of Stars, observed that:{{cite book |last1=Jaschek |first1= C|last2=Jascheck |first2=M | date= 1990|title= The Classification of Stars|location=Cambridge |publisher=Cambridge University Press |page=22 |isbn=978-0-521-26773-1}}

:Stellar interior specialists use 'metals' to designate any element other than hydrogen and helium, and in consequence ‘metal abundance’ implies all elements other than the first two. For spectroscopists this is very misleading, because they use the word in the chemical sense. On the other hand photometrists, who observe combined effects of all lines (i.e. without distinguishing the different elements) often use this word 'metal abundance', in which case it may also include the effect of the hydrogen lines.

{{Main|Metal–insulator transition}}

File:VO2-MI.png.{{Cite journal |last1=Shao |first1=Zewei |last2=Cao |first2=Xun |last3=Luo |first3=Hongjie |last4=Jin |first4=Ping |date=2018 |title=Recent progress in the phase-transition mechanism and modulation of vanadium dioxide materials |journal=NPG Asia Materials |language=en |volume=10 |issue=7 |pages=581–605 |doi=10.1038/s41427-018-0061-2 |bibcode=2018npgAM..10..581S |issn=1884-4049|doi-access=free }}]]

There are many cases where an element or compound is metallic under certain circumstances, but a nonmetal in others. One example is metallic hydrogen which forms under very high pressures.{{Cite journal |last1=Wigner |first1=E. |last2=Huntington |first2=H. B. |date=1935 |title=On the Possibility of a Metallic Modification of Hydrogen |url=https://pubs.aip.org/jcp/article/3/12/764/203469/On-the-Possibility-of-a-Metallic-Modification-of |journal=The Journal of Chemical Physics |language=en |volume=3 |issue=12 |pages=764–770 |doi=10.1063/1.1749590 |bibcode=1935JChPh...3..764W |issn=0021-9606}} There are many other cases as discussed by Mott,{{Cite journal |last=Mott |first=N. F. |date=1968 |title=Metal-Insulator Transition |url=https://link.aps.org/doi/10.1103/RevModPhys.40.677 |journal=Reviews of Modern Physics |language=en |volume=40 |issue=4 |pages=677–683 |doi=10.1103/RevModPhys.40.677 |bibcode=1968RvMP...40..677M |issn=0034-6861}} Inada et al{{Cite journal |last1=Imada |first1=Masatoshi |last2=Fujimori |first2=Atsushi |last3=Tokura |first3=Yoshinori |date=1998 |title=Metal-insulator transitions |url=https://link.aps.org/doi/10.1103/RevModPhys.70.1039 |journal=Reviews of Modern Physics |language=en |volume=70 |issue=4 |pages=1039–1263 |doi=10.1103/RevModPhys.70.1039 |bibcode=1998RvMP...70.1039I |issn=0034-6861}} and more recently by Yonezawa.

There can also be local transitions to a nonmetal, particularly in semiconductor devices. One example is a field-effect transistor where an electric field can lead to a region where there are no electrons at the Fermi energy (depletion zone).{{Cite journal |last=Kushwah |first=D. S. |date=1975 |title=Field Effect Transistors-A review of their growth and the state of the art |url=http://www.tandfonline.com/doi/full/10.1080/09747338.1975.11450118 |journal=IETE Journal of Education |language=en |volume=16 |issue=3 |pages=126–132 |doi=10.1080/09747338.1975.11450118 |issn=0974-7338}}{{Cite journal |last=Zhang |first=Shubo |date=2020 |title=Review of Modern Field Effect Transistor Technologies for Scaling |journal=Journal of Physics: Conference Series |volume=1617 |issue=1 |pages=012054 |doi=10.1088/1742-6596/1617/1/012054 |bibcode=2020JPhCS1617a2054Z |issn=1742-6588|doi-access=free }}

File:Capacitor schematic with dielectric.svg

Nonmetals have a wide range of properties, for instance the nonmetal diamond is the hardest known material, while the nonmetal molybdenum disulfide is a solid lubricants used in space.{{Cite journal |last1=Vazirisereshk |first1=Mohammad R. |last2=Martini |first2=Ashlie |last3=Strubbe |first3=David A. |last4=Baykara |first4=Mehmet Z. |date=2019 |title=Solid Lubrication with MoS2: A Review |journal=Lubricants |language=en |volume=7 |issue=7 |pages=57 |doi=10.3390/lubricants7070057 |doi-access=free |issn=2075-4442|arxiv=1906.05854 }} There are some properties specific to them not having electrons at the Fermi energy. The main ones, for which more details are available in the links are:{{Rp|location=Chpt 27-29}}{{Cite book |last=Griffiths |first=David J. |url=https://www.cambridge.org/highereducation/product/9781108333511/book |title=Introduction to Electrodynamics |date=2017 |publisher=Cambridge University Press |isbn=978-1-108-33351-1 |edition=4 |doi=10.1017/9781108333511.008}}

• Dielectric polarization,{{Cite web |date=2021 |title=Dielectric {{!}} Definition, Properties, & Polarization {{!}} Britannica |url=https://global.britannica.com/science/dielectric |archive-url=https://web.archive.org/web/20210427153917/https://global.britannica.com/science/dielectric |archive-date=2021-04-27 |access-date=2024-06-16}} approximately equivalent to alignment of local dipoles with an electric field, as in capacitors.
• Electrostriction,{{Cite web |title=Electrostriction {{!}} Piezoelectricity, Ferroelectricity, Magnetostriction {{!}} Britannica |url=https://www.britannica.com/science/electrostriction |access-date=2024-06-16 |website=www.britannica.com |language=en}} a change in volume due to an electric field, or more accurately polarization density.
• Flexoelectricity, where there is a coupling between strain gradients and polarization.{{Cite journal |last1=Zubko |first1=Pavlo |last2=Catalan |first2=Gustau |last3=Tagantsev |first3=Alexander K. |date=2013 |title=Flexoelectric Effect in Solids |url=https://www.annualreviews.org/doi/10.1146/annurev-matsci-071312-121634 |journal=Annual Review of Materials Research |language=en |volume=43 |issue=1 |pages=387–421 |doi=10.1146/annurev-matsci-071312-121634 |bibcode=2013AnRMS..43..387Z |hdl=10261/99362 |issn=1531-7331|hdl-access=free }} This plays a role in the generation of static electricity due to the triboelectric effect.{{Cite journal |last1=Mizzi |first1=C. A. |last2=Lin |first2=A. Y. W. |last3=Marks |first3=L. D. |date=2019 |title=Does Flexoelectricity Drive Triboelectricity? |url=https://link.aps.org/doi/10.1103/PhysRevLett.123.116103 |journal=Physical Review Letters |language=en |volume=123 |issue=11 |page=116103 |doi=10.1103/PhysRevLett.123.116103 |pmid=31573269 |arxiv=1904.10383 |bibcode=2019PhRvL.123k6103M |issn=0031-9007}}
• Piezoelectricity, a coupling between polarization and linear strains.
• A decreased resistance with temperature, due to having more carriers (via Fermi–Dirac statistics) available in partially occupied higher energy bands{{Citation |last1=Kasap |first1=Safa |title=Electrical Conduction in Metals and Semiconductors |date=2017 |work=Springer Handbook of Electronic and Photonic Materials |pages=1 |editor-last=Kasap |editor-first=Safa |url=https://doi.org/10.1007/978-3-319-48933-9_2 |access-date=2024-06-30 |place=Cham |publisher=Springer International Publishing |language=en |doi=10.1007/978-3-319-48933-9_2 |isbn=978-3-319-48933-9 |last2=Koughia |first2=Cyril |last3=Ruda |first3=Harry E. |editor2-last=Capper |editor2-first=Peter}}
• Increased conductivity when illuminated with light or ultraviolet radiation, called photoconductivity. This is similar to the effect of temperature, but with the photons exciting electrons into partially occupied states.{{Cite book |last=Rogers |first=Alan |url=http://dx.doi.org/10.1201/9781315222042 |title=Essentials of Photonics |publisher=CRC Press |year=2009 |isbn=9781315222042 |edition=2nd |doi=10.1201/9781315222042}}
• Transmit electric fields as in the capacitor figure above; in a metal there is electric-field screening that prevents this beyond very small distances, see Classical Electrodynamics.{{Cite book |last=Jackson |first=John David |title=Classical electrodynamics |date=2009 |publisher=Wiley |isbn=978-0-471-30932-1 |edition=3rd |location=Hoboken, NY}}

• {{Annotated link|Abundance of the chemical elements}}
• {{Annotated link|Charge-transfer insulators}}
• {{Annotated link|Charge transport mechanisms}}
• {{Annotated link|Dielectric strength}}
• {{Annotated link|Electrical conduction}}
• {{Annotated link|Kondo insulator}}
• {{Annotated link|List of data references for chemical elements}}
• {{Annotated link|List of manufacturing processes}}
• {{Annotated link|List of materials properties}}
• {{Annotated link|List of states of matter}}
• {{Annotated link|Metallicity distribution function}}
• {{Annotated link|Mott insulator}}
• {{Annotated link|Superconductor-insulator transition}}
• {{Annotated link|Topological insulator}}

{{Reflist}}

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Category:Condensed matter physics

Category:Materials science

Category:Metallurgy

Category:Nonmetals

Category:Periodic table

Category:Solid-state chemistry