Methylphosphonyl dichloride

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| ImageFile1 = Methylphosphonic dichloride-2D-by-AHRLS-2012.png

| ImageSize1 = 150px

| ImageFile2 = Methylphosphonic-dichloride-3D-balls-by-AHRLS-2012.png

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| PIN = Methylphosphonic dichloride

| OtherNames = Methanephosphonic dichloride
Methanephosphonic acid dichloride
Methylphosphonyl dichloride
Dichloro

|Section1={{Chembox Identifiers

| CASNo = 676-97-1

| PubChem = 12671

| ChemSpiderID = 12150

| EINECS = 211-634-4

| UNNumber = 9206

| SMILES = CP(=O)(Cl)Cl

| InChI = 1/CH3Cl2OP/c1-5(2,3)4/h1H3

| InChIKey = SCLFRABIDYGTAZ-UHFFFAOYAS

| StdInChI = 1S/CH3Cl2OP/c1-5(2,3)4/h1H3

| StdInChIKey = SCLFRABIDYGTAZ-UHFFFAOYSA-N

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|Section2={{Chembox Properties

| C=1 | H=3 | Cl=2 | O=1 | P=1

| Appearance = White crystalline solid

| Density = 1.468 g/mL at 20 °C

| MeltingPtC = 28 to 34

| MeltingPt_notes =

| BoilingPtC = 163

| Solubility = Reacts with water

| SolubleOther = Ether, THF

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|Section3={{Chembox Hazards

| MainHazards = Very toxic, reacts with water

| FlashPt = >110 °C

| LD50 = 26 ppm/4h by inhalation (rat)

| GHSPictograms = {{GHS05}}{{GHS06}}

| GHSSignalWord = Danger

| HPhrases = {{H-phrases|314|330}}

| PPhrases = {{P-phrases|260|264|271|280|284|301+330+331|303+361+353|304+340|305+351+338|310|320|321|363|403+233|405|501}}

| AutoignitionPt =

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Methylphosphonyl dichloride (DC) or dichloro is an organophosphorus compound. It has commercial application in oligonucleotide synthesis,{{list journal|work=Aldrich Handbook & Catalog of Fine Chemicals|location=Milwaukee, WI|publisher=Aldrich Chemical Company|date=1994}} p. 871. As [https://pubchem.ncbi.nlm.nih.gov/source/hsdb/6329#section=Manufacturing-Use-Information cited] in HSDB. but is most notable as being a precursor to several chemical weapons agents. It is a white crystalline solid that melts slightly above room temperature.{{Cite web |date=June 26, 2020 |title=SAFETY DATA SHEET Methylphosphonic dichloride |url=https://www.sigmaaldrich.com/US/en/sds/aldrich/228052 |access-date=April 27, 2022 |website=SAFETY DATA SHEET Methylphosphonic dichloride |publisher=MilliporeSigma}}

Synthesis and reactions

Methylphosphonyl dichloride is produced by oxidation of methyldichlorophosphine, with sulfuryl chloride:Svara, J.; Weferling, N.; Hofmann, T. "Phosphorus Compounds, Organic," In 'Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2008. {{doi|10.1002/14356007.a19_545.pub2}}.

:CH3PCl2 + SO2Cl2 → CH3P(O)Cl2 + SOCl2

It can also be produced from a range of methylphosphonates (e.g. dimethyl methylphosphonate) via chlorination with thionyl chloride. Various amines catalyse this process.{{cite journal|last=Maier|first=Ludwig|title=Organic Phosphorus Compounds 90.l A Convenient, One-Step Synthesis of Alkyl- and Arylphosphonyl Dichlorides|journal=Phosphorus, Sulfur, and Silicon and the Related Elements|year=1990|volume=47|issue=3–4|pages=465–470|doi=10.1080/10426509008038002}}

With hydrogen fluoride or sodium fluoride, it can be used to produce methylphosphonyl difluoride. With alcohols, it converts to the dialkoxide:{{cite journal |doi=10.15227/orgsyn.073.0152|title=Bis(Trifluoroethyl) (carboethoxymethyl)phosphonate|journal=Organic Syntheses|year=1996|volume=73|page=152|author=Carl Patois, Philippe Savignac, Elie About-Jaudet, Noël Collignon

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:CH3P(O)Cl2 + 2{{nbsp}}HOR → CH3P(O)(OR)2 + {{nbsp}}HCl

Safety

Methylphosphonyl dichloride is very toxic and reacts vigorously with water to release hydrochloric acid. It is also listed under Schedule 2 of the Chemical Weapons Convention as it is used in the production of organophosphorus nerve agents such as sarin and soman.

References