Naphtha

File:Camp fuel.jpg, is a common naphtha-based fuel used in many lanterns and stoves.]]

The word naphtha comes from Latin through Ancient Greek ({{Lang|grc|νάφθα}}), derived from Middle Persian naft ("wet", "naphtha"),{{cite web|url=http://agiw.fak1.tu-berlin.de/Auditorium/FAByzIsl/SO8/PersErb.htm |archive-url=https://web.archive.org/web/20110811054725/http://agiw.fak1.tu-berlin.de/Auditorium/FAByzIsl/SO8/PersErb.htm |archive-date=2011-08-11 |title= Persisches Erbe im Griechischen, Lateinischen, Arabischen, Türkischen und in verschiedenen heutigen europäischen Sprachen (Persian Heritage in Greek, Latin, Arabic, Turkic and Various Modern European Languages)| author=Christian Gizewski (Technische Universität Berlin)|publisher=Technische Universität Berlin| access-date = 2010-02-28}}{{cite book|author=David Neil MacKenzie|title=A Concise Pahlavi Dictionary|year=1971|publisher=Oxford University Press|isbn=978-1-934768-59-4|page=57}} the latter meaning of which was an assimilation from the Akkadian 𒉌𒆳𒊏 {{Transliteration|akk|napṭu}} (see Semitic relatives such as Arabic {{lang|ar|نَفْط}} {{Transliteration|ar|nafṭ}} ["petroleum"], Syriac {{Lang|syc|ܢܰܦܬܳܐ}} naftā, and Hebrew {{Lang|he|נֵפְט}} {{Transliteration|he|neft}}, meaning petroleum).{{cite web |title=ENGLISH i. Persian Elements in English |url=http://www.iranicaonline.org/articles/english |website=www.iranicaonline.org |publisher=Encyclopaedia Iranica |access-date=1 September 2018 |language=en}}

The book of II Maccabees (2nd cent. BC) tells how a "thick water" was put on a sacrifice at the time of Nehemiah and when the sun shone it caught fire. It adds that "those around Nehemiah termed this 'Nephthar', which means Purification, but it is called Nephthaei by the many."{{bibleverse|2|Maccabees|1:36}} This same substance is mentioned in the Mishnah as one of the generally permitted oils for lamps on Shabbat, although Rabbi Tarfon permits only olive oil (Mishnah Shabbat 2).

In Ancient Greek, it was used to refer to any sort of petroleum or pitch. The Greek word {{lang|el|νάφθα}} designates one of the materials used to stoke the fiery furnace in the Song of the Three Children (possibly 1st or 2nd cent. BC). The translation of Charles Brenton renders this as "rosin".

The naphtha of antiquity is explained to be a "highly flammable light fraction of petroleum, an extremely volatile, strong-smelling, gaseous liquid, common in oil deposits of the Near East"; it was a chief ingredient in incendiary devices described by Latin authors of the Roman period.{{cite book|last=Mayor |first=Adrienne |author-link=Adrienne Mayor |title=Greek Fire, Poison Arrows, and Scorpion Bombs: Biological and Chemical Warfare in the Ancient World |location=Woodstock, NY |publisher=Overlook Duckworth |date=2009 |url=https://books.google.com/books?id=QysqAQAAIAAJ&q=naphtha |page=227 |isbn=0715638521}} [https://books.google.com/books?id=M_v57ETfcvQC&lpg=PP1 digital copy]

Since the 19th century, solvent naphtha has denoted a product (xylene or trimethylbenzenes) derived by fractional distillation from petroleum;{{cite book|last=Daunicht |first=Hubert K. |author-link= |title=Greek Fire, Poison Arrows, and Scorpion Bombs: Biological and Chemical Warfare in the Ancient World |location=Woodstock, NY |publisher=Overlook Duckworth |date=2009 |url=https://books.google.com/books?id=84FfBiU_gi4C&pg=PA307 |page=307 |isbn=9780715638521}} these mineral spirits, also known as "Stoddard Solvent", were originally the main active ingredient in Fels Naptha laundry soap.{{cite web|url=http://digitalhistory.hsp.org/pafrm/org/fels-company|title=Fels & Company |website=Hsp.org|accessdate=2016-09-28}} The naphtha in Fels Naptha was later removed as a cancer risk.{{Cite web |title=Portugrocer: 1942 |url=https://www.shorpy.com/node/27017 |access-date=2023-05-03 |website=Shorpy.com |language=en}}

The usage of the term "naphtha" during this time typically implies petroleum naphtha, a colorless liquid with a similar odor to gasoline. However, "coal tar naphtha", a reddish brown liquid that is a mixture of hydrocarbons (toluene, xylene, and cumene, etc.), could also be intended in some contexts.{{cite book|last=Sittig |first=Marshall |author-link= |editor1-last=Greene |editor1-first=Stanley A. |editor1-link= |editor2-last=Pohanish|editor2-first=Richard P. |editor2-link=|chapter=Naphtha |title=Sittig's Handbook of Pesticides and Agricultural Chemicals |location= |publisher=William Andrew |date=2013 |chapter-url=https://books.google.com/books?id=hAoKEHpyu6wC&pg=PA636 |page=636 |isbn=9780815519034}}

In older usage,{{when|date=January 2022}} "naphtha" simply meant crude oil, but this usage is now obsolete in English. There are a number of cognates to the word in different modern languages, typically signifying "petroleum" or "crude oil".

The Ukrainian and Belarusian word нафта (nafta), Lithuanian, Latvian and Estonian "nafta" and the Persian {{Transliteration|fa|naft}} ({{lang|fa|نفت}}) mean "crude oil". The Russian word {{lang|ru|нефть}} (neft') means "crude oil", but нафта (nafta) is a synonym of ligroin. Also, in Albania, Bosnia and Herzegovina, Bulgaria, Croatia, Finland, Italy, Serbia, Slovenia, Macedonia nafta (нафта in Cyrillic) is colloquially used to indicate diesel fuel and crude oil. In the Czech Republic and Slovakia, nafta was historically used for both diesel fuel and crude oil, but its use for crude oil is now obsolete{{cite web|url=http://slovnik.juls.savba.sk/?w=nafta&s=exact&c=k045&d=kssj4&d=psp&d=scs&d=sss&d=peciar&d=hssjV&d=ma&d=obce&d=priezviska&d=un&ie=utf-8&oe=utf-8 |title=Slovenské slovníky |publisher=Slovnik.juls.savba.sk |access-date=2015-10-26}} and it generally indicates diesel fuel. In Bulgarian, nafta means diesel fuel, while neft, as well as petrol (петрол in Cyrillic), means crude oil. Nafta is also used in everyday parlance in Argentina, Paraguay and Uruguay to refer to gasoline/petrol.{{cite book|author=Pedro Mairal|title=El año del desierto|url=https://books.google.com/books?id=dQ56G7us0-4C&pg=PA71|year=2012|publisher=Stockcero, Inc|isbn=978-1-934768-59-4|pages=71–}} In Poland, the word {{wikt-lang|pl|nafta|}} means kerosene,{{cite book|author=Andrey Taranov|title=Polish vocabulary for English speakers - 7000 words|url=https://books.google.com/books?id=kR-kAQAAQBAJ&pg=PA98|date=23 October 2013|publisher=BoD - Books on Demand|isbn=978-1-78071-417-2|pages=98–}} and colloquially crude oil (technical name for crude oil is {{wikt-lang|pl|ropa naftowa|}}, also colloquially used for diesel fuel as {{wikt-lang|pl|ropa|}}). In Flemish, the word naft(e) is used colloquially for gasoline.{{cite book|author=Michael G. Clyne|title=Pluricentric Languages: Differing Norms in Different Nations|url=https://books.google.com/books?id=wawGFWNuHiwC&pg=PA85|year=1992|publisher=Walter de Gruyter|isbn=978-3-11-012855-0|pages=85–}}

Various qualifiers have been added to the term "naphtha" by different sources in an effort to make it more specific:

One source{{cite conference | first = Rune | last = Prestvic |author2=Kjell Moljord |author3=Knut Grande |author4=Anders Holmen | title = Compositional analysis of naphtha and reformate | book-title = Catalytic naphtha reforming | pages = 2 | publisher = CRC Press | year = 2004 | location = USA | isbn = 9780203913505 | url = https://books.google.com/books?id=Bjs7d2xnm1UC&pg=PA60 | access-date = 2010-02-03}} distinguishes by boiling point:

{{blockquote|Light naphtha is the fraction boiling between 30 °C and 90 °C and consists of molecules with 5–6 carbon atoms. Heavy naphtha boils between 90 °C and 200 °C and consists of molecules with 6–12 carbon atoms.}}

Another source"Chemistry of Hazardous Materials, Third Edition", Meyer, E., Prentice Hall, 1998, page 458. which differentiates light and heavy comments on the hydrocarbon structure, but offers a less precise dividing line:

{{blockquote|Light [is] a mixture consisting mainly of straight-chained and cyclic aliphatic hydrocarbons having from five to six carbon atoms per molecule. Heavy [is] a mixture consisting mainly of straight-chained and cyclic aliphatic hydrocarbons having from seven to nine carbon atoms per molecule.}}

Both of these are useful definitions, but they are incompatible with one another and the latter does not provide for mixes containing both six and seven carbon atoms per molecule. These terms are also sufficiently broad that they are not widely useful.

"Petroleum naphtha", which contains both heavy and light naphtha, typically constitutes 15-30% of crude oil by weight.

Naphtha is used to dilute heavy crude oil to reduce its viscosity and enable/facilitate transport; undiluted heavy crude cannot normally be transported by pipeline, and may also be difficult to pump onto oil tankers. Other common dilutants include natural-gas condensate and light crude. However, naphtha is a particularly efficient dilutant and can be recycled from diluted heavy crude after transport and processing.{{Cite book|last1=Glenat|first1=Philippe|last2=Heraud|first2=Jean-Philippe|last3=Gateau|first3=Patrick|last4=Henaut|first4=Isabelle|last5=Argillier|first5=J.-Francois|date=2005-01-01|title=Heavy Oil Dilution|url=https://www.onepetro.org/conference-paper/SPE-97763-MS|language=en|publisher=Society of Petroleum Engineers|doi=10.2118/97763-MS|isbn=9781613990056|s2cid=73605226 }}{{Cite web|url=https://www.researchgate.net/publication/286937181|title=Dilution of heavy crude oils for pipeline ransportation purposes: The asphaltene instability issue}}{{Cite web|url=https://www.worldoil.com/news/2019/1/29/diluting-venezuela-s-heavy-crude-just-got-harder|title=Diluting Venezuela's heavy crude just got harder|website=www.worldoil.com|date=29 January 2019 |access-date=2019-04-09}} The importance of oil dilutants has increased as global production of lighter crude oils has fallen and shifted to exploitation of heavier reserves.

Light naphtha is used as a fuel in some commercial applications. One notable example is wick-based cigarette lighters, such as the Zippo, which draw "lighter fluid"—naphtha—into a wick from a reservoir to be ignited using the flint and wheel.

It is also a fuel for camping stoves and oil lanterns, known as "white gas", where naphtha's low boiling point makes it easy to ignite. Naphtha is sometimes preferred over kerosene because it clogs fuel lines less. The outdoor equipment manufacturer MSR published a list of trade{{nbsp}}names and translations to help outdoor enthusiasts obtain the correct products in various countries.

{{cite book

| author = MSR

| title = Where do I get fuels in foreign countries and what other types of fuel can I use?

| date = 24 August 2020

| publisher = Mountain Safety Research (MSR)

| location = Seattle, Washington, USA

| url = https://www.msrgear.com/blog/wp-content/uploads/2020/08/Fuel-Tables-by-Country1.pdf

| access-date = 2021-08-27

}} Date from PDF metadata.

Naphtha was also historically used as a fuel in some small launch boats where steam technology was impractical; most were built to circumvent safety laws relating to traditional steam launches.{{cite book |last=Durant |first=Kenneth |title=The Naptha Launch |year=1976}}

As an internal combustion engine fuel, petroleum naphtha has seen very little use and suffers from lower efficiency and low octane ratings, typically 40 to 70 RON. It can be used to run unmodified diesel engines, though it has a longer ignition-delay than diesel. Naphtha tends to be noisy in combustion due to the high pressure rise rate. There is a possibility of using naphtha as a low-octane base fuel in an octane-on-demand concept, with the engine drawing a high-octane mix only when needed. Naptha benefits from lesser emissions in refinement: fuel energy losses from "well-to-tank" are 13%; lower than the 22% losses for petroleum.{{cite journal |last1=Park |first1=Wonah |title=Naphtha as a Fuel for Internal Combustion Engines |journal=International Journal of Automotive Technology |date=August 2021 |volume=22 |issue=4 |pages=1119–1133 |doi=10.1007/s12239-021-0100-9}}

Naphtha is a crucial component in the production of plastics.{{cite web|title=How Plastics are Made|url=https://plasticseurope.org/plastics-explained/how-plastics-are-made/|website=Plastics Europe|publisher=Association of Plastics Manufacturers|location=Brussels}}

The safety data sheets (SDSs) from various naphtha vendors indicate various hazards such as flammable mixture of hydrocarbons: flammability, carcinogenicity, skin and airway irritation, etc.

{{cite web

|url=http://hazard.com/msds/mf/baker/baker/files/p1696.htm

|title=Petroleum Ether

|publisher=Hazard.com

|date=1998-04-21

|access-date=2015-10-26

}}

{{cite web

|url=https://www.recochem.com/wp-content/uploads/2023/07/Shellite-NZ-v6.pdf

|title=Material Safety Data Sheet : Shellite

|publisher=Recochem.com

|access-date=2015-10-26

}}

{{cite web

|url=http://www.cooperbooth.com/datasheets/160606.pdf

|title=Material Safety Data Sheet : Ronsonol Lighter Fuel

|publisher=Cooperbooth.com

|access-date=2015-10-26

}}{{cite web

|url=http://www.nafaa.org/msds.html

|title=NAFAA

|publisher=NAFAA

|access-date=2015-10-26

|archive-url=https://web.archive.org/web/20160304091246/http://www.nafaa.org/msds.html

|archive-date=2016-03-04

|url-status=usurped

}}

Humans can be exposed to naphtha in the workplace by inhalation, ingestion, dermal contact, and eye contact. The US Occupational Safety and Health Administration (OSHA) has set the permissible exposure limit for naphtha in the workplace as 100 ppm (400 mg/m³) over an 8-hour workday. The US National Institute for Occupational Safety and Health (NIOSH) has set a recommended exposure limit (REL) of 100 ppm (400 mg/m³) over an 8-hour workday. At levels of 1000 ppm, which equates to 10 times the lower exposure limit, naphtha is immediately dangerous to life and health.

{{Cite web

|title = CDC - NIOSH Pocket Guide to Chemical Hazards - Naphtha (coal tar)

|url = https://www.cdc.gov/niosh/npg/npgd0438.html

|website = www.cdc.gov

|access-date = 2015-11-27}}

• Coleman fuel
• Fels-Naptha
• Fractional distillation
• Fluid catalytic cracking
• Greek fire
• Hydrocarbon
• Kerosene
• Mineral spirits
• Naphtha launch
• Oil refinery
• Petroleum distillation
• Petroleum naphtha
• Tar

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Category:Commodity chemicals

Category:Hydrocarbon solvents

Category:Petroleum products