Projection-valued measure#Application in quantum mechanics
{{Short description|Mathematical operator-value measure of interest in quantum mechanics and functional analysis}}
In mathematics, particularly in functional analysis, a projection-valued measure, or spectral measure, is a function defined on certain subsets of a fixed set and whose values are self-adjoint projections on a fixed Hilbert space.{{sfn | Conway | 2000 | p=41}} A projection-valued measure (PVM) is formally similar to a real-valued measure, except that its values are self-adjoint projections rather than real numbers. As in the case of ordinary measures, it is possible to integrate complex-valued functions with respect to a PVM; the result of such an integration is a linear operator on the given Hilbert space.
Projection-valued measures are used to express results in spectral theory, such as the important spectral theorem for self-adjoint operators, in which case the PVM is sometimes referred to as the spectral measure. The Borel functional calculus for self-adjoint operators is constructed using integrals with respect to PVMs. In quantum mechanics, PVMs are the mathematical description of projective measurements.{{clarify|reason=Is this a novel term? It's not defined in the linked article.|date=May 2015}} They are generalized by positive operator valued measures (POVMs) in the same sense that a mixed state or density matrix generalizes the notion of a pure state.
Definition
Let denote a separable complex Hilbert space and a measurable space consisting of a set and a Borel σ-algebra on . A projection-valued measure is a map from to the set of bounded self-adjoint operators on satisfying the following properties:{{sfn | Hall | 2013 | p=138}}{{sfn | Reed | Simon | 1980 | p=234}}
- is an orthogonal projection for all
- and , where is the empty set and the identity operator.
- If in are disjoint, then for all ,
::
- for all
The second and fourth property show that if
E_1 and are disjoint, i.e., , the images and are orthogonal to each other.
Let and its orthogonal complement denote the image and kernel, respectively, of . If is a closed subspace of then can be wrtitten as the orthogonal decomposition and is the unique identity operator on satisfying all four properties.{{sfn | Rudin | 1991 | p=308}}{{sfn | Hall | 2013 | p=541}}
For every and the projection-valued measure forms a complex-valued measure on defined as
:
with total variation at most .{{sfn | Conway | 2000 | p=42}} It reduces to a real-valued measure when
:
and a probability measure when is a unit vector.
Example Let be a Measure space#Important classes of measure spaces and, for all , let
:
\pi(E) : L^2(X) \to L^2 (X)
be defined as
:
i.e., as multiplication by the indicator function on L2(X). Then defines a projection-valued measure.{{sfn | Conway | 2000 | p=42}} For example, if , , and there is then the associated complex measure which takes a measurable function and gives the integral
:
Extensions of projection-valued measures
If {{pi}} is a projection-valued measure on a measurable space (X, M), then the map
:
\chi_E \mapsto \pi(E)
extends to a linear map on the vector space of step functions on X. In fact, it is easy to check that this map is a ring homomorphism. This map extends in a canonical way to all bounded complex-valued measurable functions on X, and we have the following.
{{math theorem|Theorem|For any bounded Borel function on , there exists a unique bounded operator such that
{{Citation |last=Kowalski|first=Emmanuel| year=2009|title=Spectral theory in Hilbert spaces| series = ETH Zürich lecture notes | url=https://people.math.ethz.ch/~kowalski/spectral-theory.pdf|page = 50}}{{sfn | Reed | Simon | 1980 | p=227,235}}
:
where is a finite Borel measure given by
:
Hence, is a finite measure space.}}
The theorem is also correct for unbounded measurable functions but then will be an unbounded linear operator on the Hilbert space .
This allows to define the Borel functional calculus for such operators and then pass to measurable functions via the Riesz–Markov–Kakutani representation theorem. That is, if is a measurable function, then a unique measure exists such that
:
= Spectral theorem =
{{see also|Self-adjoint operator#Spectral theorem}}
Let be a separable complex Hilbert space, be a bounded self-adjoint operator and the spectrum of . Then the spectral theorem says that there exists a unique projection-valued measure , defined on a Borel subset , such that{{sfn | Reed | Simon | 1980 | p=235}}
:
where the integral extends to an unbounded function when the spectrum of is unbounded.{{sfn | Hall | 2013 | p=205}}
= Direct integrals=
First we provide a general example of projection-valued measure based on direct integrals. Suppose (X, M, μ) is a measure space and let {Hx}x ∈ X be a μ-measurable family of separable Hilbert spaces. For every E ∈ M, let {{pi}}(E) be the operator of multiplication by 1E on the Hilbert space
:
Then {{pi}} is a projection-valued measure on (X, M).
Suppose {{pi}}, ρ are projection-valued measures on (X, M) with values in the projections of H, K. {{pi}}, ρ are unitarily equivalent if and only if there is a unitary operator U:H → K such that
:
for every E ∈ M.
Theorem. If (X, M) is a standard Borel space, then for every projection-valued measure {{pi}} on (X, M) taking values in the projections of a separable Hilbert space, there is a Borel measure μ and a μ-measurable family of Hilbert spaces {Hx}x ∈ X , such that {{pi}} is unitarily equivalent to multiplication by 1E on the Hilbert space
:
The measure class{{clarify|reason=What is a measure class? A measure up to measure-preserving equivalence? Should the measure be completed?|date=May 2015}} of μ and the measure equivalence class of the multiplicity function x → dim Hx completely characterize the projection-valued measure up to unitary equivalence.
A projection-valued measure {{pi}} is homogeneous of multiplicity n if and only if the multiplicity function has constant value n. Clearly,
Theorem. Any projection-valued measure {{pi}} taking values in the projections of a separable Hilbert space is an orthogonal direct sum of homogeneous projection-valued measures:
:
where
:
and
:
Application in quantum mechanics
{{see also|Expectation value (quantum mechanics)}}
In quantum mechanics, given a projection-valued measure of a measurable space to the space of continuous endomorphisms upon a Hilbert space ,
- the projective space of the Hilbert space is interpreted as the set of possible (normalizable) states of a quantum system,{{sfn | Ashtekar | Schilling | 1999 | pp=23–65}}
- the measurable space is the value space for some quantum property of the system (an "observable"),
- the projection-valued measure expresses the probability that the observable takes on various values.
A common choice for is the real line, but it may also be
- (for position or momentum in three dimensions ),
- a discrete set (for angular momentum, energy of a bound state, etc.),
- the 2-point set "true" and "false" for the truth-value of an arbitrary proposition about .
Let be a measurable subset of and a normalized vector quantum state in , so that its Hilbert norm is unitary, . The probability that the observable takes its value in , given the system in state , is
:
P_\pi(\varphi)(E) = \langle \varphi\mid\pi(E)(\varphi)\rangle = \langle \varphi\mid\pi(E)\mid\varphi\rangle.
We can parse this in two ways. First, for each fixed , the projection is a self-adjoint operator on whose 1-eigenspace are the states for which the value of the observable always lies in , and whose 0-eigenspace are the states for which the value of the observable never lies in .
Second, for each fixed normalized vector state , the association
:
P_\pi(\varphi) :
E \mapsto \langle\varphi\mid\pi(E)\varphi\rangle
is a probability measure on making the values of the observable into a random variable.
{{Anchor|Projective measurement}}A measurement that can be performed by a projection-valued measure is called a projective measurement.
If is the real number line, there exists, associated to , a self-adjoint operator defined on by
:
which reduces to
:
if the support of is a discrete subset of .
The above operator is called the observable associated with the spectral measure.
Generalizations
The idea of a projection-valued measure is generalized by the positive operator-valued measure (POVM), where the need for the orthogonality implied by projection operators is replaced by the idea of a set of operators that are a non-orthogonal "partition of unity", i.e. a set of positive semi-definite Hermitian operators that sum to the identity. This generalization is motivated by applications to quantum information theory.
See also
Notes
{{reflist}}
References
- {{cite book | last1=Ashtekar | first1=Abhay | last2=Schilling | first2=Troy A. | title=On Einstein's Path | chapter=Geometrical Formulation of Quantum Mechanics | publisher=Springer New York | publication-place=New York, NY | year=1999 | isbn=978-1-4612-7137-6 | doi=10.1007/978-1-4612-1422-9_3 | arxiv=gr-qc/9706069 }}* {{cite book | last=Conway | first=John B. | title=A course in operator theory | publisher=American mathematical society | publication-place=Providence (R.I.) | date=2000 | isbn=978-0-8218-2065-0}}
- {{cite book | last=Hall | first=Brian C. | title=Quantum Theory for Mathematicians | publisher=Springer Science & Business Media | publication-place=New York | date=2013 | isbn=978-1-4614-7116-5}}
- Mackey, G. W., The Theory of Unitary Group Representations, The University of Chicago Press, 1976
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- {{Narici Beckenstein Topological Vector Spaces|edition=2}}
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- G. Teschl, Mathematical Methods in Quantum Mechanics with Applications to Schrödinger Operators, https://www.mat.univie.ac.at/~gerald/ftp/book-schroe/, American Mathematical Society, 2009.
- {{Trèves François Topological vector spaces, distributions and kernels}}
- Varadarajan, V. S., Geometry of Quantum Theory V2, Springer Verlag, 1970.
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{{Spectral theory}}
{{Functional analysis}}
{{Analysis in topological vector spaces}}