Sodium fluorosilicate

{{Chembox

| PIN = Sodium fluorosilicate

| SystematicName = Sodium hexafluoridosilicate(2–)

{{cite manual|section = Parent Hydride Names and Substitutive Nomenclature|url = http://old.iupac.org/publications/books/rbook/Red_Book_2005.pdf|title = Nomenclature of Inorganic Chemistry, IUPAC Recommendations 2005|publisher = RSC Publishing|year = 2005|pages = 114–135}}

| OtherNames = Disodium hexafluorosilicate/sodium fluosilicate/sodium silicofluoride

| ImageFile = Natriumhexafluorosilicat.png

| ImageSize = 250px

| ImageAlt = Unit cell of the compound

| ImageCaption = Unit cell of sodium hexafluoridosilicate

|Section1={{Chembox Identifiers

| CASNo = 16893-85-9

| CASNo_Ref = {{cascite|correct|CAS}}

| UNII_Ref = {{fdacite|correct|FDA}}

| UNII = 806AV2E065

| PubChem = 28127

| ChemSpiderID = 26165

| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}

| EINECS = 240-934-8

| UNNumber = 2674

| RTECS = VV8410000

| SMILES = [Na+].[Na+].F[Si--](F)(F)(F)(F)F

| StdInChI = 1S/F6Si.2Na/c1-7(2,3,4,5)6;;/q-2;2*+1

| StdInChIKey = TWGUZEUZLCYTCG-UHFFFAOYSA-N}}

|Section2={{Chembox Properties

| Formula= Na2[SiF6]

| MolarMass = 188 g/mol

| Appearance = white granular powder

| Odor = odorless

| Density = 2.7 g/cm3

| Solubility = 0.64 g/100 mL (20 °C)
1.27 g/100 mL (50 °C)
2.45 g/100 mL (100 °C)

| SolubleOther = insoluble in alcohol

| RefractIndex = 1.312

}}

| Section3 = {{Chembox Structure

| Structure_ref = {{cite journal|author=Allan Zalkin, J. D. Forrester, David H. Templeton|year=1964|volume=17|pages=1408–1412|doi=10.1107/S0365110X64003516|doi-access=free|journal=Acta Crystallographica|title=The Crystal Structure of Sodium Fluorosilicate|issue=11|bibcode=1964AcCry..17.1408Z }}

| CrystalStruct = trigonal

| SpaceGroup = P321

| LattConst_a = 8.859

| LattConst_c = 5.038

| UnitCellFormulas = 4

}}

|Section4={{Chembox Hazards

| NFPA-H = 2

| NFPA-F = 0

| NFPA-R = 0

| LDLo = 70 mg/kg (mouse, oral)
125 mg/kg (rabbit, oral){{IDLH|fluoride|Fluorides (as F)}}

}}

|Section7={{Chembox Related

| OtherCations = Ammonium hexafluorosilicate

Fluorosilicic acid}}

}}

Sodium fluorosilicate is a compound with the chemical formula Na2[SiF6]. Unlike other sodium salts, it has a low solubility in water.

Natural occurrence

Sodium hexafluorosilicate occurs naturally as the rare mineral malladrite found within some volcanic fumaroles.{{cite web|url=https://www.mindat.org/min-2554.html|title=Malladrite}}

Manufacturing

Sodium fluorosilicate is made by neutralizing fluorosilicic acid with sodium chloride or sodium sulfate.

:H2[SiF6] + 2 NaCl → Na2[SiF6] + 2 HCl

Possible application

Sodium fluorosilicate is used in some countries as additives for water fluoridation, opal glass raw material, ore refining, or other fluoride chemical (like sodium fluoride, magnesium silicofluoride, cryolite, aluminum fluoride) production.{{cite web |url=http://www.pub.gov.sg/general/pages/watertreatment.aspx |title=PUB |access-date=2009-08-10 |url-status=dead |archive-url=https://web.archive.org/web/20090326084915/http://www.pub.gov.sg/GENERAL/Pages/WaterTreatment.aspx |archive-date=2009-03-26 }}

It is used for extraction of beryllium from beryl, by roasting the mineral with it at 700-750 °C, leaching the soluble fluoride with water, and then precipitating it as Be(OH)2 at about pH 13.{{Cite book |last=Greenwood |first=Norman Neill |title=Chemistry of the elements |last2=Earnshaw |first2=Alan |date=1997 |publisher=Butterworth-Heinemann |isbn=978-0-7506-3365-9 |edition=2nd |location=Oxford Auckland Boston [etc.]}}

It also is an ingredient in some ceramic cements.

See also

References

{{Reflist}}

{{sodium compounds}}

{{Fluorine compounds}}

{{silicon compounds}}

Category:Sodium compounds

Category:Hexafluorosilicates