Spodumene

{{Short description|Pyroxene, inosilicate mineral rich in lithium}}

{{redirect|Kunzite|the Sailor Moon character|Dark Kingdom#Kunzite}}

{{Infobox mineral

| name = Spodumene

| boxwidth =

| boxbgcolor =

| image = Spodumene-usa59abg.jpg

| caption = Walnut Hill Pegmatite Prospect, Huntington, Hampshire County, Massachusetts, U.S. (size: 14.2 × 9.2 × 3.0 cm)

| formula = lithium aluminium silicate, LiAl(SiO₃)₂

| IMAsymbol = Spd{{cite journal |last=Warr |first=L.N. |title=IMA–CNMNC approved mineral symbols |journal=Mineralogical Magazine |volume=85 |pages=291–320 |date=2021|issue=3 |doi=10.1180/mgm.2021.43 |bibcode=2021MinM...85..291W |s2cid=235729616 |doi-access=free }}

| strunz = 9.DA.30

| dana = 65.1.4.1

| system = Monoclinic

| class = Prismatic (2/m)
(same H-M symbol)

| symmetry = C2/c

| unit cell = a = 9.46 Å, b = 8.39 Å
c = 5.22 Å
β = 110.17°; Z = 4

| color = Highly variable: white, colorless, gray, pink, lilac, violet, yellow and green, may be bicolored; emerald green – hiddenite; lilac – kunzite; yellow – triphane

| habit = prismatic, generally flattened and elongated, striated parallel to {100}, commonly massive

| twinning = Common on {100}

| cleavage = Perfect prismatic, two directions {110} ∧ {1{{overline|1}}0} at 87°

| fracture = Uneven to subconchoidal

| tenacity = Brittle

| mohs = 6.5–7

| luster = Vitreous, pearly on cleavage

| refractive = n_α = 1.648–1.661 n_β = 1.655–1.670 n_γ = 1.662–1.679

| opticalprop = Biaxial (+)

| birefringence = δ = 0.014–0.018

| pleochroism = Strong in kunzite: α-purple, γ-colorless; hiddenite: α-green, γ-colorless

| 2V = 54° to 69°

| streak = white

| gravity = 3.03–3.23

| melt =

| fusibility = 3.5

| diagnostic =

| solubility = insoluble

| diaphaneity =

| other = Tenebrescence, chatoyancy

| references = [http://www.mindat.org/min-3733.html Spodumene] {{Webarchive|url=https://web.archive.org/web/20171201131256/http://www.mindat.org/min-3733.html |date=2017-12-01 }}, Mindat.orgAnthony, John W., Bideaux, Richard A., Bladh, Kenneth W., and Nichols, Monte C. (1990). [http://rruff.geo.arizona.edu/doclib/hom/spodumene.pdf Handbook of Mineralogy] {{Webarchive|url=https://web.archive.org/web/20120527173625/http://rruff.geo.arizona.edu/doclib/hom/spodumene.pdf |date=2012-05-27 }}. Mineral Data Publishing, Tucson, ArizonaHurlbut, Cornelius S.; Klein, Cornelis, 1985, Manual of Mineralogy, 20th ed., {{ISBN|0-471-80580-7}}Deer, Howie and Zussman, Rock Forming Minerals, v. 2 Chain Silicates, Wiley, 1963 pp. 92–98

}}

Spodumene is a pyroxene mineral consisting of lithium aluminium inosilicate, Li Al(Si O₃)₂, and is a commercially important source of lithium. It occurs as colorless to yellowish, purplish, or lilac kunzite (see below), yellowish-green or emerald-green hiddenite, prismatic crystals, often of great size. Single crystals of {{convert|14.3|m|abbr=on}} in size are reported from the Black Hills of South Dakota, United States.{{cite journal |last=Schwartz |first=G. |title=The Black Hills Mineral Region |url=http://www.minsocam.org/msa/collectors_corner/arc/black_hills.htm |journal=American Mineralogist |volume=13 |pages=56–63 |date=1928}}Robert Louis Bonewitz, 2005, Rock and Gem, London, Dorling Kindersley

The naturally occurring low-temperature form α-spodumene is in the monoclinic system, and the high-temperature β-spodumene crystallizes in the tetragonal system. α-Spodumene converts to β-spodumene at temperatures above 900 °C. Crystals are typically heavily striated parallel to the principal axis. Crystal faces are often etched and pitted with triangular markings.{{Not verified in body|date=June 2022}}

Discovery and occurrence

Spodumene was first described in 1800 for an occurrence in the type locality in Utö, Södermanland, Sweden. It was discovered by Brazilian naturalist Jose Bonifacio de Andrada e Silva. The name is derived from the Greek spodumenos (σποδούμενος), meaning "burnt to ashes", owing to the opaque ash-grey appearance of material refined for use in industry.

Spodumene occurs in lithium-rich granite pegmatites and aplites. Associated minerals include quartz, albite, petalite, eucryptite, lepidolite, and beryl.

Transparent material has long been used as a gemstone with varieties kunzite and hiddenite noted for their strong pleochroism. Source localities include the Democratic Republic of Congo (DRC), Afghanistan, Australia, Brazil, Madagascar (see mining), Pakistan, Québec in Canada, and North Carolina and California in the U.S.

Since 2018, the DRC has been known to have the largest lithium spodumene hard-rock deposit in the world, with mining operations occurring in the central DRC territory of Manono, Tanganyika Province.{{cite news |title=This Congo project could supply the world with lithium |url=https://www.mining.com/one-congo-project-supply-world-lithium/ |work=MiningDotCom |date=10 December 2018 |access-date=26 March 2021 |archive-date=14 April 2021 |archive-url=https://web.archive.org/web/20210414030827/https://www.mining.com/one-congo-project-supply-world-lithium/ |url-status=live }} As of 2021, the Australian company AVZ Minerals{{cite web |title=AVZ Minerals Limited |url=https://avzminerals.com.au/ |website=AVZ Minerals |access-date=25 March 2021 |archive-date=14 April 2021 |archive-url=https://web.archive.org/web/20210414031226/https://avzminerals.com.au/ |url-status=live }} is developing the Manono Lithium and Tin project, and has a resource size of 400 million tonnes of high-grade low-impurity ore at 1.65% lithium oxide (Li₂O){{Cite web|title=AVZ Minerals Definitive Feasibility Study (DFS – April 2020)|url=https://avzminerals.com.au/manono-project-definitive-feasibility-review|website=AVZ Minerals|access-date=2021-03-31|archive-date=2021-04-14|archive-url=https://web.archive.org/web/20210414054727/https://avzminerals.com.au/manono-project-definitive-feasibility-review|url-status=live}} spodumene hard-rock based on studies and drilling of Roche Dure, one of several pegmatites in the deposit.

Economic importance

Spodumene is an important source of lithium, for use in ceramics, mobile phones and batteries (including for automotive applications), medicine, Pyroceram, and as a fluxing agent. As of 2019, around half of lithium is extracted from mineral ores, which mainly consist of spodumene. Lithium is recovered from spodumene by dissolution in acid, or extraction with other reagents, after roasting to convert it to the more reactive β-spodumene. The advantage of spodumene as a lithium source compared to brine sources is the higher lithium concentration, but at a higher extraction cost.{{cite journal |last1=Rioyo |first1=Javier |last2=Tuset |first2=Sergio |last3=Grau |first3=Ramón |title=Lithium Extraction from Spodumene by the Traditional Sulfuric Acid Process: A Review |url=https://doi.org/10.1080/08827508.2020.1798234 |journal=Mineral Processing and Extractive Metallurgy Review |volume=43 |pages=97–106 |date=12 August 2020 |issn=0882-7508 |s2cid=225417879 |doi=10.1080/08827508.2020.1798234}}

In 2016, the price of spodumene concentrate was forecast to be $500–600/ton for years to come.{{cite web |title=Spodumene concentrate forecasted price 2020 |url=https://www.statista.com/statistics/712619/price-forecast-of-spodumene/ |website=Statista |archive-url= https://web.archive.org/web/20201201193452/https://www.statista.com/statistics/712619/price-forecast-of-spodumene/ |archive-date=1 December 2020 |date=21 July 2016 |url-status=live}} However, price spiked above $800 in January 2018, and production increased more than consumption, resulting in the price declining to $400 by September 2020.{{cite web |last1=Shi |first1=Carrie |last2=Ouerghi |first2=Dalila |title=Demand pick-up halts spodumene price fall |url=https://www.metalbulletin.com/Article/3954467/Demand-pick-up-halts-spodumene-price-fall.html |website=www.metalbulletin.com |archive-url=https://web.archive.org/web/20201011184528/https://www.metalbulletin.com/Article/3954467/Demand-pick-up-halts-spodumene-price-fall.html |archive-date=11 October 2020 |date=5 October 2020 |url-status=live}}{{cite web |title=Lithium Resources and Energy Quarterly |url=https://publications.industry.gov.au/publications/resourcesandenergyquarterlydecember2019/documents/Resources-and-Energy-Quarterly-December-2019-Lithium.pdf |archive-url=https://web.archive.org/web/20200922052832/https://publications.industry.gov.au/publications/resourcesandenergyquarterlydecember2019/documents/Resources-and-Energy-Quarterly-December-2019-Lithium.pdf |archive-date=22 September 2020 |date=December 2019 |url-status=live}}

World production of lithium via spodumene was around 80,000 metric tonnes per annum in 2018, primarily from the Greenbushes pegmatite of Western Australia and from some Chinese and Chilean sources. The Talison Minerals mine in Greenbushes, Western Australia (involving Tianqi Lithium, Albemarle Corporation, and Global Advanced Metals), is reported to be the world's second-largest and to have the highest grade of ore at 2.4% Li₂O (2012 figures).{{cite web |title=Greenbushes Lithium Mine |url=http://www.goldendragoncapital.com/greenbushes-lithium-mine/ |website=Golden Dragon Capital |access-date=18 January 2019 |archive-date=19 January 2019 |archive-url=https://web.archive.org/web/20190119121438/http://www.goldendragoncapital.com/greenbushes-lithium-mine/ |url-status=dead }}

In 2020, Australia expanded spodumene mining to become the leading lithium-producing country in the world.{{cite web|url=https://pubs.usgs.gov/periodicals/mcs2020/mcs2020-lithium.pdf|title=Mineral Commodity Summaries 2020|last=Jaskula|first=Brian W.|date=January 2020|website=U.S. Geological Survey|access-date=29 June 2020|archive-date=1 November 2020|archive-url=https://web.archive.org/web/20201101085310/https://pubs.usgs.gov/periodicals/mcs2020/mcs2020-lithium.pdf|url-status=live}}

An important economic concentrate of spodumene, known as spodumene concentrate 6 or SC6, is a high-purity lithium ore with around 6% lithium content being produced as a raw material for the subsequent production of lithium-ion batteries for electric vehicles.{{cite news |title=Piedmont Lithium stock soars on confirmed Tesla deal |url=https://www.mining.com/piedmont-lithium-soars-after-confirming-tesla-deal/ |last=Jamasmie |first=Cecilia |work=mining.com |date=28 September 2020 |accessdate=13 March 2021 |archive-date=16 March 2021 |archive-url=https://web.archive.org/web/20210316204716/https://www.mining.com/piedmont-lithium-soars-after-confirming-tesla-deal/ |url-status=live }}[https://d1io3yog0oux5.cloudfront.net/_387a8ad2078edb4536fdea17b0a793e2/piedmontlithium/db/336/2620/pdf/2118399.pdf Piedmont Lithium Signs Sales Agreement with Tesla] {{Webarchive|url=https://web.archive.org/web/20210126175847/https://d1io3yog0oux5.cloudfront.net/_387a8ad2078edb4536fdea17b0a793e2/piedmontlithium/db/336/2620/pdf/2118399.pdf |date=2021-01-26 }}, 28 September 2020, retrieved 14 March 2021.

Refining

Extraction of lithium from spodumene, often SC6, is challenging due to the tight binding of lithium in the crystal structure.

Traditional lithium refining in the 2010s involves acid leaching of lithium-containing ores, precipitation of impurities, concentration of the lithium solution, and then conversion to lithium carbonate or lithium hydroxide. These refining methods result in significant quantities of caustic waste effluent and tailings, which are usually either highly acidic or alkali. Suitable extraction reagents include alkali metal sulfates, such as sodium sulfate, sodium carbonate, chlorine, or hydrofluoric acid.{{cite journal |last1=Choubey |first1=Pankaj K. |last2=Kim |first2=Min-seuk |last3=Srivastava |first3=Rajiv R. |last4=Lee |first4=Jae-chun |last5=Lee |first5=Jin-Young |title=Advance review on the exploitation of the prominent energy-storage element: Lithium. Part I: From mineral and brine resources |journal=Minerals Engineering |volume=89 |pages=119–137 |date=April 2016 |doi=10.1016/j.mineng.2016.01.010|bibcode=2016MiEng..89..119C }}

Another processing method relies on pyrometallurgical processing of SC6—roasting at high temperatures exceeding {{convert|800|C||sp=us}} to convert the spodumene from the tightly bound alpha structure to a more open beta structure from which the lithium is more easily extracted—then cooling and reacting with various reagents in a sequence of hydrometallurgical processing steps. Some offer the use of noncaustic reagents and result in reduced waste streams, potentially allowing the use of a closed-loop refining process.{{cite news |title=Tesla’s lithium refinery plant on the Texas Gulf Coast is ahead of schedule and should begin production by mid-2024 |url=https://eepower.com/news/tesla-lithium-extraction-facility-opening-mid-2024-in-texas/# |last=Clemens|first=Kevin |work=EE Power |date=3 November 2023 |accessdate=18 November 2024}} Tesla has developed and, as of 2025, is operationalizing at scale, this process of lithium refinement that does not require strong acids to extract lithium from spodumene. Their method mixes sodium chloride with the open-beta-structure spodumene concentrate and water. Agitation at high temperatures produces a slurry rich in lithium that can be filtered and purified into lithium hydroxide. The sands and limestone waste products can be repurposed as construction materials. A $375 million Tesla refinery plant located on 1,200 acres in Robstown, Texas, is under construction using this process. It began partial operation in December 2024. The site was chosen for its proximity to the Port of Corpus Christi, where spodumene can easily be imported.{{Cite web |last=Lingle |first=Brandon |date=2024-12-16 |title=Tesla begins operation at its South Texas lithium refinery, firing up its kiln for first time |url=https://www.expressnews.com/business/article/tesla-lithium-refinery-texas-kiln-starts-19983809.php |access-date=2025-01-30 |website=San Antonio Express-News |archive-date=2024-12-22 |archive-url=https://web.archive.org/web/20241222124318/https://www.expressnews.com/business/article/tesla-lithium-refinery-texas-kiln-starts-19983809.php |url-status=live }}

A common form of more highly refined lithium from both of the above processes is lithium hydroxide, commonly used as an input in the battery industry to manufacture lithium-ion (Li-ion) battery cathode material.

Gemstone varieties

=Hiddenite=

Hiddenite is a pale, emerald-green gem variety first reported from Alexander County, North Carolina, U.S.Smith, John Lawrence. "[https://www.ajsonline.org/content/s3-21/122/128 Hiddenite, an emerald-green variety of spodumene.] {{Webarchive|url=https://web.archive.org/web/20210823121914/https://www.ajsonline.org/content/s3-21/122/128 |date=2021-08-23 }}" American Journal of Science 3.122 (1881): 128–130. It was named in honor of William Earl Hidden (16 February 1853 – 12 June 1918), mining engineer, mineral collector, and mineral dealer.{{cite journal |last=Cook |first=Robert B. |title=Connoisseur's Choice: Spodumene var. Kunzite, Nuristan, Afghanistan |url=https://doi.org/10.1080/00357529709605063 |journal=Rocks & Minerals |volume=72 |issue=5 |pages=340–343 |date=1 September 1997 |issn=0035-7529 |doi=10.1080/00357529709605063|bibcode=1997RoMin..72..340C }}{{Additional citation needed|date=August 2021}}

This emerald-green variety of spodumene is colored by chromium, just as for emeralds. Some green spodumene is colored with substances other than chromium; such stones tend to have a lighter color; they are not true hiddenite.

=Kunzite=

Kunzite is a purple-colored gemstone, a variety of spodumene, with the color coming from minor to trace amounts of manganese. Exposure to sunlight can fade its color.

Kunzite was discovered in 1902, and was named after George Frederick Kunz, Tiffany & Co's chief jeweler at the time, and a noted mineralogist. It has been found in Brazil, the U.S., Canada, CIS, Mexico, Sweden, Western Australia, Afghanistan, and Pakistan.{{Cite web |title=Kunzite Gemstone {{!}} Kunzite Stone – GIA |url=https://www.gia.edu/kunzite |access-date=2023-03-01 |website=www.gia.edu |archive-date=2023-03-01 |archive-url=https://web.archive.org/web/20230301044710/https://www.gia.edu/kunzite |url-status=live }}

Spodumene.jpg|An almost colorless kunzite crystal (upper left), a cut pale pink kunzite (upper right), and a greenish hiddenite crystal (below) (unknown scale)

Kunzite Nouristan.jpg|Kunzite, Nuristan Province, Afghanistan

Spodumene var. hiddenite - Araçuaí, Minas Gerais, Brazil.jpg|Hiddenite from Araçuaí, Minas Gerais, Brazil

=Triphane=

Triphane is the name used for yellowish varieties of spodumene.{{cite journal |last=Brooks |first=Kent |title=Lithium minerals |url=https://onlinelibrary.wiley.com/doi/abs/10.1111/gto.12326 |journal=Geology Today |volume=36 |issue=5 |pages=192–197 |date=2020 |issn=1365-2451 |s2cid=243253247 |doi=10.1111/gto.12326 |bibcode=2020GeolT..36..192B |archive-date=2021-08-23 |access-date=2021-08-23 |archive-url=https://web.archive.org/web/20210823122353/https://onlinelibrary.wiley.com/doi/abs/10.1111/gto.12326 |url-status=live }}

References

External links

{{Wikisource-inline|list=
{{Cite EB1911|wstitle=Kunzite |short=x |noicon=x}}
{{Cite EB1911 |last=Rudler |first=Frederick William |wstitle=Spodumene|short=x |noicon=x}}
{{Cite NIE|wstitle=Spodumene|year=1905 |short=x |noicon=x}}

}}

Category:Aluminium minerals

Category:Gemstones

Category:Inosilicates

Category:Lithium minerals

Category:Monoclinic minerals

Category:Minerals in space group 15

Category:Pyroxene group