Strontium sulfate

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|Verifiedfields = changed

|Watchedfields = changed

|verifiedrevid = 477162743

|Reference =

{{Cite book|last = Lide|first = David R.|year = 1998|title = Handbook of Chemistry and Physics| edition = 87|place = Boca Raton, FL|publisher = CRC Press|isbn = 0-8493-0594-2|pages = 4–87; 1364}}

|ImageFile = Strontium-sulfate-from-xtal-3D-SF.png

|ImageSize =

|IUPACName = Strontium sulfate

|OtherNames = Celestine

|Section1={{Chembox Identifiers

|ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}

|ChemSpiderID = 2341151

|InChI = 1/H2O4S.Sr/c1-5(2,3)4;/h(H2,1,2,3,4);/q;+2/p-2

|InChIKey = UBXAKNTVXQMEAG-NUQVWONBAV

|SMILES = [Sr+2].[O-]S([O-])(=O)=O

|StdInChI_Ref = {{stdinchicite|correct|chemspider}}

|StdInChI = 1S/H2O4S.Sr/c1-5(2,3)4;/h(H2,1,2,3,4);/q;+2/p-2

|StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}

|StdInChIKey = UBXAKNTVXQMEAG-UHFFFAOYSA-L

|CASNo = 7759-02-6

|CASNo_Ref = {{cascite|correct|CAS}}

|UNII_Ref = {{fdacite|changed|FDA}}

|UNII = 7Q3KX2L47F

|PubChem = 3084026

|EINECS = 231-850-2

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|Section2={{Chembox Properties

|Formula = SrSO4

|MolarMass = 183.68 g/mol

|Appearance = white orthorhombic crystals

|Density = 3.96 g/cm3

|MeltingPtC = 1606

|Solubility = 0.0135 g/100 mL (25 °C)
0.014 g/100 mL (30 °C)

|SolubleOther = insoluble in ethanol, alkalis
slightly soluble in acids

|SolubilityProduct = 3.44 x 10−7

|RefractIndex = 1.622{{cite book|last =Patnaik|first=Pradyot|year=2003|title=Handbook of Inorganic Chemical Compounds |publisher=McGraw-Hill|pages=560–576|isbn =0-07-049439-8|url=https://books.google.com/books?id=Xqj-TTzkvTEC|access-date=2009-06-06}}

|MagSus = −57.9·10−6 cm3/mol

}}

|Section3={{Chembox Structure

|CrystalStruct = Orthorhombic, oP24

|SpaceGroup = Pnma, No. 62{{cite journal|last1=Krystek|title=Lattice Parameters of (BaxSr100-x)SO4 Doped with Europium|first1=M.|author8 = Krystek M.|doi=10.1002/pssa.2210540256|journal=Physica Status Solidi A|volume=54|year=1979|page=K133|issue=2|bibcode=1979PSSAR..54..133K}}

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|Section4={{Chembox Thermochemistry

|DeltaHf = −1453.1 kJ·mol−1

|Entropy = 117.0 J·mol−1·K−1

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|Section5={{Chembox Hazards

|ExternalSDS = [http://www.bariumchemicals.com/Products/MSDS_Printview.asp?MSDSid=51 External MSDS data]

|NFPA-H = 1

|NFPA-F = 0

|NFPA-R = 0

|FlashPt = Not flammable

}}

|Section6={{Chembox Related

|OtherAnions = Strontium chloride
Strontium oxide

|OtherCations = Beryllium sulfate
Magnesium sulfate
Calcium sulfate
Barium sulfate

}}

}}

Strontium sulfate (SrSO4) is the sulfate salt of strontium. It is a white crystalline powder and occurs in nature as the mineral celestine. It is poorly soluble in water to the extent of 1 part in 8,800. It is more soluble in dilute HCl and nitric acid and appreciably soluble in alkali chloride solutions (e.g. sodium chloride).

Structure

Strontium sulfate is a polymeric material, isostructural with barium sulfate. Crystallized strontium sulfate is utilized by a small group of radiolarian protozoa, called the Acantharea, as a main constituent of their skeleton.

Applications and chemistry

Strontium sulfate is of interest as a naturally occurring precursor to other strontium compounds, which are more useful. In industry it is converted to the carbonate for use as ceramic precursor and the nitrate for use in pyrotechnics.J. Paul MacMillan, Jai Won Park, Rolf Gerstenberg, Heinz Wagner, Karl Köhler, Peter Wallbrecht “Strontium and Strontium Compounds” in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim. {{doi|10.1002/14356007.a25_321}}.

The low aqueous solubility of strontium sulfate can lead to scale formation in processes where these ions meet. For example, it can form on surfaces of equipment in underground oil wells depending on the groundwater conditions.{{Cite journal|url=https://www.onepetro.org/journal-paper/SPE-9625-PA|doi = 10.2118/9625-PA|title = A Study of Solubility of Strontium Sulfate|year = 1983|last1 = Jacques|first1 = Donald F.|last2 = Bourland|first2 = Brent I.|journal = Society of Petroleum Engineers Journal|volume = 23|issue = 2|pages = 292–300}}{{cite journal | doi=10.1520/JAI100958 | title=Prediction of Strontium Sulfate Scale Formation in Oilfield Environment | year=2007 | last1=Dean | first1=S. W. | last2=Ezuber | first2=Hosni M. | journal=Journal of ASTM International | volume=4 | issue=6 | page=100958 }}

References

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{{Strontium compounds}}

{{Sulfates}}

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Category:Strontium compounds

Category:Sulfates

Category:Pyrotechnic colorants