Thorium fuel cycle
{{short description|Nuclear fuel cycle}}
File:Thorium sample 0.1g.jpg]]
The thorium fuel cycle is a nuclear fuel cycle that uses an isotope of thorium, {{SimpleNuclide|Thorium|232|link=yes}}, as the fertile material. In the reactor, {{SimpleNuclide|Thorium|232}} is transmuted into the fissile artificial uranium isotope {{SimpleNuclide|Uranium|233|link=yes}} which is the nuclear fuel. Unlike natural uranium, natural thorium contains only trace amounts of fissile material (such as {{SimpleNuclide|Thorium|231|link=yes}}), which are insufficient to initiate a nuclear chain reaction. Additional fissile material or another neutron source is necessary to initiate the fuel cycle. In a thorium-fuelled reactor, {{SimpleNuclide|Thorium|232}} absorbs neutrons to produce {{SimpleNuclide|Uranium|233}}. This parallels the process in uranium breeder reactors whereby fertile {{SimpleNuclide|Uranium|238|link=yes}} absorbs neutrons to form fissile {{SimpleNuclide|Plutonium|239|link=yes}}. Depending on the design of the reactor and fuel cycle, the generated {{SimpleNuclide|Uranium|233}} either fissions in situ or is chemically separated from the used nuclear fuel and formed into new nuclear fuel.
The thorium fuel cycle has several potential advantages over a uranium fuel cycle, including thorium's greater abundance, superior physical and nuclear properties, reduced plutonium and actinide production, and better resistance to nuclear weapons proliferation when used in a traditional light water reactor{{cite web |url=http://www.aps.org/units/fps/newsletters/201101/hargraves.cfm |title=Liquid Fuel Nuclear Reactors |author=Robert Hargraves |author2=Ralph Moir |date= January 2011 |work=American Physical Society Forum on Physics & Society |access-date=31 May 2012}}{{cite web |url=http://nuclearweaponarchive.org/Nwfaq/Nfaq6.html |first=Carey |last=Sublette |date=20 February 1999 |title=Nuclear Materials FAQ |website=nuclearweaponarchive.org |access-date=October 23, 2019 }} though not in a molten salt reactor.{{Cite journal | last1 = Kang | first1 = J. | last2 = Von Hippel | first2 = F. N. | doi = 10.1080/08929880108426485 | title = U-232 and the proliferation-resistance of U-233 in spent fuel | journal = Science & Global Security | volume = 9 | issue = 1 | pages = 1–32 | year = 2001 | bibcode = 2001S&GS....9....1K | s2cid = 8033110 }} {{cite web |url=http://www.torium.se/res/Documents/9_1kang.pdf |title=Archived copy |access-date=2015-03-02 |url-status=dead |archive-url=https://web.archive.org/web/20141203135336/http://www.torium.se/res/Documents/9_1kang.pdf |archive-date=2014-12-03 }}{{cite web|url=http://www.popularmechanics.com/science/energy/nuclear/is-the-superfuel-thorium-riskier-than-we-thought-14821644|title="Superfuel" Thorium a Proliferation Risk?|date=5 December 2012}}{{cite journal |last1=Ashley |first1=Stephen |last2=Parks |first2=Geoffrey |date=2012-12-05 |title=Thorium fuel has risks |journal=Nature |volume= 492|issue= 7427|pages=31–33 |doi= 10.1038/492031a|pmid=23222590 |s2cid=4414368 | quote=We are concerned, however, that other processes, which might be conducted in smaller facilities, could be used to convert 232Th into 233U while minimizing contamination by 232U, thus posing a proliferation threat. Notably, the chemical separation of an intermediate isotope — protactinium-233 — that decays into 233U is a cause for concern. ... The International Atomic Energy Agency (IAEA) considers 8 kilograms of 233U to be enough to construct a nuclear weapon1. Thus, 233U poses proliferation risks. |doi-access=free }}
History
{{See also|Thorium-based nuclear power}}
Concerns about the limits of worldwide uranium resources motivated initial interest in the thorium fuel cycle. It was envisioned that as uranium reserves were depleted, thorium would supplement uranium as a fertile material. However, for most countries uranium was relatively abundant and research in thorium fuel cycles waned. A notable exception was India's three-stage nuclear power programme.{{cite book| author = Ganesan Venkataraman | title = Bhabha and his magnificent obsessions|page= 157|
year = 1994|
publisher = Universities Press}}
In the twenty-first century thorium's claimed potential for improving proliferation resistance and waste characteristics led to renewed interest in the thorium fuel cycle.{{cite web| url=http://www-pub.iaea.org/MTCD/publications/PDF/te_1349_web.pdf |publisher= International Atomic Energy Agency |title= IAEA-TECDOC-1349 Potential of thorium-based fuel cycles to constrain plutonium and to reduce the long-lived waste toxicity |year= 2002 |access-date= 2009-03-24}}{{cite news | url= http://www.abc.net.au/news/newsitems/200604/s1616391.htm | title= Scientist urges switch to thorium |last=Evans |first=Brett |date= April 14, 2006 |publisher= ABC News |archive-url=https://web.archive.org/web/20100328211103/http://www.abc.net.au/news/newsitems/200604/s1616391.htm|archive-date=2010-03-28| access-date=2011-09-17 }}{{cite magazine |url= https://www.wired.com/magazine/2009/12/ff_new_nukes/ |last=Martin |first=Richard |magazine=Wired |date= December 21, 2009 | title= Uranium Is So Last Century – Enter Thorium, the New Green Nuke |access-date= 2010-06-19 }} While thorium is more abundant in the continental crust than uranium and easily extracted from monazite as a side product of rare earth element mining, it is much less abundant in seawater than uranium.{{Cite journal |last=Moore |first=Willard S. |date=1981-05-01 |title=The thorium isotope content of ocean water |url=https://dx.doi.org/10.1016/0012-821X%2881%2990046-7 |journal=Earth and Planetary Science Letters |language=en |volume=53 |issue=3 |pages=419–426 |doi=10.1016/0012-821X(81)90046-7 |bibcode=1981E&PSL..53..419M |issn=0012-821X}}
At Oak Ridge National Laboratory in the 1960s, the Molten-Salt Reactor Experiment used {{SimpleNuclide|Uranium|233}} as the fissile fuel in an experiment to demonstrate a part of the Molten Salt Breeder Reactor that was designed to operate on the thorium fuel cycle. Molten salt reactor (MSR) experiments assessed thorium's feasibility, using thorium(IV) fluoride dissolved in a molten salt fluid that eliminated the need to fabricate fuel elements. The MSR program was defunded in 1976 after its patron Alvin Weinberg was fired.{{cite web |last=Miller|first=Daniel| title=Nuclear community snubbed reactor safety message: expert|url= http://www.abc.net.au/news/2011-03-18/nuclear-community-snubbed-reactor-safety-message/2649768|work= ABC News|date=March 2011 | access-date= 2012-03-25 }}
In 1993, Carlo Rubbia proposed the concept of an energy amplifier or "accelerator driven system" (ADS), which he saw as a novel and safe way to produce nuclear energy that exploited existing accelerator technologies. Rubbia's proposal offered the potential to incinerate high-activity nuclear waste and produce energy from natural thorium and depleted uranium.{{cite web |last=Dean |first=Tim |title=New age nuclear |url=http://www.cosmosmagazine.com/features/print/348/new-age-nuclear?page=0%2C3 |work=Cosmos |date=April 2006 |access-date=2010-06-19 |archive-date=2010-01-05 |archive-url=https://web.archive.org/web/20100105201937/http://www.cosmosmagazine.com/features/print/348/new-age-nuclear?page=0%2C3 |url-status=dead }}{{cite book |url=http://www.inference.phy.cam.ac.uk/withouthotair/c24/page_166.shtml |title=Sustainable Energy – without the hot air |last=MacKay |first= David J. C. |author-link= David J. C. MacKay |date=February 20, 2009 |publisher= UIT Cambridge Ltd. |page= 166 | access-date= 2010-06-19 }}
Kirk Sorensen, former NASA scientist and Chief Technologist at Flibe Energy, has been a long-time promoter of thorium fuel cycle and particularly liquid fluoride thorium reactors (LFTRs). He first researched thorium reactors while working at NASA, while evaluating power plant designs suitable for lunar colonies. In 2006 Sorensen started "energyfromthorium.com" to promote and make information available about this technology.{{cite web|url=http://flibe-energy.com/ |title=Flibe Energy |publisher=Flibe Energy |access-date=2012-06-12}}
A 2011 MIT study concluded that although there is little in the way of barriers to a thorium fuel cycle, with current or near term light-water reactor designs there is also little incentive for any significant market penetration to occur. As such they conclude there is little chance of thorium cycles replacing conventional uranium cycles in the current nuclear power market, despite the potential benefits.{{Cite report |date=2011 |title=The Future of the Nuclear Fuel Cycle | url=https://energy.mit.edu/wp-content/uploads/2011/04/MITEI-The-Future-of-the-Nuclear-Fuel-Cycle.pdf |publisher=MIT |page=181 }}
Nuclear reactions with thorium
In the thorium cycle, fuel is formed when {{SimpleNuclide|Thorium|232}} captures a neutron (whether in a fast reactor or thermal reactor) to become {{SimpleNuclide|Thorium|233|link=yes}}. This normally emits an electron and an anti-neutrino ({{SubatomicParticle|Antineutrino}}) by beta decay to become {{SimpleNuclide|Protactinium|233|link=yes}}. This then emits another electron and anti-neutrino by a second {{SubatomicParticle|beta-}} decay to become {{SimpleNuclide|Uranium|233}}, the fuel:
:
=Fission product waste=
Nuclear fission produces radioactive fission products which can have half-lives from days to greater than 200,000 years. According to some toxicity studies,{{cite web |url= http://hal.archives-ouvertes.fr/docs/00/04/14/97/PDF/document_IAEA.pdf |last=Le Brun |first=C. |author2=L. Mathieu |author3=D. Heuer |author4=A. Nuttin | title= Impact of the MSBR concept technology on long-lived radio-toxicity and proliferation resistance |publisher= Technical Meeting on Fissile Material Management Strategies for Sustainable Nuclear Energy, Vienna 2005 | access-date= 2010-06-20 }} the thorium cycle can fully recycle actinide wastes and only emit fission product wastes, and after a few hundred years, the waste from a thorium reactor can be less toxic than the uranium ore that would have been used to produce low enriched uranium fuel for a light water reactor of the same power.
Other studies assume some actinide losses and find that actinide wastes dominate thorium cycle waste radioactivity at some future periods.{{cite web |url=http://lpsc.in2p3.fr/gpr/english/NEWNRW/NEWNRW.html#foot284 |title=Nuclear Energy With (Almost) No Radioactive Waste? |quote=according to computer simulations done at ISN, this Protactinium dominates the residual toxicity of losses at {{val|10000|u=years}} |date=July 2001 |author1=Brissot R. |author2=Heuer D. |author3=Huffer E. |author4=Le Brun, C. |author5=Loiseaux, J-M |author6=Nifenecker H. |author7=Nuttin A. |publisher=Laboratoire de Physique Subatomique et de Cosmologie (LPSC) |url-status=dead |archive-url=https://web.archive.org/web/20110525091426/http://lpsc.in2p3.fr/gpr/english/NEWNRW/NEWNRW.html#foot284 |archive-date=2011-05-25 }} Some fission products have been proposed for nuclear transmutation, which would further reduce the amount of nuclear waste and the duration during which it would have to be stored (whether in a deep geological repository or elsewhere). However, while the principal feasibility of some of those reactions has been demonstrated at laboratory scale, there is, as of 2024, no large scale deliberate transmutation of fission products anywhere in the world, and the upcoming MYRRHA research project into transmutation is mostly focused on transuranic waste. Furthermore, the cross section of some fission products is relatively low and others - such as caesium - are present as a mixture of stable, short lived and long lived isotopes in nuclear waste, making transmutation dependent on expensive isotope separation.
=Actinide waste=
In a reactor, when a neutron hits a fissile atom (such as certain isotopes of uranium), it either splits the nucleus or is captured and transmutes the atom. In the case of {{SimpleNuclide|Uranium|233}}, the transmutations tend to produce useful nuclear fuels rather than transuranic waste. When {{SimpleNuclide|Uranium|233}} absorbs a neutron, it either fissions or becomes {{SimpleNuclide|Uranium|234|link=yes}}. The chance of fissioning on absorption of a thermal neutron is about 92%; the capture-to-fission ratio of {{SimpleNuclide|Uranium|233}}, therefore, is about 1:12 – which is better than the corresponding capture vs. fission ratios of {{SimpleNuclide|Uranium|235|link=yes}} (about 1:6), or {{SimpleNuclide|Plutonium|239}} or {{SimpleNuclide|Plutonium|241|link=yes}} (both about 1:3).{{cite web |url=http://www-pub.iaea.org/MTCD/publications/PDF/TE_1450_web.pdf |publisher=International Atomic Energy Agency |title=IAEA-TECDOC-1450 Thorium Fuel Cycle – Potential Benefits and Challenges |date=May 2005 |access-date=2009-03-23 }}{{cite web |url=http://www.nndc.bnl.gov/chart/ |title=Interactive Chart of Nuclides |website=Brookhaven National Laboratory |access-date=2 March 2015 |quote=Thermal neutron cross sections in barns (isotope, capture:fission, f/f+c, f/c) 233U 45.26:531.3 92.15% 11.74; 235U 98.69:585.0 85.57% 5.928; 239Pu 270.7:747.9 73.42% 2.763; 241Pu 363.0:1012 73.60% 2.788. |archive-date=21 July 2011 |archive-url=https://web.archive.org/web/20110721051025/http://www.nndc.bnl.gov/chart/ |url-status=dead }} The result is less transuranic waste than in a reactor using the uranium-plutonium fuel cycle.
{{Thorium Cycle Transmutation}}
{{SimpleNuclide|Uranium|234}}, like most actinides with an even number of neutrons, is not fissile, but neutron capture produces fissile {{SimpleNuclide|Uranium|235}}. If the fissile isotope fails to fission on neutron capture, it produces {{SimpleNuclide|Uranium|236|link=yes}}, {{SimpleNuclide|Neptunium|237|link=yes}}, {{SimpleNuclide|Plutonium|238|link=yes}}, and eventually fissile {{SimpleNuclide|Plutonium|239}} and heavier isotopes of plutonium. The {{SimpleNuclide|Neptunium|237}} can be removed and stored as waste or retained and transmuted to plutonium, where more of it fissions, while the remainder becomes {{SimpleNuclide|Plutonium|242|link=yes}}, then americium and curium, which in turn can be removed as waste or returned to reactors for further transmutation and fission.
However, the {{SimpleNuclide|Protactinium|231|link=yes}} (with a half-life of {{val|3.27|e=4|u=years}}) formed via (n,2n) reactions with {{SimpleNuclide|Thorium|232}} (yielding {{SimpleNuclide|Thorium|231}} that decays to {{SimpleNuclide|Protactinium|231|link=yes}}), while not a transuranic waste, is a major contributor to the long-term radiotoxicity of spent nuclear fuel. While {{chem|231|Pa}} can in principle be converted back to {{chem|232|Th}} by neutron absorption, its neutron absorption cross section is relatively low, making this rather difficult and possibly uneconomic.
=Uranium-232 contamination=
{{SimpleNuclide|Uranium|232|link=yes}} is also formed in this process, via (n,2n) reactions between fast neutrons and {{SimpleNuclide|Uranium|233}}, {{SimpleNuclide|Protactinium|233|link=yes}}, and {{SimpleNuclide|Thorium|232}}:
:
\begin{align}{}\\
\ce{{^{232}_{90}Th} ->[+n] {^{233}_{90}Th} ->[\beta^-] {^{233}_{91}Pa} \text{ } ->[\beta^-] {^{233}_{92}U} ->[+n-2n] {^{232}_{92}U}}\\
\ce{{^{232}_{90}Th} ->[+n] {^{233}_{90}Th} ->[\beta^-] {^{233}_{91}Pa} \text{ } ->[+n-2n] {^{232}_{91}Pa} ->[\beta^-] {^{232}_{92}U}}\\
\ce{{^{232}_{90}Th} ->[+n-2n] {^{231}_{90}Th} ->[\beta^-] {^{231}_{91}Pa} \text{ } ->[+n] {^{232}_{91}Pa} ->[\beta^-] {^{232}_{92}U}}\\{}
\end{align}
Unlike most even numbered heavy isotopes, {{SimpleNuclide|Uranium|232}} is also a fissile fuel fissioning just over half the time when it absorbs a thermal neutron.{{Cite web|url=http://atom.kaeri.re.kr/nuchart/getEvaf.jsp?mat=9219&lib=endfb7.1|title=9219.endfb7.1|website=atom.kaeri.re.kr}} {{SimpleNuclide|Uranium|232}} has a relatively short half-life ({{val|68.9|u=years}}), and some decay products emit high energy gamma radiation, such as {{SimpleNuclide|Radon|220|link=yes}}, {{SimpleNuclide|Bismuth|212|link=yes}} and particularly {{SimpleNuclide|Thallium|208|link=yes}}. The full decay chain, along with half-lives and relevant gamma energies, is:
File:Decay chain(4n,Thorium series).PNG of 232Th, commonly called the "thorium series"]]{{SimpleNuclide|Uranium|232}} decays to {{SimpleNuclide|Thorium|228|link=yes}} where it joins the thorium series
:
\begin{align}{}\\
\ce{^{232}_{92}U ->[\alpha] ^{228}_{90}Th}\ &\mathrm{(68.9\ years)}\\
\ce{^{228}_{90}Th ->[\alpha] ^{224}_{88}Ra}\ &\mathrm{(1.9\ year)}\\
\ce{^{224}_{88}Ra ->[\alpha] ^{220}_{86}Rn}\ &\mathrm{(3.6\ day,\ 0.24\ MeV)}\\
\ce{^{220}_{86}Rn ->[\alpha] ^{216}_{84}Po}\ &\mathrm{(55\ s,\ 0.54\ MeV)}\\
\ce{^{216}_{84}Po ->[\alpha] ^{212}_{82}Pb}\ &\mathrm{(0.15\ s)}\\
\ce{^{212}_{82}Pb ->[\beta^-] ^{212}_{83}Bi}\ &\mathrm{(10.64\ h)}\\
\ce{^{212}_{83}Bi ->[\alpha] ^{208}_{81}Tl}\ &\mathrm{(61\ m,\ 0.78\ MeV)}\\
\ce{^{208}_{81}Tl ->[\beta^-] ^{208}_{82}Pb}\ &\mathrm{(3\ m,\ 2.6\ MeV)}\\{}
\end{align}
Thorium-cycle fuels produce hard gamma emissions, which damage electronics, limiting their use in bombs. {{SimpleNuclide|Uranium|232}} cannot be chemically separated from {{SimpleNuclide|Uranium|233}} from used nuclear fuel; however, chemical separation of thorium from uranium removes the decay product {{SimpleNuclide|Thorium|228}} and the radiation from the rest of the decay chain, which gradually build up as {{SimpleNuclide|Thorium|228}} reaccumulates. The contamination could also be avoided by using a molten-salt breeder reactor and separating the {{SimpleNuclide|Protactinium|233}} before it decays into {{SimpleNuclide|Uranium|233}}. The hard gamma emissions also create a radiological hazard which requires remote handling during reprocessing.
Nuclear fuel
As a fertile material thorium is similar to {{SimpleNuclide|Uranium|238}}, the major part of natural and depleted uranium. The thermal neutron absorption cross section (σa) and resonance integral (average of neutron cross sections over intermediate neutron energies) for {{SimpleNuclide|Thorium|232}} are about three and one third times those of the respective values for {{SimpleNuclide|Uranium|238}}.
=Advantages=
The primary physical advantage of thorium fuel is that it uniquely makes possible a breeder reactor that runs with slow neutrons, otherwise known as a thermal breeder reactor. These reactors are often considered simpler than the more traditional fast-neutron breeders. Although the thermal neutron fission cross section (σf) of the resulting {{SimpleNuclide|Uranium|233}} is comparable to {{SimpleNuclide|Uranium|235}} and {{SimpleNuclide|Plutonium|239}}, it has a much lower capture cross section (σγ) than the latter two fissile isotopes, providing fewer non-fissile neutron absorptions and improved neutron economy. The ratio of neutrons released per neutron absorbed (η) in {{SimpleNuclide|Uranium|233}} is greater than two over a wide range of energies, including the thermal spectrum. A breeding reactor in the uranium–plutonium cycle needs to use fast neutrons, because in the thermal spectrum one neutron absorbed by {{SimpleNuclide|Plutonium|239}} on average leads to less than two neutrons.
Thorium is estimated to be about three to four times more abundant than uranium in Earth's crust,{{cite web
|url=http://www.ans.org/pi/ps/docs/ps78.pdf
|publisher=American Nuclear Society
|title=The Use of Thorium as Nuclear Fuel
|date=November 2006
|access-date=2009-03-24
}} although present knowledge of reserves is limited. Current demand for thorium has been satisfied as a by-product of rare-earth extraction from monazite sands. Notably, there is very little thorium dissolved in seawater, so seawater extraction is not viable, as it is with uranium. Using breeder reactors, known thorium and uranium resources can both generate world-scale energy for thousands of years.
Thorium-based fuels also display favorable physical and chemical properties that improve reactor and repository performance. Compared to the predominant reactor fuel, uranium dioxide ({{chem||UO|2}}), thorium dioxide ({{chem|ThO|2}}) has a higher melting point, higher thermal conductivity, and lower coefficient of thermal expansion. Thorium dioxide also exhibits greater chemical stability and, unlike uranium dioxide, does not further oxidize.
Because the {{SimpleNuclide|Uranium|233}} produced in thorium fuels is significantly contaminated with {{SimpleNuclide|Uranium|232}} in proposed power reactor designs, thorium-based used nuclear fuel possesses inherent proliferation resistance. {{SimpleNuclide|Uranium|232}} cannot be chemically separated from {{SimpleNuclide|Uranium|233}} and has several decay products that emit high-energy gamma radiation. These high-energy photons are a radiological hazard that necessitate the use of remote handling of separated uranium and aid in the passive detection of such materials.
The long-term (on the order of roughly {{val|e=3}} to {{val|e=6|u=years}}) radiological hazard of conventional uranium-based used nuclear fuel is dominated by plutonium and other minor actinides, after which long-lived fission products become significant contributors again. A single neutron capture in {{SimpleNuclide|Uranium|238}} is sufficient to produce transuranic elements, whereas five captures are generally necessary to do so from {{SimpleNuclide|Thorium|232}}. 98–99% of thorium-cycle fuel nuclei would fission at either {{SimpleNuclide|Uranium|233}} or {{SimpleNuclide|Uranium|235}}, so fewer long-lived transuranics are produced. Because of this, thorium is a potentially attractive alternative to uranium in mixed oxide (MOX) fuels to minimize the generation of transuranics and maximize the destruction of plutonium.{{cite news |url=http://www.world-nuclear-news.org/ENF_Thorium_test_begins_2106131.html |title=Thorium test begins |publisher=World Nuclear News |date=21 June 2013 |access-date=21 July 2013}}
=Disadvantages=
There are several challenges to the application of thorium as a nuclear fuel, particularly for solid fuel reactors:
In contrast to uranium, naturally occurring thorium is effectively mononuclidic and contains no fissile isotopes; fissile material, generally {{SimpleNuclide|Uranium|233}}, {{SimpleNuclide|Uranium|235}} or plutonium, must be added to achieve criticality. This, along with the high sintering temperature necessary to make thorium-dioxide fuel, complicates fuel fabrication. Oak Ridge National Laboratory experimented with thorium tetrafluoride as fuel in a molten salt reactor from 1964 to 1969, which was expected to be easier to process and separate from contaminants that slow or stop the chain reaction.
In an open fuel cycle (i.e. utilizing {{SimpleNuclide|Uranium|233}} in situ), higher burnup is necessary to achieve a favorable neutron economy. Although thorium dioxide performed well at burnups of 170,000 MWd/t and 150,000 MWd/t at Fort St. Vrain Generating Station and AVR respectively, challenges complicate achieving this in light water reactors (LWR), which compose the vast majority of existing power reactors.
In a once-through thorium fuel cycle, thorium-based fuels produce far less long-lived transuranics than uranium-based fuels,
some long-lived actinide products constitute a long-term radiological impact, especially {{SimpleNuclide|Protactinium|231}} and {{SimpleNuclide|U|233}}. On a closed cycle,{{SimpleNuclide|U|233}} and {{SimpleNuclide|Protactinium|231}} can be reprocessed. {{SimpleNuclide|Protactinium|231}} is also considered an excellent burnable poison absorber in light water reactors.{{cite web
| url= https://reader.elsevier.com/reader/sd/pii/S2452303817300948?token=4F2E1696B49FF3CA878E8D750EE48AEEDBFABFFCB4E165FD88A005ADCB6FC033000971D801EB433E88F72767AB35BF04
| title= Protactinium-231 –New burnable neutron absorber
| date= 11 November 2017 }}
Another challenge associated with the thorium fuel cycle is the comparatively long interval over which {{SimpleNuclide|Thorium|232}} breeds to {{SimpleNuclide|Uranium|233}}. The half-life of {{SimpleNuclide|Protactinium|233}} is about 27 days, which is an order of magnitude longer than the half-life of {{SimpleNuclide|Neptunium|239|link=yes}}. As a result, substantial {{SimpleNuclide|Protactinium|233}} develops in thorium-based fuels. {{SimpleNuclide|Protactinium|233}} is a significant neutron absorber and, although it eventually breeds into fissile {{SimpleNuclide|Uranium|235}}, this requires two more neutron absorptions, which degrades neutron economy and increases the likelihood of transuranic production.
Alternatively, if solid thorium is used in a closed fuel cycle in which {{SimpleNuclide|Uranium|233}} is recycled, remote handling is necessary for fuel fabrication because of the high radiation levels resulting from the decay products of {{SimpleNuclide|Uranium|232}}. This is also true of recycled thorium because of the presence of {{SimpleNuclide|Thorium|228}}, which is part of the {{SimpleNuclide|Uranium|232}} decay sequence. Further, unlike proven uranium fuel recycling technology (e.g. PUREX), recycling technology for thorium (e.g. THOREX) is only under development.
Although the presence of {{SimpleNuclide|Uranium|232}} complicates matters, there are public documents showing that {{SimpleNuclide|Uranium|233}} has been used once in a nuclear weapon test. The United States tested a composite {{SimpleNuclide|Uranium|233}}-plutonium bomb core in the MET (Military Effects Test) blast during Operation Teapot in 1955, though with much lower yield than expected.{{cite web
| url= http://nuclearweaponarchive.org/Usa/Tests/Teapot.html
| title= Operation Teapot
| date= 11 November 2017 | access-date= 11 November 2017 }}
Advocates for liquid core and molten salt reactors such as LFTRs claim that these technologies negate thorium's disadvantages present in solid fuelled reactors. As only two liquid-core fluoride salt reactors have been built (the ORNL ARE and MSRE) and neither have used thorium, it is hard to validate the exact benefits.
Thorium-fueled reactors
Thorium fuels have fueled several different reactor types, including light water reactors, heavy water reactors, high temperature gas reactors, sodium-cooled fast reactors, and molten salt reactors.
{{cite web
|url=http://www.iaea.org/inisnkm/nkm/aws/fnss/fulltext/te_1319_f.pdf
|publisher=International Atomic Energy Agency
|title=IAEA-TECDOC-1319 Thorium Fuel Utilization: Options and trends
|date=November 2002
|access-date=2009-03-24
}}
=List of thorium-fueled reactors=
{{Split section|List of thorium-fueled reactors|discuss={{TALKPAGENAME}}#Split proposed |date=August 2020}}
{{update|date=August 2020}}
From IAEA TECDOC-1450 "Thorium Fuel Cycle – Potential Benefits and Challenges", Table 1: Thorium utilization in different experimental and power reactors. Additionally from Energy Information Administration, "Spent Nuclear Fuel Discharges from U. S. Reactors", Table B4: Dresden 1 Assembly Class.{{cite book|title=Spent Nuclear Fuel Discharges from U. S. Reactors |url=https://books.google.com/books?id=uwJr2SAEdqUC&pg=PA111|access-date=11 June 2012|year=1995 |orig-year=1993|publisher=Energy Information Administration|isbn=978-0-7881-2070-1|page=111}} They were manufactured by General Electric (assembly code XDR07G) and later sent to the Savannah River Site for reprocessing.
class="wikitable sortable" | |||||
style="text-align:center; background:#f0f0f0;"
!Name !Operation period !Country !Power !Fuel | |||||
NRX & NRU | 1947 (NRX) + 1957 (NRU); Irradiation–testing of few fuel elements | {{flagicon|CAN}} Canada | MTR (pin assemblies) | see) | 20 MW; 200 MW (Th+{{SimpleNuclide|Uranium|235}}, Test Fuel |
Dresden Unit 1 | 1960–1978 | {{flagicon|USA}} United States | BWR | 197 MW(e) | ThO2 corner rods, UO2 clad in Zircaloy-2 tube |
CIRUS; DHRUVA; & KAMINI | 1960–2010 (CIRUS); others in operation | {{flagicon|IND}} India | MTR thermal | 40 MWt; 100 MWt; 30 kWt (low power, research) | Al+{{SimpleNuclide|Uranium|233}} Driver fuel, ‘J’ rod of Th & ThO2, ‘J’ rod of ThO2 |
Indian Point Unit 1 | 1962–1965{{cite news |title=Indian Readied for New Uranium |work=Mount Vernon Argus |location=White Plains, New York |date=March 16, 1966 |page=17 |url=https://www.newspapers.com/clip/121388402/indian-readied-for-new-uranium/ |access-date=March 21, 2023}} | {{flagicon|USA}} United States | LWBR, PWR, (pin assemblies) | 285 MW(e) | Th+{{SimpleNuclide|Uranium|235}} Driver fuel, oxide pellets |
BORAX-IV & Elk River Station | 1963–1968 | {{flagicon|USA}} United States | BWR (pin assemblies) | 2.4 MW(e); 24 MW(e) | Th+{{SimpleNuclide|Uranium|235}} Driver fuel oxide pellets |
MSRE ORNL | 1964–1969 | {{flagicon|USA}} United States | MSR | 7.5 MWt | {{SimpleNuclide|Uranium|233}} molten fluorides |
Peach Bottom Unit 1 | 1966–1972 | {{flagicon|USA}} United States | HTGR, Experimental (prismatic block) | 40 MW(e) | Th+{{SimpleNuclide|Uranium|235}} Driver fuel, coated fuel particles, oxide & dicarbides |
Dragon (OECD-Euratom) | 1966–1973 | {{flagicon|GBR}} UK (also {{flagicon|SWE}} Sweden, {{flagicon|NOR}} Norway and {{flagicon|SWI}} Switzerland) | HTGR, Experimental (pin-in-block design) | 20 MWt | Th+{{SimpleNuclide|Uranium|235}} Driver fuel, coated fuel particles, oxide & dicarbides |
AVR | 1967–1988 | {{flagicon|DEU}} Germany (West) | HTGR, experimental (pebble bed reactor) | 15 MW(e) | Th+{{SimpleNuclide|Uranium|235}} Driver fuel, coated fuel particles, oxide & dicarbides |
Lingen | 1968–1973 | {{flagicon|DEU}} Germany (West) | BWR irradiation-testing | 60 MW(e) | Test fuel (Th,Pu)O2 pellets |
SUSPOP/KSTR KEMA | 1974–1977 | {{flagicon|NLD}} Netherlands | Aqueous homogeneous suspension (pin assemblies) | 1 MWt | Th+HEU, oxide pellets |
Fort St Vrain | 1976–1989 | {{flagicon|USA}} United States | HTGR, Power (prismatic block) | 330 MW(e) | Th+{{SimpleNuclide|Uranium|235}} Driver fuel, coated fuel particles, Dicarbide |
Shippingport | 1977–1982 | {{flagicon|USA}} United States | LWBR, PWR, (pin assemblies) | 100 MW(e) | Th+{{SimpleNuclide|Uranium|233}} Driver fuel, oxide pellets |
KAPS 1 &2; KGS 1 & 2; RAPS 2, 3 & 4 | 1980 (RAPS 2) +; continuing in all new PHWRs | {{flagicon|IND}} India | PHWR, (pin assemblies) | 220 MW(e) | ThO2 pellets (for neutron flux flattening of initial core after start-up) |
FBTR | 1985; in operation | {{flagicon|IND}} India | LMFBR, (pin assemblies) | 40 MWt | ThO2 blanket |
THTR-300 | 1985–1989 | {{flagicon|DEU}} Germany (West) | HTGR, power (pebble type) | 300 MW(e) | Th+{{SimpleNuclide|Uranium|235}} Driver fuel, coated fuel particles, oxide & dicarbides |
TMSR-LF1 | 2023; operating license issued | {{flagicon|CHN}} China | Liquid fuel thorium-based molten salt experimental reactor | 2 MWt | Thorium-based molten salt |
Petten | 2024; planned | {{flagicon|NLD}} Netherlands | High Flux Reactor thorium molten salt experiment | 45 MW(e) | ? |
SINAP | 2030; planned{{cite web |title=Why China is building a thorium molten-salt reactor |url=https://spectrum.ieee.org/chinas-thorium-molten-salt-reactor |website=IEEE Spectrum |access-date=24 January 2025}} | {{flagicon|CHN}} China | thorium-based molten-salt reactor | 10 MWt | Thorium-based molten salt |
See also
{{Portal inline|Nuclear technology}}
{{Portal inline|Energy}}
{{colbegin}}
- Thorium
- Thorium-232
- Occurrence of thorium
- Thorium-based nuclear power
- List of countries by thorium resources
- List of countries by uranium reserves
- Advanced heavy-water reactor
- Alvin Radkowsky
- CANDU reactor
- Fuji MSR
- Peak uranium
- Radioactive waste
- Thorium Energy Alliance
- Weinberg Foundation
- World energy resources and consumption
{{colend}}
References
{{Reflist|30em}}
Further reading
- Kasten, P. R. (1998). "[http://www.princeton.edu/sgs/publications/sgs/pdf/7_3kasten.pdf Review of the Radkowsky Thorium reactor concept]" Science & Global Security, 7(3), 237–269.
- Duncan Clark (9 September 2011), "[https://www.theguardian.com/environment/blog/2011/sep/09/thorium-weinberg-foundation Thorium advocates launch pressure group. Huge optimism for thorium nuclear energy at the launch of the Weinberg Foundation]", The Guardian
- {{Cite journal | doi = 10.1177/0096340212459125| title = Thorium: Not a near-term commercial nuclear fuel| journal = Bulletin of the Atomic Scientists| volume = 68| issue = 5| pages = 33–44| year = 2012| last1 = Nelson | first1 = A. T.| url = https://zenodo.org/record/1235552| bibcode = 2012BuAtS..68e..33N| s2cid = 144725888}}
- B.D. Kuz'minov, V.N. Manokhin, (1998) [http://www.iaea.org/inis/collection/NCLCollectionStore/_Public/29/062/29062826.pdf "Status of nuclear data for the thorium fuel cycle"], IAEA translation from the Russian journal Yadernye Konstanty (Nuclear Constants) Issue No. 3–4, 1997
- [https://www.gov.uk/government/publications/thorium-and-uranium-fuel-cycles-comparison-by-the-national-nuclear-laboratory Thorium and uranium fuel cycles] comparison by the UK National Nuclear Laboratory
- [http://www.world-nuclear.org/info/inf62.html Fact sheet on thorium] {{Webarchive|url=https://web.archive.org/web/20130216102005/http://www.world-nuclear.org/info/inf62.html |date=2013-02-16 }} at the World Nuclear Association.
- [http://alsos.wlu.edu/qsearch.aspx?browse=science/Thorium Annotated bibliography for the thorium fuel cycle] {{Webarchive|url=https://web.archive.org/web/20101007075709/http://alsos.wlu.edu/qsearch.aspx?browse=science%2FThorium |date=2010-10-07 }} from the Alsos Digital Library for Nuclear Issues
External links
- [http://www.ithec.org/ International Thorium Energy Committee]