ammonium phosphate

{{Chembox

| Verifiedfields = changed

| Watchedfields = changed

| verifiedrevid = 428203184

| ImageFile = Ammonium phosphate.png

| ImageFile1 = Triammonium-phosphate-3D-balls.png

| ImageSize1 = 240px

| ImageName1 = Ball-and-stick model of three ammonium cations and one phosphate anion

| Reference =

{{cite book | last = Lide | first = David R. | year = 1998

| title = Handbook of Chemistry and Physics

| edition = 87 | volume =

| location = Boca Raton, Florida

| publisher = CRC Press

| isbn = 978-0-8493-0594-8 | pages = 4–42, 5–19}}

| IUPACName = ammonium phosphate

| OtherNames = triammonium phosphate

|Section1={{Chembox Identifiers

| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}

| ChemSpiderID = 140090

| InChI = 1/3H3N.H3O4P/c;;;1-5(2,3)4/h3*1H3;(H3,1,2,3,4)

| InChIKey = ZRIUUUJAJJNDSS-UHFFFAOYAA

| StdInChI_Ref = {{stdinchicite|correct|chemspider}}

| StdInChI = 1S/3H3N.H3O4P/c;;;1-5(2,3)4/h3*1H3;(H3,1,2,3,4)

| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}

| StdInChIKey = ZRIUUUJAJJNDSS-UHFFFAOYSA-N

| CASNo_Comment = {{cascite|correct|CAS}}

| CASNo = 10361-65-6

| EC_number = 269-789-9

| UNII_Ref = {{fdacite|changed|FDA}}

| UNII = 2ZJF06M0I9

| PubChem = 159282

| SMILES = [O-]P([O-])([O-])=O.[NH4+].[NH4+].[NH4+]

}}

|Section2={{Chembox Properties

| Formula = (NH4)3PO4

| Appearance = White, tetrahedral crystals

| Density =

| MeltingPt =

| BoilingPt =

| Solubility = 58.0 g/100 mL (25 °C)

| SolubleOther = Insoluble in acetone{{cite book |author1=John Rumble |title=CRC Handbook of Chemistry and Physics |date=June 18, 2018 |publisher=CRC Press |isbn=978-1138561632 |pages=4–41|edition=99th |language=English}}

| MolarMass=149.09 g/mol}}

|Section3={{Chembox Hazards

| GHSPictograms = {{GHS07}}

| GHSSignalWord = Warning

| HPhrases = {{H-phrases|302|319}}

| PPhrases = {{P-phrases|264|270|280|301+312|305+351+338|330|337+313|501}}

| NFPA-H = 2

| NFPA-F = 0

| NFPA-R = 0

| MainHazards =

| FlashPt =

| AutoignitionPt = }}

|Section4={{Chembox Thermochemistry

| DeltaHf = −1671.9 kJ/mol

| DeltaHc =

| Entropy =

| HeatCapacity = }}

|Section8={{Chembox Related

| OtherCations = Trisodium phosphate
Tripotassium phosphate

| OtherCompounds = Diammonium phosphate
Monoammonium phosphate

}}

}}

Ammonium phosphate is the inorganic compound with the formula (NH4)3PO4. It is the ammonium salt of orthophosphoric acid. A related "double salt", (NH4)3PO4.(NH4)2HPO4 is also recognized but is impractical to use. Both triammonium salts evolve ammonia. In contrast to the unstable nature of the triammonium salts, the diammonium phosphate (NH4)2HPO4 and monoammonium salt (NH4)H2PO4 are stable materials that are commonly used as fertilizers to provide plants with fixed nitrogen and phosphorus.{{Ullmann|first1=Klaus|last1=Schrödter|first2=Gerhard|last2=Bettermann|first3=Thomas |last3=Staffel|first4=Friedrich|last4=Wahl|first5=Thomas|last5=Klein||first6=Thomas|last6=Hofmann|title=Phosphoric Acid and Phosphates|year=2008|doi=10.1002/14356007.a19_465.pub3}}

Ammonium phosphate is the main ingredient in pink fire retardant. {{Cite web |last=Press • • |first=Tammy Webber {{!}} The Associated |date=2025-01-14 |title=What to know about the pink flame retardants are being used for California fires |url=https://www.nbclosangeles.com/news/local/pink-flame-retardants-california-wildfires/3604543/ |access-date=2025-01-15 |website=NBC Los Angeles |language=en-US}}

Preparation of triammonium phosphate

Triammonium phosphate can be prepared in the laboratory by treating 85% phosphoric acid with 30% ammonia solution:{{cn|date=April 2019}}

:H3PO4 + 3 NH3 → (NH4)3PO4

(NH4)3PO4 is a colorless, crystalline solid. The solid, which has the odor of ammonia, is readily soluble in water. The salt converts to diammonium hydrogen phosphate (NH4)2HPO4.

See also

References

{{Reflist}}

{{Ammonium salts}}

{{Phosphates}}

Category:Phosphates

Category:Ammonium compounds

Category:Inorganic fertilizers

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