caesium sulfate
{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 405204542
| Reference = {{RubberBible62nd|page=B-92}}.
| ImageFile1 = Caesium-sulfate-2D-structure.svg
| ImageFile2 = Structure of K2SO4, K2CrO4 and some related compounds.tif
| Name = Caesium sulfate
| OtherNames = Cesium sulfate
|Section1={{Chembox Identifiers
| InChI = 1/2Cs.H2O4S/c;;1-5(2,3)4/h;;(H2,1,2,3,4)/q2*+1;/p-2
| SMILES = [Cs+].[Cs+].[O-]S([O-])(=O)=O
| InChIKey = FLJPGEWQYJVDPF-NUQVWONBAO
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/2Cs.H2O4S/c;;1-5(2,3)4/h;;(H2,1,2,3,4)/q2*+1;/p-2
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = FLJPGEWQYJVDPF-UHFFFAOYSA-L
| CASNo = 10294-54-9
| CASNo_Ref = {{cascite|correct|CAS}}
| PubChem = 25137
| UNII_Ref = {{fdacite|changed|FDA}}
| UNII = 8D6R91CS62
| EC_number = 233-662-6
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 23482
}}
|Section2={{Chembox Properties
| Formula = Cs2SO4
| MolarMass = 361.87 g/mol
| Density = 4.243 g/cm3, solid
| MeltingPtC = 1010
| Solubility = 167 g/100 ml (0 °C)
179 g/100 ml (20 °C)
| SolubleOther = insoluble in ethanol, acetone
| MagSus = −116.0·10−6 cm3/mol
}}
|Section7={{Chembox Hazards
| FlashPt = Non-flammable
| LD50 = 2830 mg/kg (oral, rat)https://chem.nlm.nih.gov/chemidplus/rn/10294-54-9 {{Dead link|date=March 2022}}
| GHSSignalWord = Warning
| GHSPictograms = {{GHS07}}{{GHS08}}
| HPhrases = {{H-phrases|302|361|412}}
| PPhrases = {{P-phrases|201|202|264|270|273|281|301+312|308+313|330|405|501}}
}}
|Section8={{Chembox Related
| OtherAnions = Caesium hydrogen sulfate
| OtherCations = Lithium sulfate
Sodium sulfate
Potassium sulfate
Rubidium sulfate
}}
}}
Caesium sulfate or cesium sulfate is the inorganic compound and salt with the formula Cs2SO4. It is a white water-soluble solid that is used to prepare dense aqueous solutions for use in isopycnic (or "density-gradient") centrifugation. It is isostructural with potassium salt.Nord, A.G. "The crystal structure of cesium sulfate, beta-Cs2SO4" Acta Chemica Scandinavica, Series A: 1976, 30, p198.
File:TopView10cnK.tif|Coordination sphere of one of two types of Cs+ site in Cs2SO4.
File:SO4sphere.tif|Environment of sulfate anion in β-Cs2SO4.
References
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External links
- [https://web.archive.org/web/20110708141703/http://www.specialmetals.chemetall.com/pdf/Cesium_Sulfate_9999.pdf Caesium sulfate data sheet from Chemetall]
{{Caesium compounds}}
{{Sulfates}}
{{sulfur compounds}}