iodine monoxide
{{about|the compound IO|the oxoanion with the formula IO−|hypoiodite|the molecule I2O|Diiodine monoxide}}
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| ImageAlt =
| ImageFile = Iodine-monoxide-3D-vdW.png
| ImageSize = 150px
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| OtherNames = Iodine(II) oxide, iodosyl, oxidoiodine
|Section1={{Chembox Identifiers
| CASNo = 14696-98-1
| CASNo_Ref = {{cascite|correct|CAS}}
| ChemSpiderID = 4574060
| UNII_Ref = {{fdacite|changed|FDA}}
| DTXSID = 101316449
| UNII =
| ChEBI = 29896
| EINECS =
| Gmelin = 1170
| PubChem = 5460557
| StdInChI = 1S/IO/c1-2
| StdInChIKey = AFSVSXMRDKPOEW-UHFFFAOYSA-N
| SMILES = [O]I
}}
|Section2={{Chembox Properties
| I=1 | O=1
| Appearance = purple gas{{cn|date=March 2023}}
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|Section3={{Chembox Hazards
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|Section6={{Chembox Related
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Iodine monoxide is a binary inorganic compound of iodine and oxygen with the chemical formula IO•. A free radical, this compound is the simplest of many iodine oxides.{{cite journal |last1=Dix |first1=Barbara |last2=Baidar |first2=Sunil |last3=Bresch |first3=James F. |last4=Hall |first4=Samuel R. |last5=Schmidt |first5=K. Sebastian |last6=Wang |first6=Siyuan |last7=Volkamer |first7=Rainer |title=Detection of iodine monoxide in the tropical free troposphere |journal=Proceedings of the National Academy of Sciences |date=5 February 2013 |volume=110 |issue=6 |pages=2035–2040 |doi=10.1073/pnas.1212386110 |language=en |issn=0027-8424|doi-access=free |pmc=3568334 }}{{cite web |title=Iodine oxide |url=https://webbook.nist.gov/cgi/inchi/InChI%3D1S/IO/c1-2 |publisher=NIST |language=en}}{{cite book |last1=Haynes |first1=William M. |title=CRC Handbook of Chemistry and Physics, 96th Edition |date=9 June 2015 |publisher=CRC Press |isbn=978-1-4822-6097-7 |page=2-17 |url=https://books.google.com/books?id=RpLYCQAAQBAJ&dq=iodine+monoxide+IO&pg=SA2-PA17 |access-date=27 March 2023 |language=en}} It is similar to the oxygen monofluoride, chlorine monoxide and bromine monoxide radicals.
Synthesis
Iodine monoxide can be obtained by the reaction between iodine and oxygen:{{cite web |last1=Nikitin |first1=I. V. |title=HALOGEN MONOXIDES |url=https://www.uspkhim.ru/RCR3788pdf |publisher=Institute of Problems of Chemical Physics, Russian Academy of Sciences |access-date=27 March 2023 |language=ru |date=13 March 2008}}
: {{chem2|I2 + O2 -> 2 IO}}
Chemical properties
Iodine monoxide decomposes to its prime elements:{{citation needed|date=May 2023}}
:{{chem2|2 IO -> I2 + O2}}
:{{chem2|2 IO + 2 NO -> I2 + 2 NO2}}
Atmosphere
Atmospheric iodine atoms (e.g. from iodomethane) can react with ozone to produce the iodine monoxide radical:{{cite web |title=The Atmospheric Chemistry of Iodine Monoxide |url=https://www.nist.gov/system/files/documents/el/fire_research/R0000232.pdf |publisher=NIST |access-date=27 March 2023}}
:{{chem2|I2 + 2 O3 -> 2 IO + 2 O2 }}
This process can contribute to ozone depletion.{{citation needed|date=May 2023}}
References
{{Reflist}}
{{Oxides}}
{{Iodine compounds}}