mercury(I) nitrate
{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 428718366
| Name = Mercury(I) nitrate
| ImageFile = Mercury(I) nitrate dihydrate.ვკ.jpg
| ImageSize =
| ImageName =
| IUPACName = Mercury(I) nitrate
| OtherNames = Mercurous nitrate
{{Citation
| last = Lide
| first = David R.
| author-link =
| year = 1998
| title = Handbook of Chemistry and Physics
| edition = 87
| volume =
| series =
| location = Boca Raton, Florida
| publisher = CRC Press
| id =
| isbn = 0-8493-0594-2
| doi =
| oclc =
| pages = 4–45
| url =
| accessdate =
}}
| Section1 = {{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 10415-75-5
| index_label = (anhydrous)
| CASNo2_Ref = {{cascite|correct|CAS}}
| CASNo2 = 14836-60-3
| index2_label = (dihydrate)
| ChemSpiderID = 23580
| ChemSpiderID2 = 9493944
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = J78005WL7R
| UNII2_Ref = {{fdacite|correct|FDA}}
| UNII2 = Z92K1EV5HQ
| PubChem = 25247
| UNNumber = 1627
| InChI = 1S/Hg.NO3/c;2-1(3)4/q+1;-1
| InChIKey = DRXYRSRECMWYAV-UHFFFAOYSA-N
| InChI2=1S/2Hg.2NO3.2H2O/c;;2*2-1(3)4;;/h;;;;2*1H2/q2*+1;2*-1;;
| InChIKey2 = LSABZDVKJBWCBE-UHFFFAOYSA-N
| SMILES = [N+](=O)([O-])[O-].[Hg+][Hg+].[N+](=O)([O-])[O-]
| SMILES2 = [N+](=O)([O-])[O-].[OH2+][Hg][Hg][OH2+].[N+](=O)([O-])[O-]
| RTECS =
| EINECS = 233-886-4
}}
| Section2 = {{Chembox Properties
| Formula = Hg2(NO3)2 (anhydrous)
Hg2(NO3)2·2H2O (dihydrate)
| MolarMass = 525.19 g/mol (anhydrous)
561.22 g/mol (dihydrate)
| Appearance = white monoclinic crystals (anhydrous)
colorless crystals (dihydrate)
| Density = ? g/cm3 (anhydrous)
4.8 g/cm3 (dihydrate)
| MeltingPt = ? (anhydrous)
decomposes at 70 °C (dihydrate)
| BoilingPt =
| Solubility = slightly soluble, reacts
| SolubleOther =
| MagSus = −27.95·10−6 cm3/mol
}}
| Section3 = {{Chembox Structure
| Coordination =
| CrystalStruct =
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| Section7 = {{Chembox Hazards
| GHSPictograms = {{GHS06}}{{GHS08}}{{GHS09}}
| GHSSignalWord = Danger
| HPhrases = {{H-phrases|300|310|330|373|410}}
| PPhrases = {{P-phrases|260|262|264|270|271|273|280|284|301+316|302+352|304+340|316|319|320|321|330|361+364|391|403+233|405|501}}
| ExternalSDS =
| NFPA-H = 3
| NFPA-F = 1
| NFPA-R = 1
| NFPA-S = OX
| FlashPt =
}}
| Section8 = {{Chembox Related
| OtherAnions = Mercury(I) fluoride
Mercury(I) chloride
Mercury(I) bromide
Mercury(I) iodide
| OtherCations = Mercury(II) nitrate
}}
}}
Mercury(I) nitrate is an inorganic compound, a salt of mercury and nitric acid with the formula Hg2(NO3)2. A yellow solid, the compound is used as a precursor to other Hg22+ complexes. The structure of the hydrate has been determined by X-ray crystallography. It consists of a [H2O-Hg-Hg-OH2]2+ center, with a Hg-Hg distance of 254 pm.{{cite journal |journal=Journal of the Chemical Society|title=The crystal Structure of Mercurous Nitrate Dihydrate|author=D. Grdenić|doi=10.1039/jr9560001312|year=1956|pages=1312–1316 }}
It was first mentioned by Prafulla Chandra Ray in 1896.{{Cite journal |last=Samanta |first=Subhas |last2=Goswami |first2=Sreebrata |last3=Chakravorty |first3=Animesh |date=February 2011 |title=On mercurous nitrite and a basic mercurous nitrate derivative |url=http://nopr.niscair.res.in/bitstream/123456789/11011/1/IJCA%2050A(2)%20137-140.pdf |journal=Indian Journal of Chemistry |volume=50A |issue=2 |pages=137-140 |issn=0975-0975}}
Reactions
Mercury(I) nitrate is formed when elemental mercury is combined with dilute nitric acid (concentrated nitric acid will yield mercury(II) nitrate). Mercury(I) nitrate is a reducing agent which is oxidized upon contact with air.
Mercuric(II) nitrate reacts with elemental mercury(0) to form mercurous(I) nitrate (comproportionation reaction):{{Citation needed|date=June 2017}}
: {{chem2|Hg(NO3)2 + Hg ⇌ Hg2(NO3)2}}
Solutions of mercury(I) nitrate are acidic due to slow reaction with water:
:Hg2(NO3)2 + H2O ⇌ Hg2(NO3)(OH) + HNO3
Hg2(NO3)(OH) forms a yellow precipitate.
If the solution is boiled, or exposed to light, mercury(I) nitrate undergoes a disproportionation reaction yielding elemental mercury and mercury(II) nitrate:
{{Citation
| last =Patnaik
| first =Pradyot
| author-link =
| year = 2003
| title =Handbook of Inorganic Chemical Compounds
| edition =
| volume =
| series =
| location =
| place =
| publisher = McGraw-Hill Professional
| pages = 573
| id =
| isbn =0-07-049439-8
| doi =
| oclc =
| url= https://books.google.com/books?id=Xqj-TTzkvTEC&q=%22Manganese%28II%29+acetate%22&pg=PA552
| accessdate = 2009-07-20
}}
: {{chem2|Hg2(NO3)2 ⇌ Hg + Hg(NO3)2}}
These reactions are reversible; the nitric acid formed can redissolve the basic salt.{{Citation needed|date=June 2017}}
References
{{reflist}}
{{Mercury compounds}}
{{nitrates}}
{{DEFAULTSORT:Mercury(I) Nitrate}}
Category:Chemical compounds containing metal–metal bonds
{{inorganic-compound-stub}}