mohs scale

{{short description|Qualitative scale characterizing scratch resistance}}

{{use dmy dates|date=August 2024}}

File:Mohssche-haerteskala hg.jpg

The Mohs scale ({{IPAc-en|m|ou|z}} {{respell|MOHZ}}) of mineral hardness is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of minerals through the ability of harder material to scratch softer material.

The scale was introduced in 1812 by the German geologist and mineralogist Friedrich Mohs, in his book {{lang|de|Versuch einer Elementar-Methode zur naturhistorischen Bestimmung und Erkennung der Fossilien}} (English: Attempt at an elementary method for the natural-historical determination and recognition of fossils);{{cite book | title=Entwicklungsgeschichte der Mineralogischen Wissenschaften | trans-title=History of the development of the mineralogical sciences | url=https://books.google.com/books?id=tD0LAQAAIAAJ&q=+Härteskala+1812 | publisher=Springer | last=von Groth | first=Paul Heinrich | date=1926 | publication-place=Berlin | page=250 | isbn=9783662409107 | lang=de }}{{cite encyclopedia |url=https://www.britannica.com/EBchecked/topic/387714/Mohs-hardness |title=Mohs hardness |encyclopedia=Encyclopædia Britannica |edition=online }}{{efn|

: {{lang|de|In demselben Jahre (1812) wurde MOHS als Professor am Joanneum angestellt und veröffentliche den ersten Teil seines Werkes {{noitalic|Versuch einer Elementarmethode zur naturhistorischen Bestimmung und Erkennung der Fossilien}}, in welcher die bekannte Härteskala aufgestellt wurde.}} — {{harvp|von Groth|1926}}

:  

: In the same year (1812) MOHS was employed as a professor at the Joanneum and published the first part of his work Attempt at an elementary method for the natural-historical determination and recognition of fossils, in which the well-known hardness scale was set up.

}} it is one of several definitions of hardness in materials science, some of which are more quantitative.{{cite web |title=Mohs scale of hardness |publisher=Mineralogical Society of America |url=http://www.minsocam.org/MSA/collectors_corner/article/mohs.htm |access-date=10 February 2021}}

The method of comparing hardness by observing which minerals can scratch others is of great antiquity, having been mentioned by Theophrastus in his treatise On Stones, {{circa| 300 BC}}, followed by Pliny the Elder in his Naturalis Historia, {{circa| AD 77}}.{{cite book |url=http://www.farlang.com/gemstones/theophrastus-on-stones/page_148/view?searchterm=scratch |title=Theophrastus on Stones |author=Theophrastus |via=Farlang.com |access-date=2011-12-10}}{{cite book |author=Pliny the Elder |title=Naturalis Historia |chapter=Book 37, Chap. 15 |chapter-url=https://www.perseus.tufts.edu/cgi-bin/ptext?lookup=Plin.+Nat.+37.15 |quote=Adamas: Six varieties of it. Two remedies.}}{{cite book |author=Pliny the Elder |title=Naturalis Historia |chapter=Book 37, Chap. 76 |chapter-url=https://www.perseus.tufts.edu/cgi-bin/ptext?lookup=Plin.+Nat.+37.76 |quote=The methods of testing precious stones.}} The Mohs scale is useful for identification of minerals in the field, but is not an accurate predictor of how well materials endure in an industrial setting.{{cite web |url=http://www.ndt-ed.org/EducationResources/CommunityCollege/Materials/Mechanical/Hardness.htm |title=Hardness |archive-url=https://web.archive.org/web/20140214185403/http://www.ndt-ed.org/EducationResources/CommunityCollege/Materials/Mechanical/Hardness.htm |archive-date=2014-02-14 |publisher=Non-Destructive Testing Resource Center |series=Materials Mechanical Hardness}}

Reference minerals

The Mohs scale of mineral hardness is based on the ability of one natural sample of mineral to visibly scratch another mineral. Minerals are chemically pure solids found in nature. Rocks are mixtures of one or more minerals.

:

style="float:right;border:none;background:white;margin-left:2em"
style="text-align:center;"

| File:Mohs scale vs absolute hardness.png

style="padding-left:2em;"| Mohs scale along the horizontal axis matched with
one of the absolute hardness scales along the
vertical. Vertical scale is logarithmic.

Diamond was the hardest known naturally occurring mineral when the scale was designed, and defines the top of the scale, arbitrarily set at 10. The hardness of a material is measured against the scale by finding the hardest material that the given material can scratch, or the softest material that can scratch the given material. For example, if some material is scratched by apatite but not by fluorite, its hardness on the Mohs scale would be between 4 and 5.{{cite web |title=Mohs scale of mineral hardness |publisher=American Federation of Mineralogical Societies |url=https://www.amfed.org/mohs-scale |via=amfed.org |access-date= }}

Technically, "scratching" a material for the purposes of the Mohs scale means creating non-elastic dislocations visible to the naked eye. Frequently, materials that are lower on the Mohs scale can create microscopic, non-elastic dislocations on materials that have a higher Mohs number. While these microscopic dislocations are permanent and sometimes detrimental to the harder material's structural integrity, they are not considered "scratches" for the determination of a Mohs scale number.{{cite report |last=Geels |first=Kay |publication-date=26 April 2000 |section=The true microstructure of materials |pages=5–13 |title=Materialographic Preparation from Sorby to the Present |department=Application notes and guides |series=The Struers metallographic library |publisher=Struers A/S |place=Copenhagen, DK |url=http://www.struers.com/resources/elements/12/2474/35art2.pdf |url-status=dead |archive-url=https://web.archive.org/web/20160307194802/http://www.struers.com/resources/elements/12/2474/35art2.pdf |archive-date=7 March 2016 }}

Each of the ten hardness values in the Mohs scale is represented by a reference mineral, most of which are widespread in rocks.

The Mohs scale is an ordinal scale. For example, corundum (9) is twice as hard as topaz (8), but diamond (10) is four times as hard as corundum.{{fact|date=October 2024}} The table below shows the comparison with the absolute hardness measured by a sclerometer, with images of the reference minerals in the rightmost column.{{cite web |title=What is important about hardness? |department=Amethyst galleries |series=Mineral gallery |url=http://www.galleries.com/minerals/hardness.htm |url-status=dead |access-date= |via=galleries.com |archive-url=https://web.archive.org/web/20061230174242/http://www.galleries.com/minerals/hardness.htm |archive-date=30 December 2006 }}{{cite web |title=Mineral hardness and hardness scales |publisher=Inland Lapidary |url=http://www.inlandlapidary.com/user_area/hardness.asp |via=inlandlapidary.com |url-status=live |access-date= |archive-url=https://web.archive.org/web/20081017152845/http://www.inlandlapidary.com/user_area/hardness.asp |archive-date=2008-10-17 }}

:

class="wikitable sortable" style="text-align:center"
Mohs
hardness

! Reference
mineral

! Chemical formula

! Absolute
hardness{{cite book |last=Mukherjee |first=Swapna |year=2012 |title=Applied Mineralogy: Applications in industry and environment |publisher=Springer Science & Business Media |isbn=978-94-007-1162-4 |page=373 |url=https://books.google.com/books?id=mllvP7ZmWqkC&pg=PA373 |via=Google books}}

!class="unsortable"| Example image

1

| Talc

| {{chem2| Mg3Si4O10(OH)2 }}

| 1

| 100px

2

| Gypsum

| {{chem2| CaSO4*2H2O }}

| 2

| 100px

3

| Calcite

| {{chem2| CaCO3 }}

| 14

| 100px

4

| Fluorite

| {{chem2| CaF2 }}

| 21

| 100px

5

| Apatite

| {{chem2| Ca5(PO4)3(OH,Cl,F) }}

| 48

| 100px

6

| Orthoclase
feldspar

| {{chem2| KAlSi3O8 }}

| 72

| 100px

7

| Quartz

| {{chem2| SiO2 }}

| 100

| 100px

8

| Topaz

| {{chem2| Al2SiO4(OH,F)2 }}

| 200

| 100px

9

| Corundum

| {{chem2| Al2O3 }}

| 400

| 100px

10

| Diamond

| {{chem2| C }}

| 1500

| 100px

Examples

{{More citations needed|section|date=November 2022}}

Below is a table of more materials by Mohs scale. Some of them have a hardness between two of the Mohs scale reference minerals. Some solid substances that are not minerals have been assigned a hardness on the Mohs scale. Hardness may be difficult to determine, or may be misleading or meaningless, if a material is a mixture of two or more substances; for example, some sources have assigned a Mohs hardness of 6 or 7 to granite but it is a rock made of several minerals, each with its own Mohs hardness (e.g. topaz-rich granite contains: topaz — Mohs 8, quartz — Mohs 7, orthoclase — Mohs 6, plagioclase — Mohs 6–6.5, mica — Mohs 2–4).

:

class="wikitable"
Hardness

! Substance

style="text-align:center;"| 0.2–0.4

| Potassium{{cite book | editor-last=Samsonov | editor-first=G.V. | year=1968 | chapter=Mechanical properties of the elements | title=Handbook of the Physicochemical Properties of the Elements | publisher=IFI-Plenum | place=New York, NY | doi=10.1007/978-1-4684-6066-7 | isbn=978-1-4684-6068-1 | page=432 }}

style="text-align:center;"| 0.5–0.6

| Lithium

style="text-align:center;"| 1

| Talc

style="text-align:center;"| 1.5

| Lead

style="text-align:center;"| 2

| Hardwood{{Cite web|title=Mohs Hardness Scale: Testing the Resistance to Being Scratched|url=https://geology.com/minerals/mohs-hardness-scale.shtml|access-date=2021-08-09|website=geology.com}}

style="text-align:center;"| 2–2.5

| Plastic

style="text-align:center;"| 2.5

| Zinc

style="text-align:center;"| 2.5–3

| Copper

style="text-align:center;"| 3

| Brass

style="text-align:center;"| 3.5

| Adamite

style="text-align:center;"| 3.5-4

| Sphalerite

style="text-align:center;"| 4

| Iron

style="text-align:center;"| 4–4.5

| Ordinary steel

style="text-align:center;"| 4.5

| Colemanite

style="text-align:center;"| 5

| Apatite

style="text-align:center;"| 5-5.5

| Goethite

style="text-align:center;"| 5.5

| Glass

style="text-align:center;"| 5.5–6

| Opal

style="text-align:center;"| 6

| Rhodium

style="text-align:center;"| 6-6.5

| Rutile

style="text-align:center;"| 6.5

| Silicon

style="text-align:center;"| 6.5–7

| Jadeite

style="text-align:center;"| 7

| Porcelain

style="text-align:center;"| 7-7.5

| Garnet

style="text-align:center;"| 7.5

| Tungsten

style="text-align:center;"| 7.5–8

| Emerald

style="text-align:center;"| 8

| Topaz

style="text-align:center;"| 8.5

| Chromium

style="text-align:center;"| 9

| Sapphire

style="text-align:center;"| 9–9.5

| Moissanite

style="text-align:center;"| 9.5–near 10

| Boron

style="text-align:center;"| 10

| Diamond

Use

Despite its lack of precision, the Mohs scale is relevant for field geologists, who use it to roughly identify minerals using scratch kits. The Mohs scale hardness of minerals can be commonly found in reference sheets.

Mohs hardness is useful in milling. It allows the assessment of which type of mill and grinding medium will best reduce a given product whose hardness is known.{{cite web |title=Size reduction, comminution |series=Grinding and milling |publisher=PowderProcess.net |url=http://www.powderprocess.net/Grinding_Milling.html |access-date=27 October 2017}}

Electronic manufacturers use the scale for testing the resilience of flat panel display components (such as cover glass for LCDs or encapsulation for OLEDs), as well as to evaluate the hardness of touch screens in consumer electronics.{{cite magazine |last=Purdy |first=Kevin |date=16 May 2014 |title=Hardness is not toughness: Why your phone's screen may not scratch, but will shatter |magazine=Computerworld |publisher=IDG Communications Inc. |url=https://www.computerworld.com/article/2833434/hardness-is-not-toughness--why-your-phone-s-screen-may-not-scratch--but-will-shatter.html |access-date=16 April 2021}}

Comparison with Vickers scale

Comparison between Mohs hardness and Vickers hardness:{{cite web |last=Ralph |first=Jolyon |title=Welcome to mindat.org |website=mindat.org |publisher=Hudson Institute of Mineralogy |url=https://www.mindat.org/ |access-date=April 16, 2017}}

:

class="wikitable" style="text-align:center"
Mineral
name

! Hardness (Mohs)

! Hardness (Vickers)
(kg/mm{{sup|2}})

Tin1.5VHN{{sub|10}} = 7–9
Bismuth2–2.5VHN{{sub|100}} = 16–18
Gold2.5VHN{{sub|10}} = 30–34
Silver2.5VHN{{sub|100}} = 61–65
Chalcocite2.5–3VHN{{sub|100}} = 84–87
Copper2.5–3VHN{{sub|100}} = 77–99
Galena2.5VHN{{sub|100}} = 79–104
Sphalerite3.5–4VHN{{sub|100}} = 208–224
Heazlewoodite4VHN{{sub|100}} = 230–254
Goethite5–5.5VHN{{sub|100}} = 667
Chromite5.5VHN{{sub|100}} = 1,278–1,456
Anatase5.5–6VHN{{sub|100}} = 616–698
Rutile6–6.5VHN{{sub|100}} = 894–974
Pyrite6–6.5VHN{{sub|100}} = 1,505–1,520
Bowieite7VHN{{sub|100}} = 858–1,288
Euclase7.5VHN{{sub|100}} = 1,310
Chromium8.5VHN{{sub|100}} = 1,875–2,000

Footnotes

{{notelist}}

See also

References

{{reflist|25em}}

Further reading

  • {{cite magazine |last=Cordua |first=William S. |year=c. 1990 |title=The hardness of minerals and rocks |magazine=Lapidary Digest |url=http://www.gemcutters.org/LDA/hardness.htm |via=gemcutters.org }}
  • {{Cite book |last=Raden |first=Aja |year=2016 |title=Gem: The definitive visual guide |publisher=DK Publishing |isbn=9781465453563 |location=New York, NY |lang=en }}

{{Mohs}}

{{Mineral identification}}

Category:Materials science

Category:Mineralogy

Category:Hardness tests

Category:1812 in science

Category:1812 in the Confederation of the Rhine

de:Härte#Härteprüfung nach Mohs