textile bleaching

Bleaching can be dated back to at least 1000BC from an Egyptian list found in the tomb of Rekh-mi-re at Thebes, which mentioned both bleached and unbleached linen.{{Cite book |last1=Nicholson |first1=Paul T. |url=https://books.google.com/books?id=Vj7A9jJrZP0C&pg=PA280 |title=Ancient Egyptian Materials and Technology |last2=Shaw |first2=Ian |date=2000-03-23 |publisher=Cambridge University Press |others=citing N Davies "The Tomb of Rekh-mi-re at Thebes" 1943, p.47 |isbn=978-0-521-45257-1 |pages=280 |language=en}} Mulrooney dates it back as far as 5000BC,{{Cite web |last1=Bach |first1=Julie |last2=Varatharajan |first2=Jenenee |title=Bleach (Sodium Hypochlorite): History |url=http://whatisbleach.weebly.com/history.html |archive-url=https://web.archive.org/web/20230311014220/https://whatisbleach.weebly.com/history.html |archive-date=11 March 2023 |access-date=2023-04-29 |website=whatisbleach.weebly.com}} while Walton claims it was introduced to Egypt from Asia.{{Cite book |last=Walton |first=Perry |url=http://archive.org/details/storyoftextiles00waltrich |title=The story of textiles |date=1912 |publisher=Boston, Mass., J. S. Lawrence |others=University of California Libraries |pages=111–115}} It’s plausible that it was discovered independently by different cultures. It’s generally assumed to have developed after noticing that garments are naturally bleached by sunlight and washing. Wood ash (potash, or impure potassium hydroxide) was an early form of soap, known to have been used in bleaching since at least 1AD.{{Cite book |url=https://books.google.com/books?id=siQH2lVmxjoC&pg=PA410 |title=Crops in peace and war - The yearbook of agriculture 1950 - 1951 |date=1950 |publisher=U.S. Government Printing Office |pages=410 |language=en}} This process of washing cloth in a solution of ashes (lye) and left in the sun, known as Grassing, is one of the oldest methods of bleaching textile goods. To bleach linen and cotton-based fabrics, the Grassing method has been used. Linen has long been bleached in Europe with Grassing method.{{Cite book|last=Nystrom|first=Paul Henry|url=https://books.google.com/books?id=MH81AAAAMAAJ&q=Grassing.%E2%80%94The+oldest+bleaching|title=Textiles|date=1916|publisher=D. Appleton|pages=266|language=en|quote=Grassing . — The oldest bleaching method is that of "grassing", still used to a certain extent in Europe for bleaching linens . The linen fabrics are laid on the grass or ground for weeks . The oxygen of the air and that given off by green plants}} The linens were laid out on the grass for over seven days after boiling with the lyes of ashes and rinsing.{{Cite book|last=Sansone|first=Antonio|url=https://books.google.com/books?id=mmBDAQAAIAAJ&q=Grassing+bleaching&pg=PA109|title=Dyeing: Comprising the Dyeing and Bleaching of Wool, Silk, Cotton, Flax, Hemp, China Grass &c|date=1888|publisher=A. Heywood & son|pages=109|language=en}} Bleachfield was an open area to spread cloth, it was a field near watercourse used by a bleachery. Bleachfields were common in and around the mill towns during the British Industrial Revolution{{Cite book|last=Aspin|first=C. (Christopher)|url=https://archive.org/details/cottonindustry0000aspi|title=The cotton industry|date=1981|location=Aylesbury |publisher= Shire Publications Ltd|isbn=978-0-85263-545-2|pages=24}}

The Dutch were bleaching by about the 12th century and are credited with soaking the bleached cloth in a bath of soured milk for 5 – 8 days.{{Cite book |url=https://books.google.com/books?id=fmBJAAAAYAAJ&pg=PA704 |title=The Encyclopaedia Britannica: A Dictionary of Arts, Sciences, and General Literature: Bleaching |date=1894 |publisher=Maxwell Sommerville |pages=704 |language=en}} This softened and neutralised the harsh effects of the caustic lye. By the 17th century the Dutch were renowned for their bleaching skills and much of their trade was for customers abroad.{{Cite book |last=Davids |first=Karel |url=https://books.google.com/books?id=bu95DwAAQBAJ&pg=PA134 |title=The Rise and Decline of Dutch Technological Leadership: Technology, Economy and Culture in the Netherlands, 1350-1800 |date=2008-08-31 |publisher=BRILL |isbn=978-90-474-4332-2 |volume=1 |pages=134 |language=en}} Around 1756 an alternative to soured milk was proposed by the Scottish doctor, Francis Home using a weak solution of sulphuric acid.{{Cite journal |last=Page |first=Frederick G |date=2002 |title=Francis Home and Joseph Black: the Chemistry and Testing of Alkaline Salts in the Early Bleaching and Alkali Trade |url=https://docslib.org/doc/11501435/francis-home-and-joseph-black-the-chemistry-and-testing-of-alkaline-salts-in-the-early-bleaching-and-alkali-trade |journal=Bulletin for the History of Chemistry |volume=27 |issue=2 |pages=107–113 |via=docslib.org}} This was made commercially viable by John Roebuck's manufacture of sulphuric acid and reduced the soaking time to 12 – 24 hours. A final rinse and drying finished the bleaching process.

The English East India Company imported bleached, painted and printed calico from India during the 17th century.{{Cite book |last=Chaudhuri |first=K. N. |url=https://books.google.com/books?id=Dyn3oh06ue8C&pg=PA199 |title=The English East India Company: The Study of an Early Joint-stock Company 1600-1640 |date=1999 |publisher=Taylor & Francis |isbn=978-0-415-19076-3 |pages=199 |language=en}} This disrupted the English silk and wool trades{{Cite web |title=House of Commons Journal Volume 11: 19 February 1696 {{!}} British History Online |url=https://www.british-history.ac.uk/commons-jrnl/vol11/pp456-457 |access-date=2023-04-29 |website=www.british-history.ac.uk}} and an act of parliament, the Encouragement of Manufactures Act 1698 (11 Will. 3. c. 10), was passed that prohibited the wearing of printed calicos manufactured in China, India or Persia.{{Cite book |last=Pickering |first=Danby |url=https://archive.org/details/statutesatlarge31britgoog/page/328/mode/2up |title=Statutes at large 8 Gui III - 1 Ann (1696 - 1701) |date=1762 |publisher=Cambridge [London] |others=University of Michigan |volume=10 |location=Great Britain |pages=328–331}} This inadvertently established a calico bleaching and printing industry using unbleached Indian calico. A second law in 1721 prohibited the use and wear of all printed, painted, stained or dyed calicoes {{Cite book |last=Pickering |first=Danby |url=https://archive.org/details/dli.bengal.10689.22525/page/n343/mode/2up |title=The Statutes at Large 5 - 9 Geo 1 (1718 - 1721) |date=1765 |publisher=Joseph Bentham |volume=14 |location=Cambridge |pages=318–321}} which stimulated demand for linen and fustian. The calico acts were repealed in 1774 when cloth was made using imported cotton from America.{{Cite book |last=Pickering |first=Danby |url=https://archive.org/details/statutesatlarge70britgoog/page/436/mode/2up |title=Statutes at large 13 - 14 Geo 3 (1773 - 1774) |date=1762 |publisher=Charles Bathurst |others=University of Michigan |volume=30 |location=Cambridge [London] |pages=437}}

After discovering Chlorine in the late 18th century, when chemical bleaching came into existence, the chemical bleaching rose above Grassing, as it was quicker and possible in indoors.

The French chemist Claude Louis Berthollet first demonstrated the bleaching properties of chlorine and subsequently developed liquid bleaches around 1789. James Watt is credited with bringing it to Britain, and a fellow Scot, Charles Tennant patented a more practical bleaching powder that made chlorine-based bleaching a commercial success.

{{Main|Scouring (textiles)}}

Scouring is the first process carried out with or without chemicals, at room temperature or at suitable higher temperatures with the addition of suitable wetting agents, alkali and so on. Scouring removes the impurities such as waxes, pectins and makes the textile material hydrophilic or water absorbent.{{Cite book|url=https://archive.org/details/FacultyOfEngineeringEditingVersion|title=Faculty Of Engineering|pages=18|language=English}}{{Cite book|last1=Horrocks|first1=A. Richard|url=https://books.google.com/books?id=QUqdBAAAQBAJ&q=%22Scouring%22+textiles+-wikipedia&pg=PA191|title=Handbook of Technical Textiles: Technical Textile Processes|last2=Anand|first2=Subhash C.|date=2015-12-01|publisher=Woodhead Publishing|isbn=978-1-78242-481-9|pages=191|language=en}}{{Cite book|last=Trotman|first=E. R. (Edward Russell)|url=https://archive.org/details/textilescouringb0000trot|title=Textile scouring and bleaching|date=1968|location=London |publisher= Griffin|isbn=978-0-85264-067-8}}{{Rp|78}} Scouring is then followed by the bleaching process.{{Rp|169}}{{Rp|193}}

The term "bleach" originates from a French word signifying "to whiten." In essence, the process of bleaching involves whitening by removing substances that impart color to the material undergoing the bleaching treatment.{{Cite book |last1=O'Neill |first1=Charles |url=http://archive.org/details/dictionaryofdyei00oneiiala |title=A dictionary of dyeing and calico printing : containing a brief account of dyeing and printing textile fabrics |last2=Fesquet |first2=A. A. |date=1869 |publisher=Philadelphia : H.C. Baird |others=University of California Libraries}} Bleaching is the process of decolorizing the material after it has been scoured.{{Rp|169}} Bleaching textiles can be classified as oxidative bleaching and reductive bleaching which can be carried out with oxidizing and reductive bleaching agents.{{Cite book|last=Karmakar|first=S. R.|url=https://books.google.com/books?id=rc5yfbdbXr8C&q=Bleaching+of+textiles+can+be+classified+into+oxidative+bleaching+and+reductive+bleaching.&pg=PA161|title=Chemical Technology in the Pre-Treatment Processes of Textiles|date=1999-11-02|publisher=Elsevier|isbn=978-0-08-053947-8|language=en}}{{Rp|161}} Bleaching agents attack the chromophores and alter the color absorbing properties of the objects.{{Cite web|title=Bleaching Agent - an overview {{!}} ScienceDirect Topics|url=https://www.sciencedirect.com/topics/chemistry/bleaching-agent#:~:text=Bleaching%20Agents-,Bleaching%20agents%20are%20formulations%20that%20whiten%20or%20lighten%20a%20substrate,and%20commercial%20and%20household%20laundering.|access-date=2021-08-01|website=www.sciencedirect.com}}

Generally oxidative bleachings are carried out using sodium hypochlorite, sodium chlorite or sulfuric acid.

Vegetable fibres, animal fibers, and mineral fibres are the three major types of natural fibers. Natural fibers such as cotton, ramie, jute, wool, and regenerated fibers such as bamboo are all generally bleached with oxidative methods.{{Cite book|url=https://books.google.com/books?id=yBcS0XlQVE0C&q=Natural+fibres+like+cotton,+ramie,+jute,+wool,+bamboo+are+all+generally+bleached+with+oxidative+methods.|title=The Indian Textile Journal|date=2012|publisher=Indian Textile Journal Limited|pages=113|language=en}}

It is the conjugated double bonds of the substrate that makes the substrate capable of absorbing visible light. Hence, it looks yellower and need bleaching. When bleaching action carries out with oxygen, it removes the chromophoric sites and makes the cloths whiter. Oxygen is a degrading bleaching agent. Its bleaching action is based on destroying the phenolic groups and the carbon–carbon double bonds..{{Cite web|title=Bleaching Agent - an overview {{!}} ScienceDirect Topics|url=https://www.sciencedirect.com/topics/earth-and-planetary-sciences/bleaching-agent|access-date=2021-07-27|website=www.sciencedirect.com}} The major source of chemical bleaching is Hydrogen peroxide {{chem|H|2|O|2}} that contains a single bond, (–O–O–). When this breaks down it gives rise to very reactive oxygen specie, which is the active agent of the bleach. Around sixty percent of the world Hydrogen peroxide is used in chemical bleaching of textiles and wood pulp.{{Cite journal|last1=Hage|first1=Ronald|last2=Lienke|first2=Achim|date=2006|title=Applications of Transition-Metal Catalysts to Textile and Wood-Pulp Bleaching|url=https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200500525|journal=Angewandte Chemie International Edition|language=en|volume=45|issue=2|pages=206–222|doi=10.1002/anie.200500525|issn=1521-3773|pmid=16342123}}

Reductive bleaching is done with sodium hydrosulphite, a powerful reducing agent. Fibres like polyamides, polyacrylics and polyacetates can be bleached using reductive bleaching technology.

{{Main|Optical brightener}}

Bleaching of textiles may include an additional application of optical brighteners (OBAs). Optical brightening agents are chemical compounds that absorb light in the ultraviolet and violet region (usually 340-370 nm) of the electromagnetic spectrum, and re-emit light in the blue region (typically 420-470 nm) by fluorescence. After scouring and bleaching, optical brightening agents are applied to make the textile material appear a more brilliant white. These OBAs are available in different tints such as blue, violet and red.{{Citation|last1=Smulders|first1=Eduard|title=Laundry Detergents|date=2007|url=https://onlinelibrary.wiley.com/doi/abs/10.1002/14356007.a08_315.pub2|encyclopedia=Ullmann's Encyclopedia of Industrial Chemistry|publisher=American Cancer Society|language=en|doi=10.1002/14356007.a08_315.pub2|isbn=978-3-527-30673-2|access-date=2021-08-01|last2=Rybinski|first2=Wolfgang von|last3=Sung|first3=Eric|last4=Rähse|first4=Wilfried|last5=Steber|first5=Josef|last6=Wiebel|first6=Frederike|last7=Nordskog|first7=Anette}}

File:Canonization 2014-The Canonization of Saint John XXIII and Saint John Paul II (14036966125).jpg at the Vatican. Popes have traditionally worn white since 1566.]]

Whiteness in colorimetry is the degree to which a surface is white.{{Cite book|title=Colorimetry : understanding the CIE system|date=2007|publisher=CIE/Commission internationale de l'eclairage|others=János Schanda, International Commission on Illumination|isbn=978-0-470-17563-7|location=Vienna, Austria|oclc=181346337}} The term "whiteness" refers to the degree to which a surface resembles the properties of a perfect reflecting diffuser, i.e. an ideal reflecting surface that neither absorbs nor transmits light, but instead reflects it evenly in all directions.{{Citation|last=Westland|first=Stephen|title=CIE Whiteness|date=2014|url=https://doi.org/10.1007/978-3-642-27851-8_5-1|encyclopedia=Encyclopedia of Color Science and Technology|pages=1–5|editor-last=Luo|editor-first=Ronnier|place=Berlin, Heidelberg|publisher=Springer|language=en|doi=10.1007/978-3-642-27851-8_5-1|isbn=978-3-642-27851-8|access-date=2021-08-01}}

CIE Whiteness is a formula that measures the degree of whiteness. The CIE Whiteness Index is a measure or methodology developed by the Commission on illumination.{{Cite book|last=Amutha|first=K.|url=https://books.google.com/books?id=sMn1CwAAQBAJ&dq=The+CIE+Whiteness+Index&pg=PA105|title=A Practical Guide to Textile Testing|date=2016-04-05|publisher=CRC Press|isbn=978-93-85059-62-9|pages=105|language=en}}

File:Splendor Solis - Traité d'Alchimie - Femmes lavant le linge.jpg| Grassing, laying out linens to bleach in sunlight

File:Linen Bleach Green (8251136135).jpg| Linen Bleaching/ Grassing

File:Bleekveld.jpg|Bleekveld in een dorp (Bleachfield in a village), circa 1650 (Jan Brueghel the Younger)

File:Jan Brueghel (I) and Joos de Momper (II) - Market and washing place in Flanders.jpg|Market and washing place in Flanders

File:Bleaching vats for cloth in the piece. Silk industry, South Manchester, Conn., U.S.A (NYPL b11707678-G90F070 026F).tiff|Bleaching vats for cloth in the piece.

File:EB1911 Bleaching - Fig. 4. —High Pressure Blow-through Kier.jpg|High Pressure Blow-through Kier

File:EB1911 Bleaching - Fig. 5. —Roller Washing Machine.jpg|alt=Bleaching—Roller Washing Machine|Bleaching—The Mather Kier, cross section

File:EB1911 Bleaching - Fig. 6.—The Mather Kier, cross section.jpg|Bleaching—The Mather Kier, cross section

File:EB1911 Bleaching - Fig. 7.—The Mather Kier, longitudinal section.jpg|Bleaching—The Mather Kier, longitudinal section

File:EB1911 Bleaching - Fig. 8.—Mather & Platt’s Horizontal Drying Machine.jpg|Bleaching—Mather & Platt’s Horizontal Drying Machine

File:EB1911 Bleaching - Fig. 9.—Horizontal Drying Machine threaded with Cloth.jpg|Bleaching—Horizontal Drying Machine threaded with Cloth

• White
• Dyeing
• Color of clothing
• Color temperature
• History of cotton

{{Reflist}}

{{EB1911 poster|Bleaching}}

• [http://www.thesmarttime.com/ Textile Processing Guide] at thesmarttime.com

{{DEFAULTSORT:Textile Bleaching}}

Category:Textiles

Category:Industrial processes

Category:Textile techniques