tin(II) sulfate
{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 477315237
| Name = Tin(II) sulfate
| ImageFile = Zinn(II)-sulfat.png
| ImageAlt = Tin(II) sulfate crystallizes in an heavily distorted barium sulfrate structure.
| ImageCaption = Unit cell of tin(II) sulfate.
| ImageName = Tin(II) sulfate
| OtherNames = Stannous sulfate
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 21106484
| InChI = 1/H2O4S.Sn.2H/c1-5(2,3)4;;;/h(H2,1,2,3,4);;;/q;+2;;/p-2/rH2O4S.H2Sn/c1-5(2,3)4;/h(H2,1,2,3,4);1H2/q;+2/p-2
| InChIKey = RCIVOBGSMSSVTR-YHUAHBEBAB
| SMILES = [O-]S(=O)(=O)[O-].[SnH2+2]
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/H2O4S.Sn.2H/c1-5(2,3)4;;;/h(H2,1,2,3,4);;;/q;+2;;/p-2
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = RCIVOBGSMSSVTR-UHFFFAOYSA-L
| CASNo = 7488-55-3
| CASNo_Ref = {{cascite|correct|CAS}}
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = 0MFE10J96E
| EINECS = 231-302-2
| PubChem = 62643
}}
|Section2={{Chembox Properties
| Formula = SnSO4
| MolarMass = 214.773 g/mol
| Appearance = white-yellowish crystalline solid
deliquescent
| Density = 4.15 g/cm3
| Solubility = 33 g/100 mL (25 °C)
| MeltingPtC = 378
| BoilingPt = decomposes to SnO2 and SO2
}}
|Section3={{Chembox Structure
|CrystalStruct = Primitive orthorhombic
|LattConst_a = 8.80 Å
|LattConst_b = 5.32 Å
|LattConst_c = 7.12 Å
|SpaceGroup = Pnma, No. 62
}}
|Section7={{Chembox Hazards
| NFPA-H = 1
| NFPA-F = 0
| NFPA-R = 0
| FlashPt = Non-flammable
| LD50 = 2207 mg/kg (oral, rat)
2152 mg/kg (oral, mouse){{IDLH|7440315|Tin (inorganic compounds, as Sn)}}
}}
|Section8={{Chembox Related
| OtherAnions = Tin(II) chloride, tin(II) bromide, tin(II) iodide
| OtherCations = Lead(II) sulfate
| OtherFunction =
| OtherFunction_label =
| OtherCompounds =
}}
}}
Tin(II) sulfate (SnSO4) is a chemical compound. It is a white solid that can absorb enough moisture from the air to become fully dissolved, forming an aqueous solution; this property is known as deliquescence. It can be prepared by a displacement reaction between metallic tin and copper(II) sulfate:{{Greenwood&Earnshaw1st|page=451}}
:{{chem2 | Sn (s) + CuSO4 (aq) -> Cu (s) + SnSO4 (aq) }}
Tin(II) sulfate is a convenient source of tin(II) ions uncontaminated by tin(IV) species.
Structure
In the solid state the sulfate ions are linked together by O-Sn-O bridges. The tin atom has three oxygen atoms arranged pyramidally at 226 pm with the three O-Sn-O bond angles of 79°, 77.1° and 77.1°. Other Sn-O distances are longer ranging from 295 - 334pm.{{cite journal|last1=Donaldson|first1=J. D.|last2=Puxley|first2=D. C.|title=The crystal structure of tin(II) sulphate|journal=Acta Crystallographica Section B|volume=28|issue=3|year=1972|pages=864–867|issn=0567-7408|doi=10.1107/S0567740872003322|bibcode=1972AcCrB..28..864D }}
References
{{reflist}}
{{Tin compounds}}
{{Sulfates}}
{{sulfur compounds}}