triphylite

{{Short description|Mineral}}

{{Expand German|Triphylin|date=July 2015}}

{{Infobox mineral

| name =

| category = Phosphate minerals

| boxwidth =

| boxbgcolor =

| image = Triphylite-112567.jpg

| imagesize =

| caption = Triphylite crystal in matrix, collected from Smith Quarry (Chandler Mills Quarry), Newport, New Hampshire {{coord|43|21|28|N|72|15|8|W}}{{cite web|title=Chandlers Mill Quarry, Newport, Sullivan Co., New Hampshire, USA|url=http://www.mindat.org/maps.php?id=3940|publisher=MinDat.org}}

| formula = LiFePO4

| IMAsymbol = Trp{{Cite journal|last=Warr|first=L.N.|date=2021|title=IMA–CNMNC approved mineral symbols|journal=Mineralogical Magazine|volume=85|issue=3|pages=291–320|doi=10.1180/mgm.2021.43|bibcode=2021MinM...85..291W|s2cid=235729616|doi-access=free}}

| molweight =

| strunz = 8.AB.10

| system = Orthorhombic

| class = Dipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)

| symmetry = Pmnb

| color = Green–blue gray, brown–black

| habit = Massive, granular, prismatic

| twinning =

| cleavage = {100} perfect, {010} imperfect, {011} poor

| fracture = Uneven–subconchoidal

| mohs = 4–5

| luster = Vitreous–subresinous

| polish =

| refractive = nα=1.675–1.694, nβ=1.684–1.695, nγ=1.685–1.700

| opticalprop = Biaxial (+), 2V = 0°–65°

| birefringence = δ = 0.0060–0.0080

| pleochroism =

| fluorescence=

| absorption =

| streak = White–grayish white

| gravity =

| density =

| melt =

| fusibility =

| diagnostic =

| solubility =

| diaphaneity = Transparent–translucent

| unit cell = a = 6.0285(6) Å, b = 10.3586(9) Å, c = 4.7031(3) Å, Z = 4

| other =

| references ={{cite web|url=http://webmineral.com/data/Triphylite.shtml|title=Triphylite|publisher=WebMineral.com|accessdate=July 15, 2015}}{{cite web|url=http://www.mindat.org/min-4020.html|title=Triphylite|publisher=Mindat.org}}{{cite encyclopedia|url=http://rruff.info/doclib/hom/triphylite.pdf |title=Triphylite|encyclopedia=Handbook of Mineralogy |editor1-first=John W. |editor1-last=Anthony|editor2-first=Richard A. |editor2-last=Bideaux|editor3-first=Kenneth W. |editor3-last=Bladh|editor4-first= Monte C. |editor4-last=Nichols |publisher=Mineralogical Society of America|location=Chantilly, VA}}}}

Triphylite is a lithium iron(II) phosphate mineral with the chemical formula LiFePO4.[http://ima-cnmnc.nrm.se/imalist.htm IMA-CNMNC List of Mineral Names] (May 2015), International Mineralogical Association It is a member of the triphylite group and forms a complete solid solution series with the lithium manganese(II) phosphate, lithiophilite. Triphylite crystallizes in the orthorhombic crystal system. It rarely forms prismatic crystals and is more frequently found in hypidiomorphic rock. It is bluish- to greenish-gray in color, but upon alteration becomes brown to black.

Etymology and history

The mineral was first discovered and examined in 1834 by German mineralogist Johann Nepomuk von Fuchs at Hennenkobel Mine in the Bavarian Forest.{{cite journal|first=Johann Nepomuk|last=von Fuchs|title=Ueber ein neues Mineral (Triphylin)|journal=Journal für Praktische Chemie|year=1834|volume=3|pages=98–104|doi=10.1002/prac.18340030120|url=https://zenodo.org/record/1427758}}.{{cite journal|first=Johann Nepomuk|last=von Fuchs|title=Vermischte Notizen, 3. Triphylin|journal=Journal für Praktische Chemie|year=1835|volume=5|page=319|doi=10.1002/prac.18350050138|url=https://zenodo.org/record/1427760}}. The name derives from the Greek words tri ("three") and phulon ("family"), referring to the three cations found in natural samples of triphylite (Li+, Fe2+, Mn2+).

Crystal structure

:File:Crystal_structure-Triphylite.png

Triphylite crystallizes in an orthorhombic crystal system. The lithium coordinates to six oxygen atoms in a distorted octahedron. Likewise, the iron centers are octahedrally coordinated. The structure contains isolated phosphate tetrahedra.{{cite encyclopedia|title=Triphylin|encyclopedia=Römpp Online|url=https://roempp.thieme.de/lexicon/RD-20-03081|accessdate=2020-06-13}}

Properties

Triphylite is soluble in hydrochloric and sulfuric acid. Under a blowpipe, it melts to form a dark gray, magnetic ball. Over time, the mineral undergoes alteration by oxidation, increasing the oxidation state of iron from +2 to +3 and allowing the lithium to escape, forming heterosite, FePO4.

Triphylite forms a complex solution series with lithiophilite, LiMnPO4, so that natural sources of triphylite usually contain manganese. The structures of members within this series are similar to olivine-type silicates.{{cite web|url=https://www.mindat.org/min-31812.html|title=Lithiophite-Triphylite Series|publisher=Mindat.org}}

References