:Isotopes of hassium
{{Short description|none}}
{{Infobox hassium isotopes}}
Hassium (108Hs) is a synthetic element, and thus a standard atomic weight cannot be given. Like all synthetic elements, it has no stable isotopes. The first isotope to be synthesized was 265Hs in 1984. There are 13 known isotopes from 263Hs to 277Hs and up to six isomers. The most stable known isotope is 271Hs, with a half-life of about 46 seconds, though this assignment is not definite due to uncertainty arising from a low number of measurements. The isotopes 269Hs and 270Hs respectively have half-lives of about 12 seconds and 7.6 seconds. It is also possible that the isomer 277mHs is more stable than these, with a reported half-life {{val|130|100}} seconds, but only one event of decay of this isotope has been registered as of 2016.{{Cite web|title=Radioactive Elements|url=https://ciaaw.org/radioactive-elements.htm|date=2018|access-date=2020-09-20|website=Commission on Isotopic Abundances and Atomic Weights|language=en}}{{sfn|Audi et al.|2017|p=030001-136}}
List of isotopes
{{Anchor|Hassium-263m|Hassium-274|Hassium-276|Hassium-278|Hassium-279|Hassium-280}}
{{Isotopes table
|symbol=Hs
|refs=AME2020 II
|notes=m, unc(), mass#, spin#, SF
}}
|-id=Hassium-263
| 263Hs
| style="text-align:right" | 108
| style="text-align:right" | 155
| 263.12848(21)#
| 760(40) μs
| α
| 259Sg
| 3/2+#
|-id=Hassium-264
| rowspan=2 style="text-align:right" | 108
| rowspan=2 style="text-align:right" | 156
| rowspan=2|264.12836(3)
| rowspan=2|0.7(3) ms
| α (70%)
| 260Sg
| rowspan=2|0+
|-
| SF (30%)
| (various)
|-id=Hassium-265
| style="text-align:right" | 108
| style="text-align:right" | 157
| 265.129792(26)
| 1.96(16) ms
| α
| 261Sg
| 9/2+#
|-id=Hassium-265m
| style="text-indent:.3em" | 265mHs
| colspan="3" style="text-indent:2em" | 229(22) keV
| 360(150) μs
| α
| 261Sg
| 3/2+#
|-id=Hassium-266
| rowspan=2|266HsNot directly synthesized, occurs as decay product of 270Ds{{cite book |last1=Ackermann |first1=Dieter |title=Proceedings of 50th International Winter Meeting on Nuclear Physics — PoS(Bormio2012) |chapter=270Ds and its decay products – K-isomers, α-sf competition and masses |date=23–27 January 2012 |page=030 |doi=10.22323/1.160.0030 |chapter-url=https://pos.sissa.it/160/030/pdf |access-date=1 July 2023 |doi-access=free }}
| rowspan=2 style="text-align:right" | 108
| rowspan=2 style="text-align:right" | 158
| rowspan=2| 266.130049(29)
| rowspan=2|{{val|2.97|0.78|0.51|u=ms}}
| α (76%)
| 262Sg
| rowspan=2|0+
|-
| SF (24%)
| (various)
|-id=Hassium-266m
| style="text-indent:.3em" | 266mHs
| colspan="3" style="text-indent:2em" | 1100(70) keV
| 280(220) ms
[{{val|74|354|34|u=ms}}]
| α
| 262Sg
| 9-#
|-id=Hassium-267
| 267Hs
| style="text-align:right" | 108
| style="text-align:right" | 159
| 267.13168(10)#
| 55(11) ms
| α
| 263Sg
| 5/2+#
|-id=Hassium-267m
| style="text-indent:.3em" | 267mHsExistence of this isomer is unconfirmed
| colspan="3" style="text-indent:2em" | 39(24) keV
| 990(90) μs
| α
| 263Sg
|
|-id=Hassium-268
| 268Hs
| style="text-align:right" | 108
| style="text-align:right" | 160
| 268.13201(32)#
| 1.42(1.13) s
[{{val|0.38|1.8|0.17|u=s}}]
| α
| 264Sg
| 0+
|-id=Hassium-269
| 269Hs
| style="text-align:right" | 108
| style="text-align:right" | 161
| 269.13365(14)#
| α
| 265Sg
| 9/2+#
|-id=Hassium-269m
| rowspan=2 style="text-indent:1em" | 269mHs
| rowspan=2 colspan="3" style="text-indent:2em" | 20 keV#
| rowspan=2|{{val|2.8|13.6|1.3|u=s}}
| α
| 265mSg
| rowspan=2|1/2#
|-
| IT
| 269Hs
|-id=Hassium-270
| rowspan=2 style="text-align:right" | 108
| rowspan=2 style="text-align:right" | 162
| rowspan=2|270.13431(27)#
| rowspan=2|{{val|7.6|4.9|2.2|u=s}}
| α
| 266Sg
| rowspan=2|0+
|-
| SF (<50%)
| (various)
|-id=Hassium-271
| 271Hs
| style="text-align:right" | 108
| style="text-align:right" | 163
| 271.13708(30)#
| α
| 267Sg
| 11/2#
|-id=Hassium-271m
| rowspan=2 style="text-indent:1em" | 271mHs
| rowspan=2 colspan="3" style="text-indent:2em" | 20 keV#
| rowspan=2|{{val|7.1|8.4|2.5|u=s}}
| α
| 267mSg
| rowspan=2|3/2#
|-
| IT
| 271Hs
|-id=Hassium-272
| 272HsNot directly synthesized, occurs in decay chain of 276Ds{{cite journal |title=New isotope 276Ds and its decay products 272Hs and 268Sg from the 232Th + 48Ca reaction |last1=Oganessian |first1=Yu. Ts. |last2=Utyonkov |first2=V. K. |last3=Shumeiko |first3=M. V. |display-authors=et al. |date=2023 |journal=Physical Review C |volume=108 |number=24611 |page=024611 |doi=10.1103/PhysRevC.108.024611|bibcode=2023PhRvC.108b4611O |s2cid=261170871 }}
| style="text-align:right" | 108
| style="text-align:right" | 164
| 272.13849(55)#
| {{val|160|190|60|u=ms}}
| α
| 268Sg
| 0+
|-id=Hassium-273
| 273HsNot directly synthesized, occurs in decay chain of 285Fl
| style="text-align:right" | 108
| style="text-align:right" | 165
| 273.14146(40)#
| α
| 269Sg
| 3/2+#
|-id=Hassium-275
| rowspan=2|275HsNot directly synthesized, occurs in decay chain of 287Fl{{cite journal |title=Investigation of 48Ca-induced reactions with 242Pu and 238U targets at the JINR Superheavy Element Factory |journal=Physical Review C |volume=106 |number=24612 |year=2022 |first1=Yu. Ts. |last1=Oganessian |first2=V. K. |last2=Utyonkov |first3=D. |last3=Ibadullayev |page=024612 |display-authors=et al. |doi= 10.1103/PhysRevC.106.024612|bibcode=2022PhRvC.106b4612O |osti=1883808 |s2cid=251759318 }}
| rowspan=2 style="text-align:right" | 108
| rowspan=2 style="text-align:right" | 167
| rowspan=2|275.14653(64)#
| rowspan=2|{{val|600|230|130|u=ms}}
| α
| 271Sg
| rowspan=2|
|-
| SF (<11%)
| (various)
|-id=Hassium-277
| 277HsNot directly synthesized, occurs in decay chain of 289Fl
| style="text-align:right" | 108
| style="text-align:right" | 169
| 277.15177(48)#
| SF
| (various)
| 3/2+#
|-id=Hassium-277m
| style="text-indent:.3em" | 277mHs{{NUBASE2020|ref}}
| colspan="3" style="text-indent:2em" | 100(100) keV#
| 130(100) s
| SF
| (various)
|
{{Isotopes table/footer}}
Isotopes and nuclear properties
=Target-projectile combinations leading to ''Z''=108 compound nuclei=
class="wikitable" style="text-align:center"
!Target!!Projectile!!CN!!Attempt result | ||
-
!136Xe |136Xe | 272Hs | {{no|Failure to date}} |
198Pt
|70Zn||268Hs||{{no|Failure to date{{cite web |url=http://www.nupecc.org/ecos/sh_0710.pdf |title=Archived copy |website=www.nupecc.org |access-date=11 January 2022 |archive-url=https://web.archive.org/web/20070823154030/http://www.nupecc.org/ecos/sh_0710.pdf |archive-date=23 August 2007 |url-status=dead}}}} | ||
---|---|---|
208Pb
|58Fe||266Hs||{{yes|Successful reaction}} | ||
207Pb
|58Fe||265Hs||{{yes|Successful reaction}} | ||
208Pb
|56Fe||264Hs||{{yes|Successful reaction}} | ||
207Pb
|56Fe||263Hs||{{unk|Reaction yet to be attempted}} | ||
206Pb
|58Fe||264Hs||{{yes|Successful reaction}} | ||
209Bi
|55Mn||264Hs||{{no|Failure to date}} | ||
226Ra
|48Ca||274Hs||{{yes|Successful reaction}} | ||
232Th
|40Ar||272Hs||{{unk|Reaction yet to be attempted}} | ||
238U
|36S||274Hs||{{yes|Successful reaction}} | ||
238U
|34S||272Hs||{{yes|Successful reaction}} | ||
244Pu
|30Si||274Hs||{{unk|Reaction yet to be attempted}} | ||
248Cm
|26Mg||274Hs||{{yes|Successful reaction}} | ||
248Cm
|25Mg||273Hs||{{no|Failure to date}} | ||
250Cm
|26Mg||276Hs||{{unk|Reaction yet to be attempted}} | ||
249Cf
|22Ne||271Hs||{{yes|Successful reaction}} |
=Nucleosynthesis=
Superheavy elements such as hassium are produced by bombarding lighter elements in particle accelerators that induce fusion reactions. Whereas most of the isotopes of hassium can be synthesized directly this way, some heavier ones have only been observed as decay products of elements with higher atomic numbers.{{Cite journal |first1=Peter |last1=Armbruster |name-list-style=amp|first2=Gottfried|last2=Münzenberg |title=Creating superheavy elements |journal=Scientific American |volume=34 |pages=36–42 |year=1989}}
Depending on the energies involved, the former are separated into "hot" and "cold". In hot fusion reactions, very light, high-energy projectiles are accelerated toward very heavy targets (actinides), giving rise to compound nuclei at high excitation energy (~40–50 MeV) that may either fission or evaporate several (3 to 5) neutrons.{{cite journal |last1=Barber |first1=Robert C. |last2=Gäggeler |first2=Heinz W. |last3=Karol |first3=Paul J. |last4=Nakahara |first4=Hiromichi |last5=Vardaci |first5=Emanuele |last6=Vogt |first6=Erich |title=Discovery of the element with atomic number 112 (IUPAC Technical Report) |journal=Pure and Applied Chemistry |volume=81 |issue=7 |page=1331 |year=2009 |doi=10.1351/PAC-REP-08-03-05|doi-access=free }} In cold fusion reactions, the produced fused nuclei have a relatively low excitation energy (~10–20 MeV), which decreases the probability that these products will undergo fission reactions. As the fused nuclei cool to the ground state, they require emission of only one or two neutrons, and thus, allows for the generation of more neutron-rich products. The latter is a distinct concept from that of where nuclear fusion claimed to be achieved at room temperature conditions (see cold fusion).{{cite journal |last1=Fleischmann |first1=Martin |last2=Pons |first2=Stanley |year=1989 |title=Electrochemically induced nuclear fusion of deuterium |journal=Journal of Electroanalytical Chemistry and Interfacial Electrochemistry |volume=261 |issue=2 |pages=301–308 |doi=10.1016/0022-0728(89)80006-3}}
==Cold fusion==
Before the first successful synthesis of hassium in 1984 by the GSI team, scientists at the Joint Institute for Nuclear Research (JINR) in Dubna, Russia also tried to synthesize hassium by bombarding lead-208 with iron-58 in 1978. No hassium atoms were identified. They repeated the experiment in 1984 and were able to detect a spontaneous fission activity assigned to 260Sg, the daughter of 264Hs.{{Cite journal|doi=10.1007/BF01415635|title=On the stability of the nuclei of element 108 with A=263–265|year=1984|last1=Oganessian |first1=Yu Ts|journal=Zeitschrift für Physik A|volume=319|pages=215–217|last2=Demin|first2=A. G.|last3=Hussonnois|first3=M.|last4=Tretyakova|first4=S. P.|last5=Kharitonov|first5=Yu P.|last6=Utyonkov|first6=V. K.|last7=Shirokovsky|first7=I. V.|last8=Constantinescu|first8=O.|last9=Bruchertseifer|first9=H.|last10=Korotkin|first10=Yu S.|bibcode = 1984ZPhyA.319..215O|issue=2 |s2cid = 123170572|display-authors=8}} Later that year, they tried the experiment again, and tried to chemically identify the decay products of hassium to provide support to their synthesis of element 108. They were able to detect several alpha decays of 253Es and 253Fm, decay products of 265Hs.{{Cite journal|doi=10.1351/pac199365081757|title=Discovery of the transfermium elements. Part II: Introduction to discovery profiles. Part III: Discovery profiles of the transfermium elements (Note: for Part I see Pure Appl. Chem., Vol. 63, No. 6, pp. 879–886, 1991)|year=1993|last1=Barber |first1=R. C.|journal=Pure and Applied Chemistry|volume=65|pages=1757|last2=Greenwood|first2=N. N.|last3=Hrynkiewicz|first3=A. Z.|last4=Jeannin|first4=Y. P.|last5=Lefort|first5=M.|last6=Sakai|first6=M.|last7=Ulehla|first7=I.|last8=Wapstra|first8=A. P.|last9=Wilkinson|first9=D. H.|issue=8|s2cid=195819585|doi-access=free}}
In the official discovery of the element in 1984, the team at GSI studied the same reaction using the alpha decay genetic correlation method and were able to positively identify 3 atoms of 265Hs.{{cite journal |last1=Münzenberg |first1=G. |last2=Armbruster |first2=P. |last3=Folger |first3=H. |last4=Heßberger |first4=F. P. |last5=Hofmann |first5=S. |last6=Keller |first6=J. |last7=Poppensieker |first7=K. |last8=Reisdorf |first8=W. |last9=Schmidt |first9=K.-H. |last10=Schött |first10=H. -J. |last11=Leino |first11=M. E. |last12=Hingmann |first12=R. |year=1984 |title=The identification of element 108 |journal=Zeitschrift für Physik A |volume=317 |issue=2 |pages=235–236 |doi=10.1007/BF01421260 |bibcode = 1984ZPhyA.317..235M |s2cid=123288075 |display-authors=8 }} After an upgrade of their facilities in 1993, the team repeated the experiment in 1994 and detected 75 atoms of 265Hs and 2 atoms of 264Hs, during the measurement of a partial excitation function for the 1n neutron evaporation channel.{{Cite journal|doi=10.1088/0034-4885/61/6/002|year=1998|last=Hofmann |first=S. |journal=Reports on Progress in Physics|volume=61|pages=639–689|bibcode = 1998RPPh...61..639H|title=New elements – approaching|issue=6 |s2cid=250756383 }} A further run of the reaction was conducted in late 1997 in which a further 20 atoms were detected.{{Cite journal|doi=10.1007/s002180050343|title=Excitation function for the production of 265 108 and 266 109|year=1997|last1=Hofmann |first1=S.| journal=Zeitschrift für Physik A|volume=358|pages=377–378|last2=Heßberger|first2=F.P.|last3=Ninov|first3=V.|last4=Armbruster|first4=P.|last5=Münzenberg|first5=G.|last6=Stodel|first6=C.|last7=Popeko|first7=A.G.|last8=Yeremin|first8=A.V.|last9=Saro|first9=S.|last10=Leino|first10=M.|bibcode = 1997ZPhyA.358..377H|issue=4 |s2cid=124304673|display-authors=8}} This discovery experiment was successfully repeated in 2002 at RIKEN (10 atoms) and in 2003 at GANIL (7 atoms). The team at RIKEN further studied the reaction in 2008 in order to conduct the first spectroscopic studies of the even-even nucleus 264Hs. They were also able to detect a further 29 atoms of 265Hs.
The team at Dubna also conducted the analogous reaction with a lead-207 target instead of a lead-208 target in 1984:
:{{nuclide|link=yes|lead|207}} + {{nuclide|link=yes|iron|58}} → {{nuclide|link=yes|hassium|264}} + {{SubatomicParticle|link=yes|neutron}}
They were able to detect the same spontaneous fission activity as observed in the reaction with a lead-208 target and once again assigned it to 260Sg, daughter of 264Hs. The team at GSI first studied the reaction in 1986 using the method of genetic correlation of alpha decays and identified a single atom of 264Hs with a cross section of 3.2 pb.{{Cite journal|doi=10.1007/BF01290935|title=Evidence for264108, the heaviest known even-even isotope|year=1986|last1=Münzenberg |first1=G.|journal=Zeitschrift für Physik A|volume=324|pages=489–490|last2=Armbruster|first2=P.|last3=Berthes|first3=G.|last4=Folger|first4=H.|last5=Heßberger|first5=F. P.|last6=Hofmann|first6=S.|last7=Poppensieker|first7=K.|last8=Reisdorf|first8=W.|last9=Quint|first9=B.|last10=Schmidt|first10=K. -H.|last11=Schött |first11=H. -J. |last12=Sümmerer |first12=K.|last13=Zychor|first13=I.|last14=Leino|first14=M. E.|last15=Gollerthan|first15=U.|last16=Hanelt|first16=E.|bibcode = 1986ZPhyA.324..489M|issue=4 |s2cid=121616566|display-authors=8}} The reaction was repeated in 1994 and the team were able to measure both alpha decay and spontaneous fission for 264Hs. This reaction was also studied in 2008 at RIKEN in order to conduct the first spectroscopic studies of the even-even nucleus 264Hs. The team detected 11 atoms of 264Hs.
In 2008, the team at RIKEN conducted the analogous reaction with a lead-206 target for the first time:
:{{nuclide|link=yes|lead|206}} + {{nuclide|link=yes|iron|58}} → {{nuclide|link=yes|hassium|263}} + {{SubatomicParticle|link=yes|neutron}}
They were able to identify 8 atoms of the new isotope 263Hs.[http://159.93.28.88/linkc/flnr_presentations/Mendeleev%20simposium/Morita.ppt Mendeleev Symposium. Morita] {{webarchive |url=https://web.archive.org/web/20110927212405/http://159.93.28.88/linkc/flnr_presentations/Mendeleev%20simposium/Morita.ppt |date=September 27, 2011 }}
In 2008, the team at the Lawrence Berkeley National Laboratory (LBNL) studied the analogous reaction with iron-56 projectiles for the first time:
:{{nuclide|link=yes|lead|208}} + {{nuclide|link=yes|iron|56}} → {{nuclide|link=yes|hassium|263}} + {{SubatomicParticle|link=yes|neutron}}
They were able to produce and identify six atoms of the new isotope 263Hs.{{Cite journal|doi=10.1103/PhysRevC.79.011602|title=New Isotope 263108|year=2009 |last1=Dragojević |first1=I. |journal=Physical Review C|volume=79|issue=1|pages=011602|last2=Gregorich|first2=K.|last3=Düllmann|first3=Ch.|last4=Dvorak|first4=J.|last5=Ellison|first5=P.|last6=Gates|first6=J.|last7=Nelson|first7=S.|last8=Stavsetra|first8=L.|last9=Nitsche|first9=H.|bibcode = 2009PhRvC..79a1602D }} A few months later, the RIKEN team also published their results on the same reaction.{{Cite journal|doi=10.1143/JPSJ.78.035003|title=Production and Decay Properties of 263108|year=2009 |last1=Kaji |first1=Daiya |journal=Journal of the Physical Society of Japan |volume=78 |pages=035003 |last2=Morimoto |first2=Kouji |last3=Sato |first3=Nozomi |last4=Ichikawa |first4=Takatoshi |last5=Ideguchi |first5=Eiji |last6=Ozeki |first6=Kazutaka |last7=Haba |first7=Hiromitsu |last8=Koura |first8=Hiroyuki |last9=Kudou |first9=Yuki |last10=Ozawa |first10=Akira |last11=Sumita |first11=Takayuki |last12=Yamaguchi |first12=Takayuki |last13=Yoneda |first13=Akira |last14=Yoshida |first14=Atsushi |last15=Morita |first15=Kosuke |bibcode = 2009JPSJ...78c5003K |issue=3 |display-authors=8}}
Further attempts to synthesise nuclei of hassium were performed the team at Dubna in 1983 using the cold fusion reaction between a bismuth-209 target and manganese-55 projectiles:
:{{nuclide|link=yes|bismuth|209}} + {{nuclide|link=yes|manganese|55}} → {{nuclide|hassium|264−x}} + x {{SubatomicParticle|link=yes|Neutron}} (x = 1 or 2)
They were able to detect a spontaneous fission activity assigned to 255Rf, a product of the 263Hs decay chain. Identical results were measured in a repeat run in 1984. In a subsequent experiment in 1983, they applied the method of chemical identification of a descendant to provide support to the synthesis of hassium. They were able to detect alpha decays from fermium isotopes, assigned as descendants of the decay of 262Hs. This reaction has not been tried since and 262Hs is currently unconfirmed.
==Hot fusion==
Under the leadership of Yuri Oganessian, the team at the Joint Institute for Nuclear Research studied the hot fusion reaction between calcium-48 projectiles and radium-226 targets in 1978:
:{{nuclide|link=yes|radium|226}} + {{nuclide|link=yes|calcium|48}} → {{nuclide|link=yes|hassium|270}} + 4 {{SubatomicParticle|link=yes|Neutron}}
However, results are not available in the literature. The reaction was repeated at the JINR in June 2008 and 4 atoms of the isotope 270Hs were detected.{{cite web |url=http://www1.jinr.ru/Reports/2008/english/06_flnr_e.pdf |title=Flerov Laboratory of Nuclear Reactions}}{{page needed|date=October 2015}} In January 2009, the team repeated the experiment and a further 2 atoms of 270Hs were detected.{{cite web |url=http://www.np.ph.bham.ac.uk/iop09/iop_talks/07_04_09_Parallel_2/Y%20Tsyganov.ppt |title=Results of 226Ra+48Ca Experiment |last1=Tsyganov |first1=Yu. |last2=Oganessian |first2=Yu. |last3=Utyonkov |first3=V. |last4=Lobanov |first4=Yu. |last5=Abdullin |first5=F. |last6=Shirokovsky |first6=I. |last7=Polyakov |first7=A. |last8=Subbotin |first8=V. |last9=Sukhov |first9=A. |date=2009-04-07 |access-date=2012-12-25 }}{{dead link|date=July 2020|bot=medic}}{{cbignore|bot=medic}} [http://www.powershow.com/view1/1ac3df-ODU4Z/Results_of_226Ra_48Ca_Experiment_YuTsyganov_YuOganessian_VUtyonkov_YuLobanov_FAbdullin_IS_powerpoint_ppt_presentation Alt URL]
The team at Dubna studied the reaction between californium-249 targets and neon-22 projectiles in 1983 by detecting spontaneous fission activities:
:{{nuclide|link=yes|californium|249}} + {{nuclide|link=yes|neon|22}} → {{nuclide|hassium|271−x}} + x {{SubatomicParticle|link=yes|Neutron}}
Several short spontaneous fission activities were found, indicating the formation of nuclei of hassium.
The hot fusion reaction between uranium-238 targets and projectiles of the rare and expensive isotope sulfur-36 was conducted at the GSI in April–May 2008:
:{{nuclide|link=yes|uranium|238}} + {{nuclide|link=yes|sulfur|36}} → {{nuclide|link=yes|hassium|270}} + 4 {{SubatomicParticle|link=yes|Neutron}}
Preliminary results show that a single atom of 270Hs was detected. This experiment confirmed the decay properties of the isotopes 270Hs and 266Sg.[http://www.gsi.de/informationen/wti/library/scientificreport2008/PAPERS/NUSTAR-SHE-02.pdf Observation of 270Hs in the complete fusion reaction 36S+238U*] {{webarchive|url=https://web.archive.org/web/20120303012421/http://www.gsi.de/informationen/wti/library/scientificreport2008/PAPERS/NUSTAR-SHE-02.pdf |date=2012-03-03 }} R. Graeger et al., GSI Report 2008
In March 1994, the team at Dubna led by the late Yuri Lazarev attempted the analogous reaction with sulfur-34 projectiles:
:{{nuclide|link=yes|uranium|238}} + {{nuclide|link=yes|sulfur|34}} → {{nuclide|hassium|272−x}} + x {{SubatomicParticle|link=yes|Neutron}} (x = 4 or 5)
They announced the detection of 3 atoms of 267Hs from the 5n neutron evaporation channel.{{Cite journal|title=New Nuclide 267108 Produced by the 238U + 34S Reaction|doi=10.1103/PhysRevLett.75.1903|year=1995|last1=Lazarev |first1=Yu. A. |journal=Physical Review Letters |volume=75 |pages=1903–1906 |pmid=10059158 |last2=Lobanov |first2=YV |last3=Oganessian |first3=YT |last4=Tsyganov |first4=YS |last5=Utyonkov |first5=VK |last6=Abdullin |first6=FS |last7=Iliev |first7=S |last8=Polyakov |first8=AN |last9=Rigol |first9=J |last10=Shirokovsky |first10=I. |last11=Subbotin |first11=V. |last12=Sukhov |first12=A. |last13=Buklanov |first13=G. |last14=Gikal |first14=B. |last15=Kutner |first15=V. |last16=Mezentsev |first16=A. |last17=Sedykh |first17=I. |last18=Vakatov |first18=D. |last19=Lougheed |first19=R. |last20=Wild |first20=J. |last21=Moody |first21=K. |last22=Hulet |first22=E. |issue=10 |bibcode=1995PhRvL..75.1903L |display-authors=8|url=https://cds.cern.ch/record/284096/files/SCAN-9507002.pdf }} The decay properties were confirmed by the team at GSI in their simultaneous study of darmstadtium. The reaction was repeated at the GSI in January–February 2009 in order to search for the new isotope 268Hs. The team, led by Prof. Nishio, detected a single atom each of both 268Hs and 267Hs. The new isotope 268Hs underwent alpha decay to the previously known isotope 264Sg.
Between May 2001 and August 2005, a GSI–PSI (Paul Scherrer Institute) collaboration studied the nuclear reaction between curium-248 targets and magnesium-26 projectiles:
:{{nuclide|link=yes|curium|248}} + {{nuclide|link=yes|magnesium|26}} → {{nuclide|hassium|274−x}} + x {{SubatomicParticle|link=yes|Neutron}} (x = 3, 4, or 5)
The team studied the excitation function of the 3n, 4n, and 5n evaporation channels leading to the isotopes 269Hs, 270Hs, and 271Hs.[http://lch.web.psi.ch/files/anrep01/B-01heavies.pdf "Decay properties of 269Hs and evidence for the new nuclide 270Hs"] {{webarchive|url=https://www.webcitation.org/6CGIR6Ekz?url=http://lch.web.psi.ch/files/anrep01/B-01heavies.pdf |date=2012-11-18 }}, Turler et al., GSI Annual Report 2001. Retrieved 2008-03-01.{{cite web |url=http://www2.ha.physik.uni-muenchen.de/heaviest_atoms/talks/Dvorak.pdf |title=On the production and chemical separation of Hs (element 108) |last1=Dvorak |first1=Jan |date=2006-09-25 |publisher=Technical University of Munich |archive-url=https://web.archive.org/web/20090225155329/http://www2.ha.physik.uni-muenchen.de/heaviest_atoms/talks/Dvorak.pdf |archive-date=2009-02-25 |access-date=2012-12-23}} The synthesis of the doubly magic isotope 270Hs was published in December 2006 by the team of scientists from the Technical University of Munich.[http://www.gsi.de/informationen/wti/library/scientificreport2006/PAPERS/NUSTAR-SHE-06.pdf "Doubly magic 270Hs"] {{webarchive|url=https://web.archive.org/web/20120303012501/http://www.gsi.de/informationen/wti/library/scientificreport2006/PAPERS/NUSTAR-SHE-06.pdf |date=2012-03-03 }}, Turler et al., GSI report, 2006. Retrieved 2008-03-01. It was reported that this isotope decayed by emission of an alpha particle with an energy of 8.83 MeV and a half-life of ~22 s. This figure has since been revised to 3.6 s.
==As decay product==
Hassium isotopes have been observed as decay products of darmstadtium. Darmstadtium currently has ten known isotopes, all but one of which have been shown to undergo alpha decays to become hassium nuclei with mass numbers between 263 and 277. Hassium isotopes with mass numbers 266, 272, 273, 275, and 277 to date have only been produced by decay of darmstadtium nuclei. Parent darmstadtium nuclei can be themselves decay products of copernicium, flerovium, or livermorium.{{cite web |url=http://www.nndc.bnl.gov/chart/reCenter.jsp?z=108&n=161 |title=Interactive Chart of Nuclides |publisher=Brookhaven National Laboratory |last=Sonzogni |first=Alejandro |location=National Nuclear Data Center |access-date=2008-06-06 |archive-date=2016-01-12 |archive-url=https://web.archive.org/web/20160112161051/http://www.nndc.bnl.gov/chart/reCenter.jsp?z=108&n=161 |url-status=dead }} For example, in 2004, the Dubna team identified hassium-277 as a final product in the decay of livermorium-293 via an alpha decay sequence:
:{{nuclide|livermorium|293}} → {{nuclide|flerovium|289}} + {{nuclide|helium|4}}
:{{nuclide|flerovium|289}} → {{nuclide|copernicium|285}} + {{nuclide|helium|4}}
:{{nuclide|copernicium|285}} → {{nuclide|darmstadtium|281}} + {{nuclide|helium|4}}
:{{nuclide|darmstadtium|281}} → {{nuclide|hassium|277}} + {{nuclide|helium|4}}
{{clear}}
=Unconfirmed isotopes=
;277mHs
An isotope assigned to 277Hs has been observed on one occasion decaying by SF with a long half-life of ~11 minutes.{{cite journal |title=Synthesis of superheavy nuclei in 48Ca+244Pu interactions |author1=Yu. Ts. Oganessian |author2=V. K. Utyonkov |author3=Yu. V. Lobanov |author4=F. Sh. Abdullin |author5=A. N. Polyakov |author6=I. V. Shirokovsky |author7=Yu. S. Tsyganov |author8=G. G. Gulbekian |author9=S. L. Bogomolov |display-authors=etal |journal=Nuclei Experiment: Physics of Atomic Nuclei |date=October 2000 |volume=63 |issue=10 |pages=1679–1687 |doi=10.1134/1.1320137 |bibcode=2000PAN....63.1679O|s2cid=118044323 }} The isotope is not observed in the decay of the ground state of 281Ds but is observed in the decay from a rare, as yet unconfirmed isomeric level, namely 281mDs. The half-life is very long for the ground state and it is possible that it belongs to an isomeric level in 277Hs. It has also been suggested that this activity actually comes from 278Bh, formed as the great-great-granddaughter of 290Fl through one electron capture to 290Nh and three further alpha decays. Furthermore, in 2009, the team at the GSI observed a small alpha decay branch for 281Ds producing the nuclide 277Hs decaying by SF in a short lifetime. The measured half-life is close to the expected value for ground state isomer, 277Hs. Further research is required to confirm the production of the isomer.
=Retracted isotopes=
;273Hs
In 1999, American scientists at the University of California, Berkeley, announced that they had succeeded in synthesizing three atoms of 293118.{{cite journal |last1=Ninov |first1=V. |year=1999 |title=Observation of Superheavy Nuclei Produced in the Reaction of {{SimpleNuclide|Krypton|86}} with {{SimpleNuclide|Lead|208}} |journal=Physical Review Letters |volume=83 |issue=6 |pages=1104–1107 |doi=10.1103/PhysRevLett.83.1104 |bibcode=1999PhRvL..83.1104N|url=https://zenodo.org/record/1233919 |display-authors=etal}} These parent nuclei were reported to have successively emitted three alpha particles to form hassium-273 nuclei, which were claimed to have undergone an alpha decay, emitting alpha particles with decay energies of 9.78 and 9.47 MeV and half-life 1.2 s, but their claim was retracted in 2001.{{Cite news |author=Public Affairs Department |date=21 July 2001 |title=Results of element 118 experiment retracted |url=http://enews.lbl.gov/Science-Articles/Archive/118-retraction.html |publisher=Berkeley Lab |access-date=2008-01-18 |archive-url=https://web.archive.org/web/20080129191344/http://enews.lbl.gov/Science-Articles/Archive/118-retraction.html |archive-date=29 January 2008 |url-status=dead }} The isotope, however, was produced in 2010 by the same team. The new data matched the previous (fabricated){{cite news |url=https://www.nytimes.com/2002/10/15/science/at-lawrence-berkeley-physicists-say-a-colleague-took-them-for-a-ride.html?scp=2&sq=victor%20ninov&st=cse&pagewanted=1 |title=At Lawrence Berkeley, Physicists Say a Colleague Took Them for a Ride |author=George Johnson |newspaper=The New York Times |date=15 October 2002}} data.
=<sup>270</sup>Hs: prospects for a deformed doubly magic nucleus=
According to macroscopic-microscopic (MM) theory, Z = 108 is a deformed proton magic number, in combination with the neutron shell at N = 162. This means that such nuclei are permanently deformed in their ground state but have high, narrow fission barriers to further deformation and hence relatively long SF partial half-lives. The SF half-lives in this region are typically reduced by a factor of 109 in comparison with those in the vicinity of the spherical doubly magic nucleus 298Fl, caused by an increase in the probability of barrier penetration by quantum tunnelling, due to the narrower fission barrier.
In addition, N = 162 has been calculated as a deformed neutron magic number and hence the nucleus 270Hs has promise as a deformed doubly magic nucleus. Experimental data from the decay of Z = 110 isotopes 271Ds and 273Ds, provides strong evidence for the magic nature of the N = 162 sub-shell. The recent synthesis of 269Hs, 270Hs, and 271Hs also fully support the assignment of N = 162 as a magic closed shell. In particular, the low decay energy for 270Hs is in complete agreement with calculations.{{Cite journal|title = Properties of the hypothetical spherical superheavy nuclei|author = Robert Smolanczuk|year = 1997 |journal=Physical Review C |volume=56|issue=2 |pages = 812–824 |doi= 10.1103/PhysRevC.56.812|bibcode = 1997PhRvC..56..812S }}
==Evidence for the ''Z'' = 108 deformed proton shell==
Evidence for the magicity of the Z = 108 proton shell can be deemed from two sources:
- the variation in the partial spontaneous fission half-lives for isotones
- the large gap in Qα for isotonic pairs between Z = 108 and Z = 110.
For SF, it is necessary to measure the half-lives for the isotonic nuclei 268Sg, 270Hs and 272Ds. Since fission of 270Hs has not been measured, detailed data of 268Sg fission is not yet available, and 272Ds is still unknown, this method cannot be used to date to confirm the stabilizing nature of the Z = 108 shell.
However, good evidence for the magicity of Z = 108 can be deemed from the large differences in the alpha decay energies measured for 270Hs, 271Ds and 273Ds. More conclusive evidence would come from the determination of the decay energy of the yet-unknown nuclide 272Ds.
=Nuclear isomerism=
;277Hs
An isotope assigned to 277Hs has been observed on one occasion decaying by spontaneous fission with a long half-life of ~11 minutes.{{cite journal|doi=10.1134/1.1320137|title=Synthesis of superheavy nuclei in 48Ca+244Pu interactions|year=2000|last1=Oganessian|first1=Yu. Ts.|last2=Utyonkov|first2=V. K.|last3=Lobanov|first3=Yu. V.|last4=Abdullin|first4=F. Sh.|last5=Polyakov|first5=A. N.|last6=Shirokovsky|first6=I. V.|last7=Tsyganov|first7=Yu. S.|last8=Gulbekian|first8=G. G.|last9=Bogomolov|first9=S. L.|last10=Gikal|first10=B. N.|last11=Mezentsev|first11=A. N.|last12=Iliev|first12=S.|last13=Subbotin|first13=V. G.|last14=Sukhov|first14=A. M.|last15=Ivanov|first15=O. V.|last16=Buklanov|first16=G. V.|last17=Subotic|first17=K.|last18=Itkis|first18=M. G.|last19=Moody|first19=K. J.|last20=Wild|first20=J. F.|last21=Stoyer|first21=N. J.|last22=Stoyer|first22=M. A.|last23=Lougheed|first23=R. W.|journal=Physics of Atomic Nuclei|volume=63|issue=10|pages=1679–1687|bibcode = 2000PAN....63.1679O |s2cid=118044323|display-authors=8}} The isotope is not observed in the decay of the most common isomer of 281Ds but is observed in the decay from a rare, as yet unconfirmed isomeric level, namely 281mDs. The half-life is very long for the ground state and it is possible that it belongs to an isomeric level in 277Hs. Furthermore, in 2009, the team at the GSI observed a small alpha decay branch for 281Ds producing an isotope of 277Hs decaying by spontaneous fission with a short lifetime. The measured half-life is close to the expected value for ground state isomer, 277Hs. Further research is required to confirm the production of the isomer. A more recent study suggests that this observed activity may actually be from 278Bh.{{cite journal |last1=Hofmann |first1=S. |last2=Heinz |first2=S. |first3=R. |last3=Mann |first4=J. |last4=Maurer |first5=G. |last5=Münzenberg |first6=S. |last6=Antalic |first7=W. |last7=Barth |first8=H. G. |last8=Burkhard |first9=L. |last9=Dahl |first10=K. |last10=Eberhardt |first11=R. |last11=Grzywacz |first12=J. H. |last12=Hamilton |first13=R. A. |last13=Henderson |first14=J. M. |last14=Kenneally |first15=B. |last15=Kindler |first16=I. |last16=Kojouharov |first17=R. |last17=Lang |first18=B. |last18=Lommel |first19=K. |last19=Miernik |first20=D. |last20=Miller |first21=K. J. |last21=Moody |first22=K. |last22=Morita |first23=K. |last23=Nishio |first24=A. G. |last24=Popeko |first25=J. B. |last25=Roberto |first26=J. |last26=Runke |first27=K. P. |last27=Rykaczewski |first28=S. |last28=Saro |first29=C. |last29=Scheidenberger |first30=H. J. |last30=Schött |first31=D. A. |last31=Shaughnessy |first32=M. A. |last32=Stoyer |first33=P. |last33=Thörle-Popiesch |first34=K. |last34=Tinschert |first35=N. |last35=Trautmann |first36=J. |last36=Uusitalo |first37=A. V. |last37=Yeremin |date=2016 |title=Review of even element super-heavy nuclei and search for element 120 |journal=The European Physical Journal A |volume=2016 |issue=52 |pages=180 |doi=10.1140/epja/i2016-16180-4|bibcode=2016EPJA...52..180H |s2cid=124362890 |url=https://zenodo.org/record/897926 }}
;269Hs
The direct synthesis of 269Hs has resulted in the observation of three alpha particles with energies 9.21, 9.10, and 8.94 MeV emitted from 269Hs atoms. However, when this isotope is indirectly synthesized from the decay of 277Cn, only alpha particles with energy 9.21 MeV have been observed, indicating that this decay occurs from an isomeric level. Further research is required to confirm this.
;267Hs
267Hs is known to decay by alpha decay, emitting alpha particles with energies of 9.88, 9.83, and 9.75 MeV. It has a half-life of 52 ms. In the recent syntheses of 271Ds and 271mDs, additional activities have been observed. A 0.94 ms activity emitting alpha particles with energy 9.83 MeV has been observed in addition to longer lived ~0.8 s and ~6.0 s activities. Currently, none of these are assigned and confirmed and further research is required to positively identify them.
;265Hs
The synthesis of 265Hs has also provided evidence for two isomeric levels. The ground state decays by emission of an alpha particle with energy 10.30 MeV and has a half-life of 2.0 ms. The isomeric state has 300 keV of excess energy and decays by the emission of an alpha particle with energy 10.57 MeV and has a half-life of 0.75 ms.
;Future experiments
Scientists at the GSI are planning to search for isomers of 270Hs using the reaction 226Ra(48Ca,4n) in 2010 using the new TASCA facility at the GSI.{{Cite web|url=http://www-win.gsi.de/tasca08/contributions/TASCA08_Cont_Andersson.pdf|archive-url=https://web.archive.org/web/20120305104908/http://www-win.gsi.de/tasca08/contributions/TASCA08_Cont_Andersson.pdf|url-status=dead|title=TASCA in Small Image Mode Spectroscopy|archive-date=March 5, 2012}} In addition, they also hope to study the spectroscopy of 269Hs, 265Sg and 261Rf, using the reaction 248Cm(26Mg,5n) or 226Ra(48Ca,5n). This will allow them to determine the level structure in 265Sg and 261Rf and attempt to give spin and parity assignments to the various proposed isomers.[http://www-win.gsi.de/tasca08/contributions/TASCA08_Cont_Yakushev2.pdf Hassium spectroscopy experiments at TASCA], A. Yakushev {{webarchive |url=https://web.archive.org/web/20120305105000/http://www-win.gsi.de/tasca08/contributions/TASCA08_Cont_Yakushev2.pdf |date=March 5, 2012 }}
=Physical production yields=
The tables below provides cross-sections and excitation energies for nuclear reactions that produce isotopes of hassium directly. Data in bold represent maxima derived from excitation function measurements. + represents an observed exit channel.
==Cold fusion==
class="wikitable" | |||||
Projectile | Target | CN | 1n | 2n | 3n |
---|---|---|---|---|---|
58Fe | 208Pb | 266Hs | 69 pb, 13.9 MeV | 4.5 pb | |
58Fe | 207Pb | 265Hs | 3.2 pb |
==Hot fusion==
class="wikitable" | |||||
Projectile | Target | CN | 3n | 4n | 5n |
---|---|---|---|---|---|
48Ca | 226Ra | 274Hs | 9.0 pb | ||
36S | 238U | 274Hs | 0.8 pb | ||
34S | 238U | 272Hs | 2.5 pb, 50.0 MeV | ||
26Mg | 248Cm | 274Hs | 2.5 pb | 3.0 pb | 7.0 pb |
=Theoretical calculations=
==Evaporation residue cross sections==
The below table contains various targets-projectile combinations for which calculations have provided estimates for cross section yields from various neutron evaporation channels. The channel with the highest expected yield is given.
DNS = Di-nuclear system ; σ = cross section
class="wikitable" style="text-align:center" | ||||||
Target | Projectile | CN | Channel (product) | σ max | Model | Ref |
---|---|---|---|---|---|---|
136Xe
| 136Xe ||272Hs || 1–4n (271–268Hs) ||10−6 pb ||DNS || [https://arxiv.org/abs/0904.2994 Influence of entrance channels on formation of superheavy nuclei in massive fusion reactions], Zhao-Qing Feng, Jun-Qing Li, Gen-Ming Jin, April 2009 | ||||||
238U | ||||||
238U
| 36S ||274Hs || 4n (270Hs) ||42.97 pb ||DNS || {{cite journal|last1=Feng|first1=Z.|last2=Jin|first2=G.|last3=Li|first3=J.|title=Production of new superheavy Z=108–114 nuclei with 238U, 244Pu and 248,250Cm targets|date=2009|arxiv=0912.4069|journal=Physical Review C|volume=80|pages=057601|doi=10.1103/PhysRevC.80.057601|s2cid=118733755 }} | ||||||
244Pu | ||||||
248Cm | ||||||
250Cm |
References
{{reflist}}
- [http://www.nndc.bnl.gov/chart/reCenter.jsp?z=108&n=162 National Nuclear Data Center, Brookhaven National Laboratory] {{Webarchive|url=https://web.archive.org/web/20160112161051/http://www.nndc.bnl.gov/chart/reCenter.jsp?z=108&n=162 |date=2016-01-12 }}
Half-life, spin, and isomer data selected from:
- {{cite journal |title=The NUBASE2016 evaluation of nuclear properties |doi=10.1088/1674-1137/41/3/030001 |last1=Audi |first1=G. |last2=Kondev |first2=F. G. |last3=Wang |first3=M. |last4=Huang |first4=W. J. |last5=Naimi |first5=S. |display-authors=3 |journal=Chinese Physics C |volume=41 |issue=3 |pages=030001 |year=2017|bibcode=2017ChPhC..41c0001A |s2cid=126750783 |ref={{harvid|Audi et al.|2017}} |url=http://pdfs.semanticscholar.org/7c02/89532fe80c913edd952e8caffd555013f596.pdf |archive-url=https://web.archive.org/web/20200801004253/http://pdfs.semanticscholar.org/7c02/89532fe80c913edd952e8caffd555013f596.pdf |url-status=dead |archive-date=2020-08-01 }}
- {{NUBASE 2012}}
- {{NUBASE 2003}}
- {{NNDC}}
- {{CRC85|chapter=11}}
- {{cite web |author=GSI |year=2011 |title=Superheavy Element Research at GSI |url=http://tan11.jinr.ru/pdf/08_Sep/S_1/01_Duellmann.pdf |publisher=GSI |access-date=20 August 2012}}
{{Navbox element isotopes}}