Lithium bromide

{{chembox

| Watchedfields = changed

| verifiedrevid = 450703470

| ImageFile1 = File:NaCl_polyhedra.png

| ImageCaption1 = __ Li+     __ Br

| ImageFile2 = Lithium-bromide-3D-ionic.png

| IUPACName = Lithium bromide

| Section1 = {{Chembox Identifiers

| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}

| ChemSpiderID = 74049

| UNII_Ref = {{fdacite|correct|FDA}}

| UNII = 864G646I84

| InChI = 1/BrH.Li/h1H;/q;+1/p-1

| InChIKey = AMXOYNBUYSYVKV-REWHXWOFAS

| SMILES = [Li+].[Br-]

| StdInChI_Ref = {{stdinchicite|correct|chemspider}}

| StdInChI = 1S/BrH.Li/h1H;/q;+1/p-1

| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}

| StdInChIKey = AMXOYNBUYSYVKV-UHFFFAOYSA-M

| CASNo = 7550-35-8

| CASNo_Ref = {{cascite|correct|CAS}}

| PubChem = 82050

| EINECS = 231-439-8

| RTECS = OJ5755000

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| Section2 = {{Chembox Properties

| Formula = LiBr

| MolarMass = 86.845 g/mol

| Appearance = White hygroscopic solid

| Density = 3.464 g/cm3

| MeltingPtC = 550

| MeltingPt_ref = Haynes, p. 4.70

| BoilingPtC = 1300

| BoilingPt_ref =

| Solubility = 143 g/100 mL (0 °C)
166.7 g/100 mL (20 °C)
266 g/100 mL (100 °C)Haynes, p. 5.169

| SolubleOther = soluble in methanol, ethanol, ether, acetone
slightly soluble in pyridine

| RefractIndex = 1.7843 (589 nm)Haynes, p. 10.249

| MagSus = −34.3·10−6 cm3/molHaynes, p. 4.128

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| Section3 = {{Chembox Structure

| Structure_ref ={{cite journal|doi=10.1002/zaac.19723910311|title=Über die Systeme Alkalimetallbromid/Mangan(II)-bromid|year=1972|last1=Seifert|first1=H.-J.|last2=Dau|first2=E.|journal=Zeitschrift für Anorganische und Allgemeine Chemie|volume=391|issue=3|pages=302–312}}

| CrystalStruct = Cubic, Pearson symbol cF8, No. 225

| SpaceGroup = Fm{{overline|3}}m

| LattConst_a = 0.5496 nm

}}

| Section4 = {{Chembox Thermochemistry

| Thermochemistry_ref=Haynes, p. 5.25

| DeltaHf = −351.2 kJ/mol

| DeltaHc =

| DeltaGf = −342.0 kJ/mol

| Entropy = 74.3 J/mol K

| HeatCapacity =

}}

| Section5 = {{Chembox Hazards

| GHSPictograms = {{GHS07}}

| GHSSignalWord = Warning

| HPhrases = {{H-phrases|315|317|319}}[https://www.sigmaaldrich.com/catalog/product/aldrich/229733?lang=en®ion=US Lithium bromide]. SIgma Aldrich

| NFPA-H = 2

| NFPA-F = 0

| NFPA-R = 0

| NFPA-S = W

| FlashPt = Not-flammable

| LD50 = 1800 mg/kg (oral, rat){{cite web|url=https://chem.nlm.nih.gov/chemidplus/rn/7550-35-8|title=ChemIDplus – 7550-35-8 – AMXOYNBUYSYVKV-UHFFFAOYSA-M – Lithium bromide – Similar structures search, synonyms, formulas, resource links, and other chemical information.|first=Michael|last=Chambers|website=chem.sis.nlm.nih.gov|access-date=3 April 2018}}

}}

| Section8 = {{Chembox Related

| OtherAnions = Lithium fluoride
Lithium chloride
Lithium iodide

| OtherCations = Sodium bromide
Potassium bromide
Rubidium bromide
Caesium bromide

}}

}}

Lithium bromide (LiBr) is a chemical compound of lithium and bromine. Its extreme hygroscopic character makes LiBr useful as a desiccant in certain air conditioning systems.Wietelmann, Ulrich and Bauer, Richard J. (2005) "Lithium and Lithium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry Wiley-VCH: Weinheim. {{doi|10.1002/14356007.a15_393.pub2}}

Production and properties

File:Sollibr.PNG

File:LiBr-Phase.svg

LiBr is prepared by treating an aqueous suspension of lithium carbonate with hydrobromic acid or by reacting lithium hydroxide with bromine. It forms several crystalline hydrates, unlike the other alkali metal bromides.{{Holleman&Wiberg|page=}}

Lithium hydroxide and hydrobromic acid (aqueous solution of hydrogen bromide) will precipitate lithium bromide in the presence of water.

:LiOH + HBr → LiBr + H2O

Uses

A 50–60% aqueous solution of lithium bromide is used in air-conditioning systems as desiccant. It is also used in absorption chilling along with water (see absorption refrigerator). Solid LiBr is a useful reagent in organic synthesis. It is included into oxidation and hydroformylation catalysts; it is also used for deprotonation and dehydration of organic compounds containing acidic protons, and for the purification of steroids and prostaglandins.

=Medical applications=

Lithium bromide was used as a sedative beginning in the early 1900s, but it fell into disfavor in the 1940s as newer sedatives became available and when some heart patients died after using the salt substitute lithium chloride.{{cite web|url=http://www.webmd.com/content/Article/87/99356.htm?pagenumber=1|title=Bipolar Disorder: Treatment and Care|website=webmd.com|access-date=3 April 2018}} Like lithium carbonate and lithium chloride, it was used as treatment for bipolar disorder.

Hazards

Lithium salts are psychoactive and somewhat corrosive. Heat is quickly generated when lithium bromide is dissolved into water because it has a negative enthalpy of solution.

References

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Cited sources