Phosphate sulfate
{{Short description|Compound with phosphate and sulfate ions}}
The phosphate sulfates are mixed anion compounds containing both phosphate and sulfate ions.
Related compounds include the arsenate sulfates, phosphate selenates, and arsenate selenates.
Some hydrogen phosphate sulfates are superprotonic conductors.
List
class="wikitable"
! !chem !mw !crystal system ! space group !unit cell !volume !density !comment !references |
Sanjuanite
|Al2(PO4)(SO4)(OH)·9H2O | | | | | | | |
Hotsonite
|Al11(SO4)3(PO4)2(OH)21 · 16H2O | |triclinic | |a=11.23, b=11.66 c=10.55 α=112° 32′, β=107° 32′ γ=64° 27′ | | |refract: α = 1.519 γ = 1.521 |
Arangasite
|Al2F(PO4)(SO4)·9H2O | |monoclinic |P2/a |a = 7.073, b = 9.634, c = 10.827, β = 100.40°, Z = 2 |725.7 | | |
peisleyite
|Na3Al16(SO4)2(PO4)10(OH)17 · 20H2O | |monoclinic | |a 13.31, b 12.62, c 23.15, β 110.0°, Z = 2 | | |discredited |
peisleyite
|Na2Al9[(P,S)O4]8(OH)6·28H2O | |triclinic |P{{overbar|1}} |a = 9.28, b = 11.98, c = 13.25, α = 91.3, β = 75.6, γ = 67.67°, Z = 4 |1308 | | |
Woodhouseite
|CaAl3(PO4)(SO4)(OH)6 | |trigonal |R{{overbar|3}}m |a = 6.993, c = 16.386 |693.95 |3.0 |Uniaxial (+) nω = 1.636 nε = 1.647 Birefringence: δ = 0.011 |
Ardéalite
|Ca2H(PO4)(SO4)•4H2O | |monoclinic | |a = 5.721, b = 30.95, c = 6.265, β= 117.26° Z = 4 |986.11 |2.32 | |
Destinezite Diadochite
|Fe2(PO4)(SO4)(OH)•6H2O | |triclinic |P{{overbar|1}} |a = 9.570, b = 9.716, c = 7.313, α = 98.74°, β = 107.90°, γ = 63.86° Z = 2 | | | |
bohuslavite
|FeIII4(PO4)3(SO4)(OH)(H2O)10·nH2O (5 ≤ n ≤ 14) | |triclinic |P{{overbar|1}} |a = 13.376 b = 13.338 c = 10.863 α = 92.80, β = 91.03, γ = 119.92°, Z = 2 |1675.7 | |pink |
Borickyite
|(Ca,Mg)(Fe3+,Al)4(PO4,SO4,CO3)(OH)8·3–7.5H2O | | | | | | | |
Camaronesite
|[Fe3+(H2O)2(PO3OH)]2(SO4)·1–2H2O | |trigonal |R32 |a = 9.0833, c = 42.944, Z = 9 |3068.5 | | |
|Fe3+4(PO4)3(SO4)(OH)·18H2O
| |triclinic |P{{overbar|1}} |a=13.376, b 13.338, c 10.863, α 92.80, β 91.03, γ 119.92° |1675.7 | | |
vanderheydenite
|Zn6(PO4)2(SO4)(OH)4·7H2O | |monoclinic |P21/n |a = 6.204 b = 19.619, c = 7.782, β = 90.67° |947.1 | |biaxial (–) α = 1.565, β = 1.580 γ = 1.582. 2V = 39.8° |
Svanbergite
|SrAl3(PO4)(SO4)(OH)6 | |trigonal |R{{overbar|3}}m |a = 6.97, c = 16.59 Z=3 |697.98 |3.2 |Uniaxial (+) nω = 1.631 - 1.635 nε = 1.646 - 1.649 Birefringence: δ = 0.015 |
Birchite
|Cd2Cu2(PO4)2(SO4) ·5H2O | | | |a = 10.489 b = 20.901 c = 6.155 Z=4 |1349.6 |3.647 |biaxial positive, nα = 1.624, nβ = 1.636, nγ = 1.669, 2Vcalc = +63°. |
Corkite
|PbFe3(OH)6SO4PO4 | |trigonal |R{{overbar|3}}m |a = 7.32, c = 17.02 Z=3 |781.2 |4.295 |Uniaxial (-) nω = 1.930 nε = 1.930 n = 1.93 - 1.96 Birefringence 0.03 |
|BaAl3(PO4)(SO4)(OH)6
| |trigonal |R{{overbar|3}}m |a = , c = Z=3 | | | |
hinsdalite
|(Pb,Sr)Al3(PO4)(SO4)(OH)6 | | | | | | | |
Tsumebite
|Pb2Cu(PO4,SO4)(OH) | | | | | | | |
Delvauxite
|CaFe43+(PO4,SO4)2(OH)8·4–6H2O | | | | | | | |
Rossiantonite
|Al3(PO4)(SO4)2(OH)2(H2O)10·4H2O | |triclinic |P{{overbar|1 }} |a = 10.3410, b = 10.9600, c = 11.1446, α = 86.985, β = 65.727, γ = 75.064°, Z = 2 |1110.5 | | |
Schlossmacherite
|(H3O,Ca)Al3(AsO4,PO4,SO4)2(OH)6 | | | | | | | |
Arthurite
|Cu(Fe3+)2(AsO4,PO4,SO4)2(O,OH)2·4(H2O) | | | | | | | |
cobaltarthurite
| | | | | | | | |
Phosphoinnelite
|Ba4Na3Ti3Si4O14(PO4,SO4)2(O,F)3 | |triclinic |P{{overbar|1}}? |a = 5.38, b = 7.10, c = 14.76; α = 99.00°, β = 94.94°, γ = 90.14° Z = 1 |555 |3.82 |biaxial (+), α = 1.730, β = 1.745, and γ = 1.764, 2V 90° |
Francolite
|(Ca, Mg, Sr, Na)10(PO4, SO4, CO3)6F2–3 | | | | | | | |
|Al4(UO2)2(PO4)4(SO4)(OH)2 · 18H2O
| | | | | | | |
|Al4(UO2)2(PO4)4(SO4)(OH)2 · 20H2O
| | | | | | | |
Coconinoite
|Fe2Al2(UO2)2(PO4)4(SO4)(OH)2 · 20H2O | |monoclinic |C2/c |a =12.45, b = 12.96, c = 17.22, β = 105.7° | | | |
xiangjiangite
|Fe2Al2(UO2)2(PO4)4(SO4)(OH)2 · 22H2O | |tetragonal | |a = 7.17 Å, b = 7.17 Å, c = 22.22 Å Z=1 |1,142 | |Biaxial (-) nα = 1.558 nβ = 1.576 nγ = 1.593 2V: 87° |
Artificial
class="wikitable"
!chem !mw !crystal system ! space group !unit cell Å !volume !density !comment !references |
[H4N+]2·HSO4−·H2PO4−
| | | | | | | |{{Cite journal |last1=BEKTUROV |first1=AB |last2=NA |first2=DZHUMAGULOVA |last3=ZK |first3=KAIPOVA |last4=RS |first4=ERZHANOVA |last5=VI |first5=LITVINENKO |date=1980 |title=RECHERCHES DANS LE DOMAINE DES SULFATOPHOSPHATES. 5. TRANSFORMATIONS THERMIQUES DES MELANGES DE PHOSPHATE ET DE SULFATE D'AMMONIUM MONOSUBSTITUES ET D'HYDROSULFATE-DIHYDRO-PHOSPHATE D'AMMONIUM (NH4)2(HSO4.H2PO4) |url=https://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=PASCAL8130086444 |journal=Recherches dans le Domaine des Sulfatophosphates. 5. Transformations Thermiques des Melanges de Phosphate et de Sulfate d'Ammonium Monosubstitues et d'Hydrosulfate-Dihydro-Phosphate d'Ammonium (Nh4)2(Hso4.H2Po4)}}{{Cite web |last=PubChem |title=Diammonium phosphate sulphate |url=https://pubchem.ncbi.nlm.nih.gov/compound/15607556 |access-date=2022-07-13 |website=pubchem.ncbi.nlm.nih.gov |language=en}} |
NH4(HSO4)0.45(H2PO4)0.55
| |orthorhombic | | | | | |
18-crown[6]·[NH4][H2PO4]0.5[HSO4]0.5·H2O
| |orthrhombic |F2dd |a=8.710 b= 28.868 c=31.206 Z=16 |7846 |1.346 |dehydrate at 70° |
[(C2H5)4N+]2·HSO4−·H2PO4−
| |Monoclinic |C2/c |a = 28.0787 b = 11.8671 c = 14.1533 β = 100.739° Z=8 |4633.46 |1.303 |colourless; decompose at 353K |
(NH2CH2COOH)3(H2SO4)0.7(H3PO4)0.3
| |monoclinic | | | | |called TGSP; colourless; ferroelectric, curie point 51 °C; pyroelectric | |
Na(HSO4)(H3PO4)
| |monoclinic |P 21 |a = 5.449, b = 6.832, c = 8.718, β = 95.88°, Z = 2 | 322.8 | | |
K2(HSO4)(H2PO4)
| |monoclinic |P 21/c |a = 11.150, b = 7.371, c = 9.436, β = 92.29°, Z = 4 | 774.9 | | |
K4(HSO4)3(H2PO4)
| |triclinic |P 1 |a = 7.217, b = 7.521, c = 7.574, α = 71.52°, β = 88.28°, γ = 86.20°, Z = 1 | 389.1 | | |
K4(PO2F2)2(S2O7)
|534.46 |monoclinic |C2/c |a = 13.00, b = 7.543, c = 19.01, β = 130.07°, Z = 4 |1426.5 |2.489 |colourless; pyrosulfate + difluorophosphate |
K3[O3SOPO2OSO3]
| | | | | | | |
H1−xTi2(PO4)3−x(SO4)x (x=0.5–1)
| | | | | | | |
Na2MgTi(SO4)(PO4)2
| |trigonal |R{{overbar|3}}c |a=8.4796 c=21.8091 Z=6 |1358.1 |2.818 | |
K2MgTi(SO4)(PO4)2
| |cubic |P213 |a=9.8743 Z=4 |962.84 |2.872 | |
Ca10-xNax(PO4)6-x(SO4)xF2
| |monoclinic | | | | | |
NaFe2(PO4)(SO4)2
| |hexagonal |R{{overbar|3}}c |a=8.4243 c=21.973 | | | |
NaFe1.4V0.6(PO4)(SO4)2
| | | | | | | |
[Ni(C14H10N4)3]4(PO4)2(SO4) (C14H10N4=2,2'-bi-1H-benzimidazole)
|3331.96 |cubic |I{{overbar|4}}3d |a = 24.964 Z=4 |15558 |1.423 |green |
Rb2(HSO4)(H2PO4)
| |monoclinic |P21/n |a=7.448, b=7.552, c=7.632, β=100.47°, Z=2 |422.1 | | |{{Cite journal |last1=Komornikov |first1=V. A. |last2=Grebenev |first2=V. V. |last3=Andreev |first3=P. V. |last4=Dmitricheva |first4=E. V. |date=May 2015 |title=Study of phase equilibria in the Rb3H(SO4)2-RbH2PO4-H2O system |url=http://link.springer.com/10.1134/S1063774515030086 |journal=Crystallography Reports |language=en |volume=60 |issue=3 |pages=431–437 |doi=10.1134/S1063774515030086 |bibcode=2015CryRp..60..431K |s2cid=101238604 |issn=1063-7745|url-access=subscription }}{{Cite journal |last1=Stiewe |first1=A. |last2=Sonntag |first2=R. |last3=Troyanov |first3=S.I. |last4=Hansen |first4=T. |last5=Kemnitz |first5=E. |date=January 2000 |title=Synthesis and Structure Determination of Rb2(HSO4)(H2PO4) and Rb4(HSO4)3(H2PO4) by X-Ray Single Crystal and Neutron Powder Diffraction |url=https://linkinghub.elsevier.com/retrieve/pii/S0022459699984682 |journal=Journal of Solid State Chemistry |language=en |volume=149 |issue=1 |pages=9–15 |doi=10.1006/jssc.1999.8468|bibcode=2000JSSCh.149....9S |url-access=subscription }} |
Rb2(HSO4)(H2PO4)
| |monoclinic |P21/c |a=11.555, b=7.536, c=9.593, β=91.56, Z=4 |853.0 | |at 160K |
Rb4(HSO4)3(H2PO4)
| |orthorhombic |P21212 |a=7.612, b=14.795, c=7.446, Z=2 |838.6 | | |
18-crown[6]·Rb[H2PO4]0.5[HSO4]0.5·3H2O
| |monoclinic |C2/c |a=19.802 b=8.447 c=25.777 β=101.00° Z=8 |4232 |1.572 |dehydrate at 70° |
Rb2MgTi(SO4)(PO4)2
| | | | | | | |
Sr4(PO4)2SO4
| | | | | | | |
NaZrMg(PO4)(SO4)2
| |hexagonal |R{{overbar|3}}c | | | | |
NaZrCo(PO4)(SO4)2
| |hexagonal |R{{overbar|3 }}c | | | | |
NaZrNi(PO4)(SO4)2
| |hexagonal |R{{overbar|3}}c | | | | |
NaZrCu(PO4)(SO4)2
| |hexagonal |R{{overbar|3}}c | | | | |
NaZrZn(PO4)(SO4)2
| |hexagonal |R{{overbar|3}}c | | | | |
NaZrAl(PO4)2(SO4)
| |hexagonal |R{{overbar|3}}c | | | | |
NaZrFe(PO4)2(SO4)
| |hexagonal |R{{overbar|3}}c | | | | |
H3OSb2(SO4)2(PO4)
| |triclinic |P{{overbar|1 }} |a=5.134 b=7.908 c=12.855, α=81.401° β=87.253° γ=86.49° | | | |
KSb2(SO4)2(PO4)
| |triclinic |P{{overbar|1}} |a=5.1453 =7.9149 c=12.6146, α=82.054° β=87.715° γ=86.655° | | | |
RbSb2(SO4)2(PO4)
| |triclinic |P{{overbar|1}} |a=5.1531 b=7.957 c=12.845, α=81.801° β=87.676° γ=86.703° | | | |
Cs2(HSO4)(H2PO4)
| |cubic | |ao=4.926 | | |>105 °C but can be supercooled |
Cs2(HSO4)(H2PO4)
| |monoclinic |P21/n |a = 7.856 b = 7.732 c = 7.827, β= 99.92° Z=2 |468.3 |3.261 |can substitute 2.3% ammonium; proton conductivity at 110 °C is 3×10−3 Ω−1cm−1 |{{Cite journal |last1=Chisholm |first1=Calum R. I. |last2=Haile |first2=Sossina M. |date=1999-12-01 |title=Structure and thermal behavior of the new superprotonic conductor Cs 2 (HSO 4 )(H 2 PO 4 ) |url=http://scripts.iucr.org/cgi-bin/paper?S0108768199009921 |journal=Acta Crystallographica Section B: Structural Science |volume=55 |issue=6 |pages=937–946 |doi=10.1107/S0108768199009921 |pmid=10927436 |bibcode=1999AcCrB..55..937C |issn=0108-7681}}{{Cite journal |last1=Hayashi |first1=Shigenobu |last2=Jimura |first2=Keiko |date=November 2017 |title=Incorporation of ammonium ions in Cs2(HSO4)(H2PO4) confirmed by solid-state NMR |url=https://linkinghub.elsevier.com/retrieve/pii/S0167273817305350 |journal=Solid State Ionics |language=en |volume=311 |pages=83–89 |doi=10.1016/j.ssi.2017.09.015|url-access=subscription }} |
Cs3(HSO4)2(H2PO4)
| |monoclinic |C2/c |a=19.824 b=7.859 c=19.047 β=100.20° Z=4 |1387.2 |3.302 |stable against water solution 298-313K; phase transition at 411K |
Cs4(HSO4)3(H2PO4)
| |monoclinic |C2/c |a=19.945 b=7.8565 c=8.9949 β=100.119° Z=3 |1387.5 |3.301 |colourless |{{Cite journal |last1=Makarova |first1=I. P. |last2=Grebenev |first2=V. V. |last3=Vasil’ev |first3=I. I. |last4=Dmitricheva |first4=E. V. |last5=Komornikov |first5=V. A. |last6=Dolbinina |first6=V. V. |last7=Mikheikin |first7=A. S. |date=January 2016 |title=Structure of Cs4(HSO4)3(H2PO4) single crystals |url=http://link.springer.com/10.1134/S1063774516010119 |journal=Crystallography Reports |language=en |volume=61 |issue=1 |pages=18–23 |doi=10.1134/S1063774516010119 |bibcode=2016CryRp..61...18M |s2cid=101823664 |issn=1063-7745|url-access=subscription }}{{Cite journal |last1=Makarova |first1=Irina |last2=Grebenev |first2=Vadim |last3=Dmitricheva |first3=Elena |last4=Vasiliev |first4=Ilya |last5=Komornikov |first5=Vladimir |last6=Dolbinina |first6=Valentina |last7=Mikheykin |first7=Alexey |date=2016-02-01 |title=M m H n ( X O 4 ) ( m + n )/2 crystals: structure, phase transitions, hydrogen bonds, conductivity. II. Structure and properties of Cs 3 (HSO 4 ) 2 (H 2 PO 4 ) and Cs 4 (HSO 4 ) 3 (H 2 PO 4 ) single crystals |url=http://scripts.iucr.org/cgi-bin/paper?S2052520615023069 |journal=Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials |volume=72 |issue=1 |pages=133–141 |doi=10.1107/S2052520615023069 |pmid=26830805 |issn=2052-5206|url-access=subscription }} |
Cs5(HSO4)2(H2PO4)3
| |cubic |I{{overbar|4}}3d |a=14.5668 | | |over 381K goes to tetragonal a=4.965 c=5.016 |
Cs6H(HSO4)3(H2PO4)4
| |cubic |I{{overbar|4}}3d |a=14.4758 |3033.38 |3.236 |colourless |
Cs5(HSO4)3(H2PO4)2
| |monoclinic |C2/c |a=34.07 Å,b=7.661,c=9.158,β=90.44° |2390 |3.198 | |
18-crown[6]·Cs[H2PO4]0.5[HSO4]0.5·3H2O
| |monoclinic |C2/c |a=19.840 b=8.460 c=26.19 β=101.14 Z=8 |4313 |1.689 |dehydrate at 70° |
CsNH4(HSO4)(H2PO4)
| | | | | | | |
Cs3NH4(HSO4)3(H2PO4)
| | | | | | | |
Cs2MgTi(SO4)(PO4)2
| | | | | | | |
Ba4(PO4)2SO4
| | | | | | | |
NaBa6Zr(PO4)5SO4
| |cubic |I{{overbar|4}}3d |a = 10.5449 Z=4 |1172.54 | |eulytite mineral structure |
Ba2Sr2(PO4)2SO4
| | | | | | | |
Ba3Sr(PO4)2SO4
| | | | | | | |
Ce2O(HPO4)2(SO4). 4H2O
| | | | | | |CeIV |
Ce2O(HPO4)2.4(SO4)0.6. 2H2O
| | | | | | |CeIII |
[enH2]0.5[CeIII(PO4)(HSO4)(OH2)]
| |monoclinic |P21/a |a=12.999 b=7.150 c=9.212 β=95.33 | | |cream colour |
KSr2Eu(PO4)2SO4
| | | | | | | |
RbSr2Eu(PO4)2SO4
| | | | | | | |
CsSr2Eu(PO4)2SO4
| | | | | | | |
[enH2]0.5[Ho(HPO4)(SO4)(H2O)]
| |monoclinic |P21/a |a = 12.938 b = 6.834 c = 9.100 β = 88.12° | | | |
Pb2Mg2(PO4)2SO4
| | | | | | | |
MgPb3(PO4)2(SO4)
| |cubic |I{{overbar|4}}3d |a = 10.299 Z=4 |1092.4 |5.67 | |
CaPb3(PO4)2(SO4)
| |cubic |I{{overbar|4}}3d |a = 10.296 Z=4 |1091.5 |5.77 | |
MnPb3(PO4)2(SO4)
| |cubic |I{{overbar|4}}3d |a = 10.258 Z=4 |1079.4 |5.92 | |
CoPb3(PO4)2(SO4)
| |cubic |I{{overbar|4}}3d |a = 10.356 Z=4 |1110.6 |5.78 | |
NiPb3(PO4)2(SO4)
| |cubic |I{{overbar|4}}3d |a = 10.434 Z=4 |1135.9 |5.65 | |
CuPb3(PO4)2(SO4)
| |cubic |I{{overbar|4}}3d |a = 10.422 Z=4 |1132.0 |5.70 | |
ZnPb3(PO4)2(SO4)
| |cubic |I{{overbar|4}}3d |a = 10.449 Z=4 |1140.8 |5.67 | |
CdPb3(PO4)2(SO4)
| |cubic |I{{overbar|4}}3d |a = 10.315 Z=4 |1097.5 |6.17 | |
SrPb3(PO4)2(SO4)
| |cubic |I{{overbar|4}}3d |a = 10.369 Z=4 |1114.8 |5.93 | |
Th2(PO4)2SO4·2 H2O
| | | | | | |decompose 450 °C |
Organic derivatives
A catenated sulfophosphate has the sulfur and phosphorus joined by an oxygen atom. In biochemistry, metabolism of sulfate may use such a group, for example with adenosine-5'-phosphosulfate.{{Cite web |last=PubChem |title=Adenosine-5'-phosphosulfate |url=https://pubchem.ncbi.nlm.nih.gov/compound/10238 |access-date=2022-07-14 |website=pubchem.ncbi.nlm.nih.gov |language=en}}