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Phosphate sulfate

{{Short description|Compound with phosphate and sulfate ions}}

The phosphate sulfates are mixed anion compounds containing both phosphate and sulfate ions.

Related compounds include the arsenate sulfates, phosphate selenates, and arsenate selenates.

Some hydrogen phosphate sulfates are superprotonic conductors.

List

class="wikitable"

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!chem

!mw

!crystal system

! space group

!unit cell

!volume

!density

!comment

!references

Sanjuanite

|Al2(PO4)(SO4)(OH)·9H2O

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|{{cite journal |last1=Frost |first1=Ray L. |last2=Palmer |first2=Sara J. |title=A vibrational spectroscopic study of the mixed anion mineral sanjuanite Al2(PO4)(SO4)(OH)·9H2O |journal=Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy |date=September 2011 |volume=79 |issue=5 |pages=1210–1214 |doi=10.1016/j.saa.2011.04.044|pmid=21646042 |bibcode=2011AcSpA..79.1210F |url=https://eprints.qut.edu.au/42534/1/42534.pdf }}

Hotsonite

|Al11(SO4)3(PO4)2(OH)21 · 16H2O

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|triclinic

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|a=11.23, b=11.66 c=10.55 α=112° 32′, β=107° 32′ γ=64° 27′

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|refract: α = 1.519 γ = 1.521

|{{Cite journal |last1=Beukes |first1=Gerhard J. |last2=Schoch |first2=Aylva E. |last3=Van der Westhuizen |first3=Willem A. |last4=Bok |first4=Louis D. C. |last5=Bruiyn |first5=Hendrik |date=1984-10-01 |title=Hotsonite, a new hydrated aluminum-phosphate-sulphate from Pofadder, South Africa |url=https://pubs.geoscienceworld.org/msa/ammin/article-abstract/69/9-10/979/41646/Hotsonite-a-new-hydrated-aluminum-phosphate |journal=American Mineralogist |volume=69 |issue=9–10 |pages=979–983 |issn=0003-004X}}

Arangasite

|Al2F(PO4)(SO4)·9H2O

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|monoclinic

|P2/a

|a = 7.073, b = 9.634, c = 10.827, β = 100.40°, Z = 2

|725.7

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|{{Cite journal |last1=Yakubovich |first1=O. V. |last2=Steele |first2=I. M. |last3=Chernyshev |first3=V. V. |last4=Zayakina |first4=N. V. |last5=Gamyanin |first5=G. N. |last6=Karimova |first6=O. V. |date=August 2014 |title=The crystal structure of arangasite, Al 2 F(PO 4 )(SO 4 )·9H 2 O determined using low-temperature synchrotron data |url=https://www.cambridge.org/core/product/identifier/S0026461X00003571/type/journal_article |journal=Mineralogical Magazine |language=en |volume=78 |issue=4 |pages=889–903 |doi=10.1180/minmag.2014.078.4.09 |bibcode=2014MinM...78..889Y |s2cid=94078023 |issn=0026-461X|url-access=subscription }}

peisleyite

|Na3Al16(SO4)2(PO4)10(OH)17 · 20H2O

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|monoclinic

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|a 13.31, b 12.62, c 23.15, β 110.0°, Z = 2

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|discredited

|{{Cite journal |last1=Pilkington |first1=E. S. |last2=Segnit |first2=E. R. |last3=Watts |first3=J. A. |date=December 1982 |title=Peisleyite, a new sodium aluminium sulphate phosphate |url=https://www.cambridge.org/core/product/identifier/S0026461X00053275/type/journal_article |journal=Mineralogical Magazine |language=en |volume=46 |issue=341 |pages=449–452 |doi=10.1180/minmag.1982.046.341.07 |bibcode=1982MinM...46..449P |s2cid=129726668 |issn=0026-461X|url-access=subscription }}

peisleyite

|Na2Al9[(P,S)O4]8(OH)6·28H2O

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|triclinic

|P{{overbar|1}}

|a = 9.28, b = 11.98, c = 13.25, α = 91.3, β = 75.6, γ = 67.67°, Z = 4

|1308

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|{{Cite journal |last1=Mills |first1=S. J. |last2=Ma |first2=C. |last3=Birch |first3=W. D. |date=December 2011 |title=A contribution to understanding the complex nature of peisleyite |url=https://www.cambridge.org/core/product/identifier/S0026461X00008276/type/journal_article |journal=Mineralogical Magazine |language=en |volume=75 |issue=6 |pages=2733–2737 |doi=10.1180/minmag.2011.075.6.2733 |bibcode=2011MinM...75.2733M |s2cid=18661193 |issn=0026-461X}}

Woodhouseite

|CaAl3(PO4)(SO4)(OH)6

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|trigonal

|R{{overbar|3}}m

|a = 6.993, c = 16.386

|693.95

|3.0

|Uniaxial (+) nω = 1.636 nε = 1.647 Birefringence: δ = 0.011

|{{Cite web |title=Woodhouseite |url=https://www.mindat.org/min-4311.html |access-date=2022-05-25 |website=www.mindat.org}}

Ardéalite

|Ca2H(PO4)(SO4)•4H2O

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|monoclinic

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|a = 5.721, b = 30.95, c = 6.265, β= 117.26° Z = 4

|986.11

|2.32

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|{{Cite journal |last1=BALENZANO |first1=F |last2=DELL'ANNA |first2=L. |last3=DI PIERRO |first3=M. |last4=FIORE |first4=S. |date=1982 |title=Ardealite, Ca2H(PO4) (SO4).4H2O, un rarissimo fosfato-solfato idrato di calcio: risultati mineralogici preliminari |url=https://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=9403475 |journal=Ardealite, Ca2H(PO4) (SO4).4H2O, Un Rarissimo Fosfato-solfato Idrato di Calcio: Risultati Mineralogici Preliminari |volume=38 |issue=2 |pages=899–900 |issn=0037-8828}}

Destinezite Diadochite

|Fe2(PO4)(SO4)(OH)•6H2O

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|triclinic

|P{{overbar|1}}

|a = 9.570, b = 9.716, c = 7.313, α = 98.74°, β = 107.90°, γ = 63.86° Z = 2

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|{{Cite journal |last=Peacor |first=Donald R. |date=1999 |title=Destinezite ("Diadochite"), Fe2(PO4)(SO4)(OH)·6H2O: Its Crystal Structure and Role as a Soil Mineral at Alum Cave Bluff, Tennessee† |journal=Clays and Clay Minerals |volume=47 |issue=1 |pages=1–11 |doi=10.1346/CCMN.1999.0470101 |bibcode=1999CCM....47....1P |s2cid=98406559 |issn=0009-8604|doi-access=free }}

bohuslavite

|FeIII4(PO4)3(SO4)(OH)(H2O)10·nH2O (5 ≤ n ≤ 14)

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|triclinic

|P{{overbar|1}}

|a = 13.376 b = 13.338 c = 10.863 α = 92.80, β = 91.03, γ = 119.92°, Z = 2

|1675.7

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|pink

|{{Cite journal |last1=Mauro |first1=Daniela |last2=Biagioni |first2=Cristian |last3=Bonaccorsi |first3=Elena |last4=Hålenius |first4=Ulf |last5=Pasero |first5=Marco |last6=Skogby |first6=Henrik |last7=Zaccarini |first7=Federica |last8=Sejkora |first8=Jiří |last9=Plášil |first9=Jakub |last10=Kampf |first10=Anthony R. |last11=Filip |first11=Jan |date=2019-12-20 |title=Bohuslavite, Fe 4 3 + (PO4)3(SO4)(OH)(H2O)10·nH2O, a new hydrated iron phosphate-sulfate |url=http://www.schweizerbart.de/papers/ejm/detail/31/92461/Bohuslavite_Fe_4_3_PO4_3_SO4_OH_H2O_10_nH2O_a_new_?af=crossref |journal=European Journal of Mineralogy |language=en |volume=31 |issue=5–6 |pages=1033–1046 |doi=10.1127/ejm/2019/0031-2892 |bibcode=2019EJMin..31.1033M |s2cid=213555293 |issn=0935-1221|url-access=subscription }}

Borickyite

|(Ca,Mg)(Fe3+,Al)4(PO4,SO4,CO3)(OH)8·3–7.5H2O

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|{{Cite journal |last1=Frost |first1=Ray L. |last2=Palmer |first2=Sara J. |last3=Xi |first3=Yunfei |date=June 2012 |title=Is the mineral borickyite (Ca,Mg)(Fe3+,Al)4(PO4,SO4,CO3)(OH)8·3–7.5H2O the same as delvauxite CaFe43+(PO4,SO4)2(OH)8·4–6H2O? |url=https://linkinghub.elsevier.com/retrieve/pii/S1386142512002193 |journal=Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy |language=en |volume=92 |pages=377–381 |doi=10.1016/j.saa.2012.02.102|pmid=22446787 |bibcode=2012AcSpA..92..377F }}

Camaronesite

|[Fe3+(H2O)2(PO3OH)]2(SO4)·1–2H2O

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|trigonal

|R32

|a = 9.0833, c = 42.944, Z = 9

|3068.5

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|{{Cite journal |last1=Kampf |first1=A. R. |last2=Mills |first2=S. J. |last3=Nash |first3=B. P. |last4=Housley |first4=R. M. |last5=Rossman |first5=G. R. |last6=Dini |first6=M. |date=June 2013 |title=Camaronesite, [Fe 3+ (H 2 O) 2 (PO 3 OH)] 2 (SO 4 )·1–2H 2 O, a new phosphate-sulfate from the Camarones Valley, Chile, structurally related to taranakite |url=https://www.cambridge.org/core/product/identifier/S0026461X00008483/type/journal_article |journal=Mineralogical Magazine |language=en |volume=77 |issue=4 |pages=453–465 |doi=10.1180/minmag.2013.077.4.05 |bibcode=2013MinM...77..453K |s2cid=129777006 |issn=0026-461X}}

|Fe3+4(PO4)3(SO4)(OH)·18H2O

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|triclinic

|P{{overbar|1}}

|a=13.376, b 13.338, c 10.863, α 92.80, β 91.03, γ 119.92°

|1675.7

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|{{Cite journal |last1=Mauro |first1=D. |last2=Biagioni |first2=C. |last3=Bonaccorsi |first3=E. |last4=Pasero |first4=M. |last5=Skogby |first5=H. |last6=Zaccarini |first6=F. |date=2018 |title=A new iron (III) phosphate-sulfate from Apuan Alps (Tuscany, Italy): a difficult puzzle solved through a multi-technique approach |journal=Congresso Sgi-Simp 2018 |pages=521}}

vanderheydenite

|Zn6(PO4)2(SO4)(OH)4·7H2O

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|monoclinic

|P21/n

|a = 6.204 b = 19.619, c = 7.782, β = 90.67°

|947.1

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|biaxial (–) α = 1.565, β = 1.580 γ = 1.582. 2V = 39.8°

|{{Cite journal |last1=Elliott |first1=Peter |last2=Kolitsch |first2=Uwe |date=2018-10-31 |title=Description and crystal structure of vanderheydenite, Zn6(PO4)2(SO4)(OH)4·7H2O, a new mineral from Broken Hill, New South Wales, Australia |url=http://www.schweizerbart.de/papers/ejm/detail/30/89851/Description_and_crystal_structure_of_vanderheydeni?af=crossref |journal=European Journal of Mineralogy |language=en |volume=30 |issue=4 |pages=835–840 |doi=10.1127/ejm/2018/0030-2750 |bibcode=2018EJMin..30..835E |s2cid=134655965 |issn=0935-1221|url-access=subscription }}

Svanbergite

|SrAl3(PO4)(SO4)(OH)6

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|trigonal

|R{{overbar|3}}m

|a = 6.97, c = 16.59 Z=3

|697.98

|3.2

|Uniaxial (+) nω = 1.631 - 1.635 nε = 1.646 - 1.649 Birefringence: δ = 0.015

|{{Cite web |title=Svanbergite |url=https://www.mindat.org/min-3837.html |access-date=2022-05-25 |website=www.mindat.org}}

Birchite

|Cd2Cu2(PO4)2(SO4) ·5H2O

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|a = 10.489 b = 20.901 c = 6.155 Z=4

|1349.6

|3.647

|biaxial positive,

nα = 1.624, nβ = 1.636, nγ = 1.669, 2Vcalc = +63°.

|{{Cite journal |last1=Elliott |first1=P. |last2=Brugger |first2=J. |last3=Pring |first3=A. |last4=Cole |first4=M. L. |last5=Willis |first5=A. C. |last6=Kolitsch |first6=U. |date=2008-05-01 |title=Birchite, a new mineral from Broken Hill, New South Wales, Australia: Description and structure refinement |url=https://www.degruyter.com/document/doi/10.2138/am.2008.2732/html |journal=American Mineralogist |language=en |volume=93 |issue=5–6 |pages=910–917 |doi=10.2138/am.2008.2732 |bibcode=2008AmMin..93..910E |s2cid=95773593 |issn=0003-004X|url-access=subscription }}

Corkite

|PbFe3(OH)6SO4PO4

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|trigonal

|R{{overbar|3}}m

|a = 7.32, c = 17.02 Z=3

|781.2

|4.295

|Uniaxial (-) nω = 1.930 nε = 1.930 n = 1.93 - 1.96 Birefringence 0.03

|{{Cite web |title=Corkite|url=https://www.mindat.org/min-1130.html |access-date=2022-05-25 |website=www.mindat.org}}

|BaAl3(PO4)(SO4)(OH)6

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|trigonal

|R{{overbar|3}}m

|a = , c = Z=3

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|{{Cite journal |last1=Izbrodin |first1=Ivan A. |last2=Ripp |first2=German S. |last3=Doroshkevich |first3=Anna G. |date=January 2011 |title=Aluminium phosphate and phosphate-sulphate minerals in kyanite schists of the Ichetuyskoye area, West Transbaikalia, Russia: crystal chemistry and evolution |url=http://link.springer.com/10.1007/s00710-010-0135-5 |journal=Mineralogy and Petrology |language=en |volume=101 |issue=1–2 |pages=81–96 |doi=10.1007/s00710-010-0135-5 |bibcode=2011MinPe.101...81I |s2cid=129698260 |issn=0930-0708|url-access=subscription }}

hinsdalite

|(Pb,Sr)Al3(PO4)(SO4)(OH)6

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|{{Cite journal |last1=Frost |first1=Ray L. |last2=Palmer |first2=Sara J. |last3=Xi |first3=Yunfei |date=August 2011 |title=A vibrational spectroscopic study of the mineral hinsdalite (Pb,Sr)Al3(PO4)(SO4)(OH)6 |url=https://linkinghub.elsevier.com/retrieve/pii/S0022286011004777 |journal=Journal of Molecular Structure |language=en |volume=1001 |issue=1–3 |pages=43–48 |doi=10.1016/j.molstruc.2011.06.014|bibcode=2011JMoSt1001...43F }}

Tsumebite

|Pb2Cu(PO4,SO4)(OH)

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|{{Cite journal |last1=Frost |first1=Ray L. |last2=Palmer |first2=Sara J. |date=September 2011 |title=Vibrational spectroscopic study of the mineral tsumebite Pb2Cu(PO4,SO4)(OH) |url=https://linkinghub.elsevier.com/retrieve/pii/S1386142511004112 |journal=Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy |language=en |volume=79 |issue=5 |pages=1794–1797 |doi=10.1016/j.saa.2011.05.058|pmid=21680232 |bibcode=2011AcSpA..79.1794F }}

Delvauxite

|CaFe43+(PO4,SO4)2(OH)8·4–6H2O

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|{{Cite journal |last1=Frost |first1=Ray L. |last2=Palmer |first2=Sara J. |date=April 2011 |title=A Raman and infrared spectroscopic study of the mineral delvauxite CaFe43+(PO4,SO4)2(OH)8·4–6H2O—A 'colloidal' mineral |url=https://linkinghub.elsevier.com/retrieve/pii/S1386142510006517 |journal=Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy |language=en |volume=78 |issue=4 |pages=1250–1254 |doi=10.1016/j.saa.2010.12.039|pmid=21277823 |bibcode=2011AcSpA..78.1250F }}

Rossiantonite

|Al3(PO4)(SO4)2(OH)2(H2O)10·4H2O

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|triclinic

|P{{overbar|1

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|a = 10.3410, b = 10.9600, c = 11.1446, α = 86.985, β = 65.727, γ = 75.064°, Z = 2

|1110.5

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|{{Cite journal |last1=Galli |first1=E. |last2=Brigatti |first2=M. F. |last3=Malferrari |first3=D. |last4=Sauro |first4=F. |last5=De Waele |first5=J. |date=2013-10-01 |title=Rossiantonite, Al3(PO4)(SO4)2(OH)2(H2O)10{middle dot}4H2O, a new hydrated aluminum phosphate-sulfate mineral from Chimanta massif, Venezuela: Description and crystal structure |url=https://www.degruyter.com/document/doi/10.2138/am.2013.4393/html |journal=American Mineralogist |language=en |volume=98 |issue=10 |pages=1906–1913 |doi=10.2138/am.2013.4393 |hdl=11585/185099 |s2cid=102265894 |issn=0003-004X|url-access=subscription }}

Schlossmacherite

|(H3O,Ca)Al3(AsO4,PO4,SO4)2(OH)6

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|{{Cite journal |last1=Frost |first1=Ray L. |last2=Palmer |first2=Sara J. |last3=Xi |first3=Yunfei |date=February 2012 |title=Raman spectroscopy of the multi-anion mineral schlossmacherite (H3O,Ca)Al3(AsO4,PO4,SO4)2(OH)6 |url=https://linkinghub.elsevier.com/retrieve/pii/S1386142511010353 |journal=Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy |language=en |volume=87 |pages=209–213 |doi=10.1016/j.saa.2011.11.040|pmid=22169025 |bibcode=2012AcSpA..87..209F }}

Arthurite

|Cu(Fe3+)2(AsO4,PO4,SO4)2(O,OH)2·4(H2O)

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|{{Cite journal |last1=Palmer |first1=Sara J. |last2=Frost |first2=Ray L. |date=May 2011 |title=The structure of the mineral arthurite (AsO4,PO4,SO4)2(O,OH)2·4H2O – A Raman spectroscopic study |url=https://linkinghub.elsevier.com/retrieve/pii/S0022286011002523 |journal=Journal of Molecular Structure |language=en |volume=994 |issue=1–3 |pages=283–288 |doi=10.1016/j.molstruc.2011.03.034|url-access=subscription }}

cobaltarthurite

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Phosphoinnelite

|Ba4Na3Ti3Si4O14(PO4,SO4)2(O,F)3

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|triclinic

|P{{overbar|1}}?

|a = 5.38, b = 7.10, c = 14.76; α = 99.00°, β = 94.94°, γ = 90.14° Z = 1

|555

|3.82

|biaxial (+), α = 1.730, β = 1.745, and γ = 1.764, 2V 90°

|{{Cite journal |last1=Pekov |first1=I. V. |last2=Chukanov |first2=N. V. |last3=Kulikova |first3=I. M. |last4=Belakovsky |first4=D. I. |date=December 2007 |title=Phosphoinnelite, Ba4Na3Ti3Si4O14(PO4,SO4)2(O,F)3, a new mineral species from peralkaline pegmatite of the Kovdor pluton, Kola Peninsula |url=http://link.springer.com/10.1134/S1075701507070070 |journal=Geology of Ore Deposits |language=en |volume=49 |issue=7 |pages=530–536 |doi=10.1134/S1075701507070070 |bibcode=2007GeoOD..49..530P |s2cid=129616074 |issn=1075-7015|url-access=subscription }}

Francolite

|(Ca, Mg, Sr, Na)10(PO4, SO4, CO3)6F2–3

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|{{Cite journal |last1=Benmore |first1=Richard A. |last2=Coleman |first2=Max L. |last3=McArthur |first3=John M. |date=April 1983 |title=Origin of sedimentary francolite from its sulphur and carbon isotope composition |url=http://www.nature.com/articles/302516a0 |journal=Nature |language=en |volume=302 |issue=5908 |pages=516–518 |doi=10.1038/302516a0 |bibcode=1983Natur.302..516B |s2cid=4350036 |issn=0028-0836|url-access=subscription }}

|Al4(UO2)2(PO4)4(SO4)(OH)2 · 18H2O

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|{{Cite journal |last1=Frost |first1=Ray L. |last2=Palmer |first2=Sara J |last3=Čejka |first3=Jiří |date=September 2011 |title=The Application of Raman Spectroscopy to the Study of the Uranyl Mineral Coconinoite Fe 2 Al 2 (UO 2 ) 2 (PO 4 ) 4 (SO 4 )(OH) 2 · 20H 2 O |url=http://www.tandfonline.com/doi/abs/10.1080/00387010.2010.551445 |journal=Spectroscopy Letters |language=en |volume=44 |issue=6 |pages=381–387 |doi=10.1080/00387010.2010.551445 |bibcode=2011SpecL..44..381F |s2cid=96609983 |issn=0038-7010}}

|Al4(UO2)2(PO4)4(SO4)(OH)2 · 20H2O

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Coconinoite

|Fe2Al2(UO2)2(PO4)4(SO4)(OH)2 · 20H2O

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|monoclinic

|C2/c

|a =12.45, b = 12.96, c = 17.22, β = 105.7°

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xiangjiangite

|Fe2Al2(UO2)2(PO4)4(SO4)(OH)2 · 22H2O

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|tetragonal

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|a = 7.17 Å, b = 7.17 Å, c = 22.22 Å Z=1

|1,142

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|Biaxial (-) nα = 1.558 nβ = 1.576 nγ = 1.593 2V: 87°

|{{Cite web |title=Xiangjiangite |url=https://www.mindat.org/min-4334.html |access-date=2022-07-13 |website=www.mindat.org}}

Artificial

class="wikitable"

!chem

!mw

!crystal system

! space group

!unit cell Å

!volume

!density

!comment

!references

[H4N+]2·HSO4−·H2PO4−

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|{{Cite journal |last1=BEKTUROV |first1=AB |last2=NA |first2=DZHUMAGULOVA |last3=ZK |first3=KAIPOVA |last4=RS |first4=ERZHANOVA |last5=VI |first5=LITVINENKO |date=1980 |title=RECHERCHES DANS LE DOMAINE DES SULFATOPHOSPHATES. 5. TRANSFORMATIONS THERMIQUES DES MELANGES DE PHOSPHATE ET DE SULFATE D'AMMONIUM MONOSUBSTITUES ET D'HYDROSULFATE-DIHYDRO-PHOSPHATE D'AMMONIUM (NH4)2(HSO4.H2PO4) |url=https://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=PASCAL8130086444 |journal=Recherches dans le Domaine des Sulfatophosphates. 5. Transformations Thermiques des Melanges de Phosphate et de Sulfate d'Ammonium Monosubstitues et d'Hydrosulfate-Dihydro-Phosphate d'Ammonium (Nh4)2(Hso4.H2Po4)}}{{Cite web |last=PubChem |title=Diammonium phosphate sulphate |url=https://pubchem.ncbi.nlm.nih.gov/compound/15607556 |access-date=2022-07-13 |website=pubchem.ncbi.nlm.nih.gov |language=en}}

NH4(HSO4)0.45(H2PO4)0.55

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|orthorhombic

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|{{Cite journal |last1=Bouattour |first1=S. |last2=Mhiri |first2=T. |last3=Kolsi |first3=A. W. |last4=Romain |first4=F. |date=October 1999 |title=Dielectric, dsc and raman studies of the phase transitions in NH 4 (HSO 4 ) 0.45 (H 2 PO 4 ) 0.55 mixed crystals |url=http://www.tandfonline.com/doi/abs/10.1080/01411599908241337 |journal=Phase Transitions |language=en |volume=70 |issue=1 |pages=19–28 |doi=10.1080/01411599908241337 |bibcode=1999PhaTr..70...19B |issn=0141-1594|url-access=subscription }}

18-crown[6]·[NH4][H2PO4]0.5[HSO4]0.5·H2O

|

|orthrhombic

|F2dd

|a=8.710 b= 28.868 c=31.206 Z=16

|7846

|1.346

|dehydrate at 70°

|{{Cite journal |last1=Braga |first1=Dario |last2=Modena |first2=Enrico |last3=Polito |first3=Marco |last4=Rubini |first4=Katia |last5=Grepioni |first5=Fabrizia |date=2008 |title=Crystal forms of highly "dynamic" 18-crown[6] complexes with M[HSO4] and M[H2PO4] (M+ = NH4+, Rb+, Cs+): thermal behaviour and solid-state preparation |url=http://xlink.rsc.org/?DOI=b805203d |journal=New Journal of Chemistry |language=en |volume=32 |issue=10 |pages=1718 |doi=10.1039/b805203d |issn=1144-0546|url-access=subscription }}

[(C2H5)4N+]2·HSO4−·H2PO4−

|

|Monoclinic

|C2/c

|a = 28.0787 b = 11.8671 c = 14.1533 β = 100.739° Z=8

|4633.46

|1.303

|colourless; decompose at 353K

|{{Cite journal |last1=Fábry |first1=Jan |last2=Krupková |first2=Radmila |last3=Císařová |first3=Ivana |last4=Jurek |first4=Karel |date=2003-03-15 |title=Bis(tetraethylammonium) hydrogensulfate dihydrogenphosphate at 292 and 150 K |url=http://scripts.iucr.org/cgi-bin/paper?S0108270103001471 |journal=Acta Crystallographica Section C: Crystal Structure Communications |volume=59 |issue=3 |pages=o120–o123 |doi=10.1107/S0108270103001471 |pmid=12711782 |bibcode=2003AcCrC..59O.120F |issn=0108-2701|url-access=subscription }}

(NH2CH2COOH)3(H2SO4)0.7(H3PO4)0.3

|

|monoclinic

|

|

|

|

|called TGSP; colourless; ferroelectric, curie point 51 °C; pyroelectric

|

Na(HSO4)(H3PO4)

|

|monoclinic

|P 21

|a = 5.449, b = 6.832, c = 8.718, β = 95.88°, Z = 2

| 322.8

|

|

|{{Cite journal |title= Synthese und Kristallstruktur von K2(HSO4)(H2PO4), K4(HSO4)3(H2PO4) und Na(HSO4)(H3PO4)|journal= Zeitschrift für Anorganische und Allgemeine Chemie|year= 2000|doi=10.1002/1521-3749(200009)626:9<2004::AID-ZAAC2004>3.0.CO;2-0|last1= Stiewe|first1= A.|last2= Kemnitz|first2= E.|volume= 626|issue= 9|pages= 2004–2011}}

K2(HSO4)(H2PO4)

|

|monoclinic

|P 21/c

|a = 11.150, b = 7.371, c = 9.436, β = 92.29°, Z = 4

| 774.9

|

|

|

K4(HSO4)3(H2PO4)

|

|triclinic

|P 1

|a = 7.217, b = 7.521, c = 7.574, α = 71.52°, β = 88.28°, γ = 86.20°, Z = 1

| 389.1

|

|

|

K4(PO2F2)2(S2O7)

|534.46

|monoclinic

|C2/c

|a = 13.00, b = 7.543, c = 19.01, β = 130.07°, Z = 4

|1426.5

|2.489

|colourless; pyrosulfate + difluorophosphate

|{{Cite journal |last1=Zhang |first1=Wenyao |last2=Jin |first2=Wenqi |last3=Yang |first3=Zhihua |last4=Pan |first4=Shilie |date=2020 |title=K 4 (PO 2 F 2 ) 2 (S 2 O 7 ): first fluorooxophosphorsulfate with mixed-anion [S 2 O 7 ] 2− and [PO 2 F 2 ] − groups |url=http://xlink.rsc.org/?DOI=D0DT03307C |journal=Dalton Transactions |language=en |volume=49 |issue=48 |pages=17658–17664 |doi=10.1039/D0DT03307C |pmid=33231582 |s2cid=227157666 |issn=1477-9226|url-access=subscription }}

K3[O3SOPO2OSO3]

|

|

|

|

|

|

|

|{{Cite journal |last=von Lampe |first=F. |date=June 1969 |title=Darstellung eines kristallinen Sulfatophosphats, des Kalium-di-sulfato-monophosphats K3[O3SO?PO2?OSO3] |url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.19693670309 |journal=Zeitschrift für anorganische und allgemeine Chemie |language=de |volume=367 |issue=3–4 |pages=170–188 |doi=10.1002/zaac.19693670309 |issn=0044-2313|url-access=subscription }}

H1−xTi2(PO4)3−x(SO4)x (x=0.5–1)

|

|

|

|

|

|

|

|{{Cite journal |last1=Mieritz |first1=Daniel |last2=Davidowski |first2=Stephen K. |last3=Seo |first3=Dong-Kyun |date=October 2016 |title=Accessing alkali-free NASICON-type compounds through mixed oxoanion sol–gel chemistry: Hydrogen titanium phosphate sulfate, H1−Ti2(PO4)3−(SO4) (x=0.5–1) |journal=Journal of Solid State Chemistry |language=en |volume=242 |pages=116–125 |doi=10.1016/j.jssc.2016.02.007|bibcode=2016JSSCh.242..116M |doi-access=free }}

Na2MgTi(SO4)(PO4)2

|

|trigonal

|R{{overbar|3}}c

|a=8.4796 c=21.8091 Z=6

|1358.1

|2.818

|

|{{Cite journal |last1=Kanunov |first1=A. E. |last2=Asabina |first2=E. A. |last3=Orlova |first3=A. I. |date=January 2016 |title=Preparation and X-ray diffraction study of phosphate sulfates M2MgTi(SO4)(PO4)2 |url=http://link.springer.com/10.1134/S1070363216010047 |journal=Russian Journal of General Chemistry |language=en |volume=86 |issue=1 |pages=18–25 |doi=10.1134/S1070363216010047 |s2cid=102011872 |issn=1070-3632|url-access=subscription }}

K2MgTi(SO4)(PO4)2

|

|cubic

|P213

|a=9.8743 Z=4

|962.84

|2.872

|

|

Ca10-xNax(PO4)6-x(SO4)xF2

|

|monoclinic

|

|

|

|

|

|{{Cite journal |last1=Apella |first1=M. C. |last2=Baran |first2=E. J. |date=1981-05-01 |title=Zur Kristallstruktur der gemischten Phosphat/Sulfat-Fluorapatite / On the Crystal Structure of Mixed Phosphate/Sulfate Fluoroapatites |journal=Zeitschrift für Naturforschung B |language=en |volume=36 |issue=5 |pages=644–645 |doi=10.1515/znb-1981-0517 |s2cid=97118097 |issn=1865-7117|doi-access=free }}

NaFe2(PO4)(SO4)2

|

|hexagonal

|R{{overbar|3}}c

|a=8.4243 c=21.973

|

|

|

|{{Cite journal |last1=Ben Yahia |first1=Hamdi |last2=Essehli |first2=Rachid |last3=Amin |first3=Ruhul |last4=Boulahya |first4=Khalid |last5=Okumura |first5=Toyoki |last6=Belharouak |first6=Ilias |date=2018-04-01 |title=Sodium intercalation in the phosphosulfate cathode NaFe2(PO4)(SO4)2 |url=https://www.sciencedirect.com/science/article/pii/S0378775318301290 |journal=Journal of Power Sources |language=en |volume=382 |pages=144–151 |doi=10.1016/j.jpowsour.2018.02.021 |bibcode=2018JPS...382..144B |osti=1495971 |issn=0378-7753|url-access=subscription }}

NaFe1.4V0.6(PO4)(SO4)2

|

|

|

|

|

|

|

|{{Cite journal |last1=Essehli |first1=Rachid |last2=Alkhateeb |first2=Alaa |last3=Mahmoud |first3=Abdelfattah |last4=Boschini |first4=Frèdéric |last5=Ben Yahia |first5=Hamdi |last6=Amin |first6=Ruhul |last7=Belharouak |first7=Ilias |date=September 2020 |title=Optimization of the compositions of polyanionic sodium-ion battery cathode NaFe2−xVx(PO4)(SO4)2 |journal=Journal of Power Sources |language=en |volume=469 |pages=228417 |doi=10.1016/j.jpowsour.2020.228417|bibcode=2020JPS...46928417E |osti=1633153 |s2cid=225331939 |doi-access=free }}

[Ni(C14H10N4)3]4(PO4)2(SO4) (C14H10N4=2,2'-bi-1H-benzimidazole)

|3331.96

|cubic

|I{{overbar|4}}3d

|a = 24.964 Z=4

|15558

|1.423

|green

|{{Cite journal |last1=Ling |first1=Chun-Sheng |last2=Yan |first2=Lin |date=2008-11-15 |title=Tetrakis[tris(2,2′-bi-1 H -benzimidazole)nickel(II)] bis(phosphate) sulfate |url=http://scripts.iucr.org/cgi-bin/paper?S1600536808032571 |journal=Acta Crystallographica Section E: Structure Reports Online |volume=64 |issue=11 |pages=m1399 |doi=10.1107/S1600536808032571 |issn=1600-5368 |pmc=2959627 |pmid=21580849|bibcode=2008AcCrE..64m1399L }}

Rb2(HSO4)(H2PO4)

|

|monoclinic

|P21/n

|a=7.448, b=7.552, c=7.632, β=100.47°, Z=2

|422.1

|

|

|{{Cite journal |last1=Komornikov |first1=V. A. |last2=Grebenev |first2=V. V. |last3=Andreev |first3=P. V. |last4=Dmitricheva |first4=E. V. |date=May 2015 |title=Study of phase equilibria in the Rb3H(SO4)2-RbH2PO4-H2O system |url=http://link.springer.com/10.1134/S1063774515030086 |journal=Crystallography Reports |language=en |volume=60 |issue=3 |pages=431–437 |doi=10.1134/S1063774515030086 |bibcode=2015CryRp..60..431K |s2cid=101238604 |issn=1063-7745|url-access=subscription }}{{Cite journal |last1=Stiewe |first1=A. |last2=Sonntag |first2=R. |last3=Troyanov |first3=S.I. |last4=Hansen |first4=T. |last5=Kemnitz |first5=E. |date=January 2000 |title=Synthesis and Structure Determination of Rb2(HSO4)(H2PO4) and Rb4(HSO4)3(H2PO4) by X-Ray Single Crystal and Neutron Powder Diffraction |url=https://linkinghub.elsevier.com/retrieve/pii/S0022459699984682 |journal=Journal of Solid State Chemistry |language=en |volume=149 |issue=1 |pages=9–15 |doi=10.1006/jssc.1999.8468|bibcode=2000JSSCh.149....9S |url-access=subscription }}

Rb2(HSO4)(H2PO4)

|

|monoclinic

|P21/c

|a=11.555, b=7.536, c=9.593, β=91.56, Z=4

|853.0

|

|at 160K

|

Rb4(HSO4)3(H2PO4)

|

|orthorhombic

|P21212

|a=7.612, b=14.795, c=7.446, Z=2

|838.6

|

|

|

18-crown[6]·Rb[H2PO4]0.5[HSO4]0.5·3H2O

|

|monoclinic

|C2/c

|a=19.802 b=8.447 c=25.777 β=101.00° Z=8

|4232

|1.572

|dehydrate at 70°

|

Rb2MgTi(SO4)(PO4)2

|

|

|

|

|

|

|

|

Sr4(PO4)2SO4

|

|

|

|

|

|

|

|{{Cite journal |last1=Pet’kov |first1=V. I. |last2=Dmitrienko |first2=A. S. |last3=Bokov |first3=A. I. |date=July 2018 |title=Thermal expansion of phosphate–sulfates of eulytite structure |url=http://link.springer.com/10.1007/s10973-017-6676-7 |journal=Journal of Thermal Analysis and Calorimetry |language=en |volume=133 |issue=1 |pages=199–205 |doi=10.1007/s10973-017-6676-7 |s2cid=104200610 |issn=1388-6150|url-access=subscription }}

NaZrMg(PO4)(SO4)2

|

|hexagonal

|R{{overbar|3}}c

|

|

|

|

|{{Cite journal |last1=Savinykh |first1=D. O. |last2=Khainakov |first2=S. A. |last3=Orlova |first3=A. I. |last4=Garcia-Granda |first4=S. |date=June 2018 |title=New Phosphate-Sulfates with NZP Structure |url=http://link.springer.com/10.1134/S0036023618060207 |journal=Russian Journal of Inorganic Chemistry |language=en |volume=63 |issue=6 |pages=714–724 |doi=10.1134/S0036023618060207 |hdl=10651/50903 |s2cid=105627248 |issn=0036-0236|hdl-access=free }}

NaZrCo(PO4)(SO4)2

|

|hexagonal

|R{{overbar|3

}}c

|

|

|

|

|

NaZrNi(PO4)(SO4)2

|

|hexagonal

|R{{overbar|3}}c

|

|

|

|

|

NaZrCu(PO4)(SO4)2

|

|hexagonal

|R{{overbar|3}}c

|

|

|

|

|

NaZrZn(PO4)(SO4)2

|

|hexagonal

|R{{overbar|3}}c

|

|

|

|

|

NaZrAl(PO4)2(SO4)

|

|hexagonal

|R{{overbar|3}}c

|

|

|

|

|

NaZrFe(PO4)2(SO4)

|

|hexagonal

|R{{overbar|3}}c

|

|

|

|

|

H3OSb2(SO4)2(PO4)

|

|triclinic

|P{{overbar|1

}}

|a=5.134 b=7.908 c=12.855, α=81.401° β=87.253° γ=86.49°

|

|

|

|{{Cite journal |last1=Zhao |first1=Xiao |last2=Mei |first2=Dajiang |last3=Xu |first3=Jingli |last4=Wu |first4=Yuandong |date=February 2016 |title=A Sb 2 (SO 4 ) 2 (PO 4 ) ( A = H 3 O + , K, Rb): Layered Structure Containing Ordered Sulfate and Phosphate Anions: A Sb 2 (SO 4 ) 2 (PO 4 ) ( A = H 3 O + , K, Rb |url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.201500743 |journal=Zeitschrift für anorganische und allgemeine Chemie |language=en |volume=642 |issue=4 |pages=343–349 |doi=10.1002/zaac.201500743|url-access=subscription }}

KSb2(SO4)2(PO4)

|

|triclinic

|P{{overbar|1}}

|a=5.1453 =7.9149 c=12.6146, α=82.054° β=87.715° γ=86.655°

|

|

|

|

RbSb2(SO4)2(PO4)

|

|triclinic

|P{{overbar|1}}

|a=5.1531 b=7.957 c=12.845, α=81.801° β=87.676° γ=86.703°

|

|

|

|

Cs2(HSO4)(H2PO4)

|

|cubic

|

|ao=4.926

|

|

|>105 °C but can be supercooled

|{{Cite journal |last=Chisholm |first=C |date=2000-11-02 |title=Superprotonic behavior of Cs2(HSO4)(H2PO4) – a new solid acid in the CsHSO4–CsH2PO4 system |url=https://linkinghub.elsevier.com/retrieve/pii/S0167273800003155 |journal=Solid State Ionics |volume=136-137 |issue=1–2 |pages=229–241 |doi=10.1016/S0167-2738(00)00315-5|url-access=subscription }}

Cs2(HSO4)(H2PO4)

|

|monoclinic

|P21/n

|a = 7.856 b = 7.732 c = 7.827, β= 99.92° Z=2

|468.3

|3.261

|can substitute 2.3% ammonium; proton conductivity at 110 °C is 3×10−3 Ω−1cm−1

|{{Cite journal |last1=Chisholm |first1=Calum R. I. |last2=Haile |first2=Sossina M. |date=1999-12-01 |title=Structure and thermal behavior of the new superprotonic conductor Cs 2 (HSO 4 )(H 2 PO 4 ) |url=http://scripts.iucr.org/cgi-bin/paper?S0108768199009921 |journal=Acta Crystallographica Section B: Structural Science |volume=55 |issue=6 |pages=937–946 |doi=10.1107/S0108768199009921 |pmid=10927436 |bibcode=1999AcCrB..55..937C |issn=0108-7681}}{{Cite journal |last1=Hayashi |first1=Shigenobu |last2=Jimura |first2=Keiko |date=November 2017 |title=Incorporation of ammonium ions in Cs2(HSO4)(H2PO4) confirmed by solid-state NMR |url=https://linkinghub.elsevier.com/retrieve/pii/S0167273817305350 |journal=Solid State Ionics |language=en |volume=311 |pages=83–89 |doi=10.1016/j.ssi.2017.09.015|url-access=subscription }}

Cs3(HSO4)2(H2PO4)

|

|monoclinic

|C2/c

|a=19.824 b=7.859 c=19.047 β=100.20° Z=4

|1387.2

|3.302

|stable against water solution 298-313K; phase transition at 411K

|{{Cite journal |last1=Makarova |first1=I. P. |last2=Grebenev |first2=V. V. |last3=Vasiliev |first3=I. I. |last4=Dmitricheva |first4=E. V. |last5=Komornikov |first5=V. A. |last6=Dolbinina |first6=V. V. |date=July 2015 |title=Investigation of the structure of Cs3(HSO4)2(H2PO4) single crystals |url=http://link.springer.com/10.1134/S1063774515040148 |journal=Crystallography Reports |language=en |volume=60 |issue=4 |pages=498–507 |doi=10.1134/S1063774515040148 |bibcode=2015CryRp..60..498M |s2cid=93224453 |issn=1063-7745|url-access=subscription }}

Cs4(HSO4)3(H2PO4)

|

|monoclinic

|C2/c

|a=19.945 b=7.8565 c=8.9949 β=100.119° Z=3

|1387.5

|3.301

|colourless

|{{Cite journal |last1=Makarova |first1=I. P. |last2=Grebenev |first2=V. V. |last3=Vasil’ev |first3=I. I. |last4=Dmitricheva |first4=E. V. |last5=Komornikov |first5=V. A. |last6=Dolbinina |first6=V. V. |last7=Mikheikin |first7=A. S. |date=January 2016 |title=Structure of Cs4(HSO4)3(H2PO4) single crystals |url=http://link.springer.com/10.1134/S1063774516010119 |journal=Crystallography Reports |language=en |volume=61 |issue=1 |pages=18–23 |doi=10.1134/S1063774516010119 |bibcode=2016CryRp..61...18M |s2cid=101823664 |issn=1063-7745|url-access=subscription }}{{Cite journal |last1=Makarova |first1=Irina |last2=Grebenev |first2=Vadim |last3=Dmitricheva |first3=Elena |last4=Vasiliev |first4=Ilya |last5=Komornikov |first5=Vladimir |last6=Dolbinina |first6=Valentina |last7=Mikheykin |first7=Alexey |date=2016-02-01 |title=M m H n ( X O 4 ) ( m + n )/2 crystals: structure, phase transitions, hydrogen bonds, conductivity. II. Structure and properties of Cs 3 (HSO 4 ) 2 (H 2 PO 4 ) and Cs 4 (HSO 4 ) 3 (H 2 PO 4 ) single crystals |url=http://scripts.iucr.org/cgi-bin/paper?S2052520615023069 |journal=Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials |volume=72 |issue=1 |pages=133–141 |doi=10.1107/S2052520615023069 |pmid=26830805 |issn=2052-5206|url-access=subscription }}

Cs5(HSO4)2(H2PO4)3

|

|cubic

|I{{overbar|4}}3d

|a=14.5668

|

|

|over 381K goes to tetragonal a=4.965 c=5.016

|{{Cite journal |last1=Grebenev |first1=V. V. |last2=Makarova |first2=I. P. |last3=Ksenofontov |first3=D. A. |last4=Komornikov |first4=V. A. |last5=Dmitricheva |first5=E. V. |date=November 2013 |title=Phase transitions in Cs5(HSO4)2(H2PO4)3 crystal |url=http://link.springer.com/10.1134/S1063774513060138 |journal=Crystallography Reports |language=en |volume=58 |issue=6 |pages=894–898 |doi=10.1134/S1063774513060138 |bibcode=2013CryRp..58..894G |s2cid=94005540 |issn=1063-7745|url-access=subscription }}

Cs6H(HSO4)3(H2PO4)4

|

|cubic

|I{{overbar|4}}3d

|a=14.4758

|3033.38

|3.236

|colourless

|{{Cite journal |last1=Makarova |first1=I. P. |last2=Grebenev |first2=V. V. |last3=Komornikov |first3=V. A. |last4=Selezneva |first4=E. V. |date=November 2016 |title=New crystals of the CsHSO4–CsH2PO4–H2O system |url=http://link.springer.com/10.1134/S1063774516060079 |journal=Crystallography Reports |language=en |volume=61 |issue=6 |pages=918–922 |doi=10.1134/S1063774516060079 |bibcode=2016CryRp..61..918M |s2cid=99983650 |issn=1063-7745|url-access=subscription }}

Cs5(HSO4)3(H2PO4)2

|

|monoclinic

|C2/c

|a=34.07 Å,b=7.661,c=9.158,β=90.44°

|2390

|3.198

|

|{{Cite journal |last1=Haile |first1=Sossina M. |last2=Calkins |first2=Pamela M. |date=November 1998 |title=X-Ray Diffraction Study of Cs5(HSO4)3(H2PO4)2, a New Solid Acid with a Unique Hydrogen-Bond Network |url=https://linkinghub.elsevier.com/retrieve/pii/S0022459698978847 |journal=Journal of Solid State Chemistry |language=en |volume=140 |issue=2 |pages=251–265 |doi=10.1006/jssc.1998.7884|bibcode=1998JSSCh.140..251H |url-access=subscription }}

18-crown[6]·Cs[H2PO4]0.5[HSO4]0.5·3H2O

|

|monoclinic

|C2/c

|a=19.840 b=8.460 c=26.19 β=101.14 Z=8

|4313

|1.689

|dehydrate at 70°

|

CsNH4(HSO4)(H2PO4)

|

|

|

|

|

|

|

|{{Cite journal |last1=Komornikov |first1=V. A. |last2=Timakov |first2=I. S. |last3=Zajnullin |first3=O. B. |last4=Grebenev |first4=V. V. |last5=Makarova |first5=I. P. |last6=Selezneva |first6=E. V. |last7=Ksenofontov |first7=D. A. |date=November 2019 |title=New Crystals in the CsHSO4–CsH2PO4–NH4H2PO4–H2O System |url=http://link.springer.com/10.1134/S1063774519060105 |journal=Crystallography Reports |language=en |volume=64 |issue=6 |pages=984–990 |doi=10.1134/S1063774519060105 |bibcode=2019CryRp..64..984K |s2cid=209509678 |issn=1063-7745|url-access=subscription }}

Cs3NH4(HSO4)3(H2PO4)

|

|

|

|

|

|

|

|

Cs2MgTi(SO4)(PO4)2

|

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Ba4(PO4)2SO4

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NaBa6Zr(PO4)5SO4

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|cubic

|I{{overbar|4}}3d

|a = 10.5449 Z=4

|1172.54

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|eulytite mineral structure

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Ba2Sr2(PO4)2SO4

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Ba3Sr(PO4)2SO4

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Ce2O(HPO4)2(SO4). 4H2O

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|CeIV

|{{Cite journal |last1=König |first1=K.-H. |last2=Eckstein |first2=G. |date=December 1972 |title=Amorphe und kristalline cer(IV)-phosphate als ionenaustauscher—IV Makrosorption, tracersorption und nuklidtrennungen an kristallinen cer(IV)-phosphatsulfaten |url=https://linkinghub.elsevier.com/retrieve/pii/0022190272800241 |journal=Journal of Inorganic and Nuclear Chemistry |language=de |volume=34 |issue=12 |pages=3771–3779 |doi=10.1016/0022-1902(72)80024-1|url-access=subscription }}

Ce2O(HPO4)2.4(SO4)0.6. 2H2O

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|CeIII

|{{Cite journal |last1=König |first1=K.-H. |last2=Eckstein |first2=G. |date=April 1973 |title=Kationenaustausch an kristallinen Cer(III)-phosphatsulfaten |url=https://linkinghub.elsevier.com/retrieve/pii/0022190273802106 |journal=Journal of Inorganic and Nuclear Chemistry |language=de |volume=35 |issue=4 |pages=1359–1367 |doi=10.1016/0022-1902(73)80210-6|url-access=subscription }}

[enH2]0.5[CeIII(PO4)(HSO4)(OH2)]

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|monoclinic

|P21/a

|a=12.999 b=7.150 c=9.212 β=95.33

|

|

|cream colour

|{{Cite journal |last1=Wang |first1=Dan |last2=Yu |first2=Ranbo |last3=Xu |first3=Yaohua |last4=Feng |first4=Shouhua |last5=Xu |first5=Ruren |last6=Kumada |first6=Nobuhiro |last7=Kinomura |first7=Nobukazu |last8=Matsumura |first8=Yasuyuki |last9=Takano |first9=Mikio |date=November 2002 |title=The First Organically Templated Layered Cerium Phosphate-Hydrogen Sulfate: [enH 2 ] 0.5 [Ce III (PO 4 )(HSO 4 )(OH 2 )] |url=http://www.journal.csj.jp/doi/10.1246/cl.2002.1120 |journal=Chemistry Letters |language=en |volume=31 |issue=11 |pages=1120–1121 |doi=10.1246/cl.2002.1120 |issn=0366-7022|url-access=subscription }}

KSr2Eu(PO4)2SO4

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RbSr2Eu(PO4)2SO4

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CsSr2Eu(PO4)2SO4

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[enH2]0.5[Ho(HPO4)(SO4)(H2O)]

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|monoclinic

|P21/a

|a = 12.938 b = 6.834 c = 9.100 β = 88.12°

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|{{Cite journal |last1=Kumada |first1=Nobuhiro |last2=Kumon |first2=Junichi |last3=Miyagawa |first3=Kazuya |last4=Yonesaki |first4=Yoshinori |last5=Takei |first5=Takahiro |last6=Kinomura |first6=Nobukazu |last7=Wang |first7=Dan |last8=Yu |first8=Ranbo |date=2010 |title=Preparation and crystal structure of [enH2]0.5[Ho(HPO4)(SO4)(H2O)] (en; ethylenediamine) |url=http://www.jstage.jst.go.jp/article/jcersj2/118/1375/118_1375_236/_article |journal=Journal of the Ceramic Society of Japan |language=en |volume=118 |issue=1375 |pages=236–240 |doi=10.2109/jcersj2.118.236 |s2cid=98263946 |issn=1348-6535|doi-access=free }}

Pb2Mg2(PO4)2SO4

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MgPb3(PO4)2(SO4)

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|cubic

|I{{overbar|4}}3d

|a = 10.299 Z=4

|1092.4

|5.67

|

|{{Cite journal |last=Durif |first=A. |date=1957 |title= |journal=C. R. Hebd. Séances Acad. Sci. |volume=245 |pages=1151–1152}}

CaPb3(PO4)2(SO4)

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|cubic

|I{{overbar|4}}3d

|a = 10.296 Z=4

|1091.5

|5.77

|

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MnPb3(PO4)2(SO4)

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|cubic

|I{{overbar|4}}3d

|a = 10.258 Z=4

|1079.4

|5.92

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CoPb3(PO4)2(SO4)

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|cubic

|I{{overbar|4}}3d

|a = 10.356 Z=4

|1110.6

|5.78

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NiPb3(PO4)2(SO4)

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|cubic

|I{{overbar|4}}3d

|a = 10.434 Z=4

|1135.9

|5.65

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CuPb3(PO4)2(SO4)

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|cubic

|I{{overbar|4}}3d

|a = 10.422 Z=4

|1132.0

|5.70

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ZnPb3(PO4)2(SO4)

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|cubic

|I{{overbar|4}}3d

|a = 10.449 Z=4

|1140.8

|5.67

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CdPb3(PO4)2(SO4)

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|cubic

|I{{overbar|4}}3d

|a = 10.315 Z=4

|1097.5

|6.17

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SrPb3(PO4)2(SO4)

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|cubic

|I{{overbar|4}}3d

|a = 10.369 Z=4

|1114.8

|5.93

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Th2(PO4)2SO4·2 H2O

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|decompose 450 °C

|{{Cite journal |last1=Brandel |first1=Vladimir |last2=Dacheux |first2=Nicolas |last3=Rousselle |first3=Jérôme |last4=Genet |first4=Michel |date=August 2002 |title=Synthesis of some new thorium phosphates |url=https://linkinghub.elsevier.com/retrieve/pii/S1631074802014194 |journal=Comptes Rendus Chimie |language=en |volume=5 |issue=8–9 |pages=599–606 |doi=10.1016/S1631-0748(02)01419-4}}

Organic derivatives

A catenated sulfophosphate has the sulfur and phosphorus joined by an oxygen atom. In biochemistry, metabolism of sulfate may use such a group, for example with adenosine-5'-phosphosulfate.{{Cite web |last=PubChem |title=Adenosine-5'-phosphosulfate |url=https://pubchem.ncbi.nlm.nih.gov/compound/10238 |access-date=2022-07-14 |website=pubchem.ncbi.nlm.nih.gov |language=en}}

References

{{Reflist}}

{{Phosphates}}

{{Sulfates}}

Category:Phosphates

Category:Mixed anion compounds

Category:Sulfates