REFPROP

{{Short description|Fluid property prediction software}}

{{Infobox software

| name = REFPROP

| logo =

| logo size =

| logo caption =

| screenshot =

| caption =

| developer = National Institute of Standards and Technology (NIST)

| released = {{start date and age|1989}}

| latest release version = 10.0

| latest release date = 2018

| programming language = Fortran

| platform = x86-64

| language = English

| genre = Thermophysical property software

| license = Proprietary

| website = {{URL|https://www.nist.gov/srd/refprop}}

}}

REFPROP is a software program for the prediction of thermophysical properties of fluids, developed by the National Institute of Standards and Technology (NIST).{{cite journal | last1=Huber | first1=Marcia L. | last2=Lemmon | first2=Eric W. | last3=Bell | first3=Ian H. | last4=McLinden | first4=Mark O. | title=The NIST REFPROP Database for Highly Accurate Properties of Industrially Important Fluids | journal=Industrial & Engineering Chemistry Research | volume=61 | issue=42 | date=2022-10-26 | issn=0888-5885 | pmid=36329835 | pmc=9619405 | doi=10.1021/acs.iecr.2c01427 | doi-access=free | pages=15449–15472 }}{{cite book | last1=Reynolds | first1=William C. | last2=Colonna | first2=Piero | title=Thermodynamics | publisher=Cambridge University Press | publication-place=New York, NY, USA | date=2018-09-20 | isbn=978-0-521-86273-8}}{{cite book | last=Penoncello | first=Steven G. | title=Thermal Energy Systems | publisher=CRC Press | date=2018-09-19 | isbn=978-1-351-73657-2 | page=}}

The primary component of REFPROP is an equation of state for each implemented fluid. For most pure fluids, the equation of state is obtained by fitting an expression for the Helmholtz free energy to experimental data. This formulation allows the computation of all equilibrium properties of the fluid, such as density, temperature, pressure, sound speed, heat capacity, second virial coefficients, vapor pressures, saturated liquid and vapor densities, enthalpy of vaporization, entropy, and the Joule-Thomson coefficient.

REFPROP also predicts surface tension, viscosity, and thermal conductivity for many fluids, either using extended corresponding states formulations or fluid-specific equations fit directly to experimental data.

Various methods are used to compute the analogous properties of fluid mixtures.

The full list of fluids properties implemented in REFPROP v10.0 can be found in Table 2 of Huber, et al. (2022).

List of implemented fluids

REFPROP v10.0 implements equation of state models for 147 pure fluids, listed in Table 1. Except for {{chem2|F3N}}, R-13, R-123, and R-152a, all of these are Helmholtz free energy formulations.

REFPROP v10.0 also predicts surface tension, viscosity, and thermal conductivity for most of the listed fluids.

class="wikitable sortable"

|+ Table 1: List of pure fluids implemented in REFPROP v10.0

! Short name !! Full name !! Short formula !! CAS number

1,3-ButadieneButa-1,3-diene{{chem2|C4H6}}106-99-0
1-ButyneBut-1-yne{{chem2|C4H6}}107-00-6
1-PentenePent-1-ene{{chem2|C5H10}}109-67-1
2,2-Dimethylbutane2,2-Dimethylbutane{{chem2|C6H14}}75-83-2
2,3-Dimethylbutane2,3-Dimethylbutane{{chem2|C6H14}}79-29-8
3-Methylpentane3-Methylpentane{{chem2|C6H14}}96-14-0
AcetonePropanone{{chem2|C3H6O}}67-64-1
AcetyleneEthyne{{chem2|C2H2}}74-86-2
AmmoniaAmmonia{{chem2|NH3}}7664-41-7
ArgonArgon{{chem2|Ar}}7440-37-1
BenzeneBenzene{{chem2|C6H6}}71-43-2
Butanen-Butane{{chem2|C4H10}}106-97-8
Butene1-Butene{{chem2|C4H8}}106-98-9
Carbon dioxideCarbon dioxide{{chem2|CO2}}124-38-9
Carbon monoxideCarbon monoxide{{chem2|CO}}630-08-0
Carbonyl sulfideCarbon oxide sulfide{{chem2|COS}}463-58-1
ChlorineChlorine{{chem2|Cl2}}7782-50-5
ChlorobenzeneChlorobenzene{{chem2|C6H5Cl}}108-90-7
cis-Butenecis-2-Butene{{chem2|C4H8}}590-18-1
Cyclobutene1-Cyclobutene{{chem2|C4H6}}822-35-5
CyclohexaneCyclohexane{{chem2|C6H12}}110-82-7
CyclopentaneCyclopentane{{chem2|C5H10}}287-92-3
CyclopropaneCyclopropane{{chem2|C3H6}}75-19-4
D4Octamethylcyclotetrasiloxane{{chem2|C8H24O4Si4}}556-67-2
D5Decamethylcyclopentasiloxane{{chem2|C10H30O5Si5}}541-02-6
D6Dodecamethylcyclohexasiloxane{{chem2|C12H36O6Si6}}540-97-6
DEA2,2'-Iminodiethanol{{chem2|C4H11NO2}}111-42-2
DecaneDecane{{chem2|C10H22}}124-18-5
DeuteriumDeuterium{{chem2|D2}}7782-39-0
Dichloroethane1,2-Dichloroethane{{chem2|C2H4Cl2}}107-06-2
Diethyl etherDiethyl ether{{chem2|C4H10O}}60-29-7
Dimethyl carbonateDimethyl ester carbonic acid{{chem2|C3H6O3}}616-38-6
DimethyletherMethoxymethane{{chem2|C2H6O}}115-10-6
DocosaneDocosane{{chem2|C22H46}}629-97-0
DodecaneDodecane{{chem2|C12H26}}112-40-3
EthaneEthane{{chem2|C2H6}}74-84-0
EthanolEthyl alcohol{{chem2|C2H6O}}64-17-5
Ethylene glycol1,2-Ethandiol{{chem2|C2H6O2}}107-21-1
Ethyl benzenePhenylethane{{chem2|C8H10}}100-41-4
EthyleneEthene{{chem2|C2H4}}74-85-1
Ethylene oxideEthylene oxide{{chem2|C2H4O}}75-21-8
FluorineFluorine{{chem2|F2}}7782-41-4
Heavy waterDeuterium oxide{{chem2|D2O}}7789-20-0
HeliumHelium-4{{chem2|He}}7440-59-7
HeptaneHeptane{{chem2|C7H16}}142-82-5
HexadecaneHexadecane{{chem2|C16H34}}544-76-3
HexaneHexane{{chem2|C6H14}}110-54-3
HydrogenHydrogen{{chem2|H2}}1333-74-0
Hydrogen chlorideHydrogen chloride{{chem2|HCl}}7647-01-0
Hydrogen sulfideHydrogen sulfide{{chem2|H2S}}7783-06-4
Isobutane2-Methylpropane{{chem2|C4H10}}75-28-5
Isobutene2-Methyl-1-propene{{chem2|C4H8}}115-11-7
Isohexane2-Methylpentane{{chem2|C6H14}}107-83-5
Isooctane2,2,4-Trimethylpentane{{chem2|C8H18}}540-84-1
Isopentane2-Methylbutane{{chem2|C5H12}}78-78-4
KryptonKrypton{{chem2|Kr}}7439-90-9
MD2MDecamethyltetrasiloxane{{chem2|C10H30O3Si4}}141-62-8
MD3MDodecamethylpentasiloxane{{chem2|C12H36O4Si5}}141-63-9
MD4MTetradecamethylhexasiloxane{{chem2|C14H42O5Si6}}107-52-8
MDMOctamethyltrisiloxane{{chem2|C8H24O2Si3}}107-51-7
MEAEthanolamine{{chem2|C2H7NO}}141-43-5
MethaneMethane{{chem2|CH4}}74-82-8
MethanolMethanol{{chem2|CH4O}}67-56-1
Methyl linoleateMethyl(Z,Z)-9,12-octadecadienate{{chem2|C19H34O2}}112-63-0
Methyl linolenateMethyl(Z,Z,Z)-9,12,15-octadecatrienoate{{chem2|C19H32O2}}301-00-8
Methyl oleateMethylcis-9-octadecenoate{{chem2|C19H36O2}}112-62-9
Methyl palmitateMethyl hexadecanoate{{chem2|C17H34O2}}112-39-0
Methyl stearateMethyl octadecanoate{{chem2|C19H38O2}}112-61-8
Methyl cyclohexaneMethylcyclohexane{{chem2|C7H14}}108-87-2
MMHexamethyldisiloxane{{chem2|C6H18OSi2}}107-46-0
m-Xylene1,3-Dimethylbenzene{{chem2|C8H10}}108-38-3
NeonNeon{{chem2|Ne}}7440-01-9
Neopentane2,2-Dimethylpropane{{chem2|C5H12}}463-82-1
NitrogenNitrogen{{chem2|N2}}7727-37-9
Nitrogen trifluorideNitrogen trifluoride{{chem2|F3N}}7783-54-2
Nitrous oxideDinitrogen monoxide{{chem2|N2O}}10024-97-2
NonaneNonane{{chem2|C9H20}}111-84-2
Novec649,12301,1,1,2,2,4,5,5,5-Nonafluoro-4-(trifluoromethyl)-3-pentanone{{chem2|C6F12O}}756-13-8
OctaneOctane{{chem2|C8H18}}111-65-9
OrthohydrogenOrthohydrogen{{chem2|H2}}-
OxygenOxygen{{chem2|O2}}7782-44-7
o-Xylene1,2-Dimethylbenzene{{chem2|C8H10}}95-47-6
ParahydrogenParahydrogen{{chem2|H2}}-
PentanePentane{{chem2|C5H12}}109-66-0
PerfluorobutaneDecafluorobutane{{chem2|C4F10}}355-25-9
PerfluorohexaneTetradecafluorohexane{{chem2|C6F14}}355-42-0
PerfluoropentaneDodecafluoropentane{{chem2|C5F12}}678-26-2
Propadiene1,2-Propadiene{{chem2|C3H4}}463-49-0
PropanePropane{{chem2|C3H8}}74-98-6
Propyl cyclohexanen-Propyl cyclohexane{{chem2|C9H18}}1678-92-8
PropylenePropene{{chem2|C3H6}}115-07-1
Propylene oxide1,2-Epoxy propane{{chem2|C3H6O}}75-56-9
PropynePropyne{{chem2|C3H4}}74-99-7
p-Xylene1,4-Dimethylbenzene{{chem2|C8H10}}106-42-3
R11Trichlorofluoromethane{{chem2|CCl3F}}75-69-4
R1123Trifluoroethylene{{chem2|C2HF3}}359-11-5
R1131,1,2-Trichloro-1,2,2-trifluoroethane{{chem2|C2Cl3F3}}76-13-1
R1141,2-Dichlorotetrafluoroethane{{chem2|C2Cl2F4}}76-14-2
R115Chloropentafluoroethane{{chem2|C2ClF5}}76-15-3
R116Hexafluoroethane{{chem2|C2F6}}76-16-4
R12Dichlorodifluoromethane{{chem2|CCl2F2}}75-71-8
R1216Hexafluoropropene{{chem2|C3F6}}116-15-4
R1224yd(Z)(Z)-1-Chloro-2,3,3,3-tetrafluoropropene{{chem2|C3HClF4}}111512-60-8
R1232,2-Dichloro-1,1,1-trifluoroethane{{chem2|C2HCl2F3}}306-83-2
R1233zd(E)trans-1-Chloro-3,3,3-trifluoro-1-propene{{chem2|C3H2ClF3}}102687-65-0
R1234yf2,3,3,3-Tetrafluoroprop-1-ene{{chem2|C3F4H2}}754-12-1
R1234ze(E)trans-1,3,3,3-Tetrafluoropropene{{chem2|C3F4H2}}29118-24-9
R1234ze(Z)cis-1,3,3,3-Tetrafluoropropene{{chem2|C3F4H2}}29118-25-0
R1241-Chloro-1,2,2,2-tetrafluoroethane{{chem2|C2HClF4}}2837-89-0
R1243zf3,3,3-Trifluoropropene{{chem2|C3H3F3}}677-21-4
R125Pentafluoroethane{{chem2|C2HF5}}354-33-6
R13Chlorotrifluoromethane{{chem2|CClF3}}75-72-9
R1336mzz(Z)(Z)-1,1,1,4,4,4-Hexafluoro-2-butene{{chem2|C4H2F6}}692-49-9
R134a1,1,1,2-Tetrafluoroethane{{chem2|C2H2F4}}811-97-2
R13I1Trifluoroiodomethane{{chem2|CF3I}}2314-97-8
R14Tetrafluoromethane{{chem2|CF4}}75-73-0
R141b1,1-Dichloro-1-fluoroethane{{chem2|C2H3Cl2F}}1717-00-6
R142b1-Chloro-1,1-difluoroethane{{chem2|C2H3ClF2}}75-68-3
R143a1,1,1-Trifluoroethane{{chem2|C2H3F3}}420-46-2
R152a1,1-Difluoroethane{{chem2|C2H4F2}}75-37-6
R161Fluoroethane{{chem2|C2H5F}}353-36-6
R21Dichlorofluoromethane{{chem2|CHClF}}75-43-4
R218Octafluoropropane{{chem2|C3F8}}76-19-7
R22Chlorodifluoromethane{{chem2|CHClF2}}75-45-6
R227ea1,1,1,2,3,3,3-Heptafluoropropane{{chem2|C3HF7}}431-89-0
R23Trifluoromethane{{chem2|CHF3}}75-46-7
R236ea1,1,1,2,3,3-Hexafluoropropane{{chem2|C3H2F6}}431-63-0
R236fa1,1,1,3,3,3-Hexafluoropropane{{chem2|C3H2F6}}690-39-1
R245ca1,1,2,2,3-Pentafluoropropane{{chem2|C3H3F5}}679-86-7
R245fa1,1,1,3,3-Pentafluoropropane{{chem2|C3H3F5}}460-73-1
R32Difluoromethane{{chem2|CH2F2}}75-10-5
R365mfc1,1,1,3,3-Pentafluorobutane{{chem2|C4H5F5}}406-58-6
R40Methyl chloride{{chem2|CH3Cl}}74-87-3
R41Fluoromethane{{chem2|CH3F}}593-53-3
RC318Octafluorocyclobutane{{chem2|C4F8}}115-25-3
RE143aMethyl trifluoromethyl ether{{chem2|C2H3F3O}}421-14-7
RE245cb2Methyl pentafluoroethyl ether{{chem2|C3H3F5O}}22410-44-2
RE245fa22,2,2-Trifluoroethyl-difluoromethyl-ether{{chem2|C3H3F5O}}1885-48-9
RE347mcc(HFE7000)1,1,1,2,2,3,3-Heptafluoro-3methoxypropane{{chem2|C4H3F7O}}375-03-1
Sulfur dioxideSulfur dioxide{{chem2|O2S}}7446-09-5
Sulfur hexafluorideSulfur hexafluoride{{chem2|SF6}}2551-62-4
TolueneMethylbenzene{{chem2|C7H8}}108-88-3
trans-Butenetrans-2-Butene{{chem2|C4H8}}624-64-6
UndecaneUndecane{{chem2|C11H24}}1120-21-4
Vinyl chlorideChloroethylene{{chem2|C2H3Cl}}75-01-4
WaterWater{{chem2|H2O}}7732-18-5
XenonXenon{{chem2|Xe}}7440-63-3

See also

References

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