Wobbe index
{{Short description|Indicator of the interchangeability of fuel gases}}
{{More citations needed|date=February 2010}}
The Wobbe index (WI) or Wobbe number{{cite book
|last=Treloar |first=R.D.
|title=Gas Installation Technology
|url=https://archive.org/details/gasinstallationt00trel |url-access=limited |publisher=Blackwell
|year=2005
|isbn=978-1-4051-1880-4
|ref=Treloar, Gas Installation Technology
|page=[https://archive.org/details/gasinstallationt00trel/page/n39 24]
}} is an indicator of the interchangeability of fuel gases such as natural gas, liquefied petroleum gas (LPG), and town gas and is frequently defined in the specifications of gas supply and transport utilities.
If is the higher heating value, or higher calorific value, and is the specific gravity, the Wobbe index, , is defined as:
:
:
is the density of the gas at standard conditions, the definition of which changed in 1982. Published Wobbe data may be using 0 °C, 15 °C, 15.56 °C, 20 °C or 25 °C. EU directives on gas quality use 15 °C in accordance with ISO 13443 and ISO 6976.
is the density of air at standard conditions, is the molar mass of the gas and is the molar mass of air which is about 28.96 kg/kmol.
.
The Wobbe index is used to compare the combustion energy output of different composition fuel gases in an appliance (fire, cooker etc.). If two fuels have identical Wobbe indices then for given pressure and valve settings the energy output will also be identical. Typically variations of up to 5% are allowed as these would not be noticeable to the consumer.
The Wobbe index is a critical factor to minimise the impact of the changeover when analyzing the use of substitute natural gas (SNG) fuels such as propane-air mixtures. The Wobbe index also requires the addition of propane to some upgraded biomethane products,{{Cite web |url=http://www.biogasmax.eu/media/d3_3v2biogasmax_iwes_v2f_nov2010__052078600_1109_10022011.pdf |title=Bio Gas max |access-date=2012-09-07 |archive-date=2015-09-23 |archive-url=https://web.archive.org/web/20150923190029/http://www.biogasmax.eu/media/d3_3v2biogasmax_iwes_v2f_nov2010__052078600_1109_10022011.pdf |url-status=dead }} particularly in regions where natural gas has a high calorific value such as Sweden.[http://www.sgc.se/gasification2011/Resources/Ingemar_Gunnarsson.pdf Ingemar Gunnarsson]
The Wobbe index has its origins in the 1920's with Italian physicist and engineer Goffredo Wobbe.{{Cite web |url=https://www.aga.org/sites/default/files/legacy-assets/SiteCollectionDocuments/KnowledgeCenter/OpsEng/CodesStandards/0604GASINTERCHANGEABILITYSTAFFPAPER.pdf |title=American Gas Association |access-date=2022-03-01 |archive-date=2021-12-29 |archive-url=https://web.archive.org/web/20211229225516/https://www.aga.org/sites/default/files/legacy-assets/SiteCollectionDocuments/KnowledgeCenter/OpsEng/CodesStandards/0604GASINTERCHANGEABILITYSTAFFPAPER.pdf |url-status=dead }}
Wobbe index of common fuel gases<ref>[http://www.engineeringtoolbox.com/wobbe-index-d_421.html Wobbe Index and Fuel Gases]</ref>
Note that these Wobbe numbers below are not calculated at 15 °C and so are not correct according to ISO 13443, see Standard temperature and pressure.
class="wikitable sortable" | ||||
Fuel gas || Upper index kcal/Nm³ || Lower index kcal/Nm³ || Upper index MJ/m³ || Lower index MJ/m³ | ||||
---|---|---|---|---|
U
| Hydrogen | 11,528 | 9,715 | 48.23 | 40.65 |
Methane | 12,735 | 11,452 | 53.28 | 47.91 |
Ethane | 16,298 | 14,931 | 68.19 | 62.47 |
Ethylene | 15,253 | 14,344 | 63.82 | 60.01 |
Natural gas | 12,837 | 11,597 | 53.71 | 48.52 |
Propane | 19,376 | 17,817 | 81.07 | 74.54 |
Propylene | 18,413 | 17,180 | 77.04 | 71.88 |
n-butane | 22,066 | 20,336 | 92.32 | 85.08 |
Iso-butane | 21,980 | 20,247 | 91.96 | 84.71 |
Butylene-1 | 21,142 | 19,728 | 88.46 | 82.54 |
LPG | 20,755 | 19,106 | 86.84 | 79.94 |
Acetylene | 14,655 | 14,141 | 61.32 | 59.16 |
Carbon monoxide | 3,060 | 3,060 | 12.80 | 12.80 |
Usage
The Wobbe index is expressed in MJ/Nm³ (where 'Nm³' indicates'm³ in Normal conditions), or sometimes in BTU/scf. In the case of natural gas (molar mass 17 g/mol), the typical heating value is around 39 MJ/Nm³ (1,050 BTU/scf) and the specific gravity is approximately 0.59, giving a typical Wobbe index of 51 MJ/Nm³ (1,367 BTU/scf).
There are three ranges or "families" of fuel gases that have been internationally agreed based on Wobbe index. Family 1 covers manufactured gases, family 2 covers natural gases (with high and low ranges) and family 3 covers liquefied petroleum gas (LPG). Combustion equipment is typically designed to burn a fuel gas within a particular family: hydrogen-rich town gas, natural gas or LPG.
class="wikitable" style="text-align: center;" | ||
Family
! Type of gas ! Wobbe index range (MJ/Nm3) | ||
---|---|---|
1 | Town gas / Syngas
| 22.5 – 30.0 | 24.0 – 29.0 |
2 L | Natural
| 39.0 – 45.0 | |
2 H | | 45.5 – 55.0 | 48.0 – 53.0 |
3 | LPG
| 73.5 – 87.5 | 72.0 – 87.0 |
Other flame characteristics and composition limits may determine the acceptability of the replacement gas, e.g. flame speed, "yellow tipping" due to incomplete combustion, sulfur content, oxygen content, etc.
Limitations
In spite of its usefulness, Wobbe index alone is not a good indicator of the interchangeability of two or more gases, or mixtures of them. It is necessary to bear in mind other criteria while determining the plenty substitution of a fuel by other, different of the one used to adjust the burning system.{{cite web
|url=https://unalmed.academia.edu/DanielFl%C3%B3rezOrrego/Papers/1913409/Intercambiabilidad_de_gases_combustibles_Fuel_Gas_Interchangeability_Intercambiabilidade_dos_gases_combustiveis/
|title=Fuel Gas Interchangeability
|author=Flórez-Orrego, Daniel, Escola Politécnica da USP
|accessdate=8 Sep 2012
}}
References
- {{cite web | title = The Wobbe Index and Natural Gas Interchangeability | date = 2007-07-30 | publisher = Emerson Process Management | url = http://www.documentation.emersonprocess.com/groups/public/documents/application_notes-tech._briefs/d301334x012.pdf?&xBusinessUnit=Remote%20Automation%20Solutions}}
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