dipotassium phosphate
{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 433052081
| Name =
| ImageFile = Di-potassium monohydrogen phosphate.svg
| ImageSize = 150px
| ImageFile1 = Hydrogenfosforečnan draselný.JPG
| ImageFile2 = Dipotassium-phosphate-3D-vdW.png
| ImageSize1 = 180px
| IUPACName = Potassium hydrogen phosphate
| OtherNames = Potassium monohydrogen phosphate
Phosphoric acid dipotassium salt
Potassium phosphate dibasic
| Section1 = {{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 22858
| ChEMBL_Ref = {{ebicite|changed|EBI}}
| ChEMBL = 1200459
| ChEBI_Ref = {{ebicite|changed|EBI}}
| ChEBI = 131527
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = CI71S98N1Z
| UNII1_Ref = {{fdacite|correct|FDA}}
| UNII1 = RJK174X3TZ
| UNII1_Comment = (trihydrate)
| InChI = 1/2K.H3O4P/c;;1-5(2,3)4/h;;(H3,1,2,3,4)/q2*+1;/p-2
| SMILES = [K+].[K+].[O-]P([O-])(=O)O
| InChIKey = ZPWVASYFFYYZEW-NUQVWONBAH
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/2K.H3O4P/c;;1-5(2,3)4/h;;(H3,1,2,3,4)/q2*+1;/p-2
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = ZPWVASYFFYYZEW-UHFFFAOYSA-L
| CASNo = 7758-11-4
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo2 = 16788-57-1
| CASNo2_Ref = {{cascite|correct|CAS}}
| CASNo2_Comment = (trihydrate)
| PubChem = 24450
| EINECS = 231-834-5
}}
| Section2 = {{Chembox Properties
| Formula = K2HPO4
| MolarMass = 174.2 g/mol
| Appearance = white powder
deliquescent
| Odor = odorless
| Density = 2.44 g/cm3
| Solubility = 149.25 g/100 mL (20 °C)
| SolubleOther = slightly soluble in alcohol
| MeltingPt= >
| MeltingPtC = 465
| MeltingPt_notes = decomposes
| pKa = 12.4
| pKb = 6.8
}}
| Section3 =
| Section4 =
| Section5 =
| Section6 =
| Section7 = {{Chembox Hazards
| ExternalSDS =
| NFPA-H = 1
| NFPA-F = 0
| NFPA-R = 0
| MainHazards =
| FlashPt = Non-flammable
}}
| Section8 = {{Chembox Related
| OtherAnions =
| OtherCations = Disodium phosphate
Diammonium phosphate
| OtherCompounds = Monopotassium phosphate
Tripotassium phosphate
}}
}}
Dipotassium phosphate (also dipotassium hydrogen orthophosphate or potassium phosphate dibasic) is the inorganic compound with the formula K2HPO4.(H2O)x (x = 0, 3, 6). Together with monopotassium phosphate (KH2PO4.(H2O)x), it is often used as a fertilizer, food additive, and buffering agent.{{Ullmann|author1=Klaus Schrödter|author2=Gerhard Bettermann|author3=Thomas Staffel|author4=Friedrich Wahl|author5=Thomas Klein|author6=Thomas Hofmann|title=Phosphoric Acid and Phosphates|doi=10.1002/14356007.a19_465.pub3|year=2012}} It is a white or colorless solid that is soluble in water.
It is produced commercially by partial neutralization of phosphoric acid with two equivalents of potassium chloride:
: H3PO4 + 2 KCl → K2HPO4 + 2 HCl
Uses
As a food additive, dipotassium phosphate is used in imitation dairy creamers, dry powder beverages, mineral supplements, and starter cultures.{{cite book|title=Food Additives|editor=John H. Thorngate III |editor2=Seppo Salminen |editor3=Larry A. Branen |editor4=Michael P. Davidson|publisher=CRC Press|year=2001|chapter=Food Phosphates|series=Food Science and Technology |volume=116 | isbn=978-0-8247-9343-2 |doi=10.1201/9780824741709.ch25|doi-broken-date=2024-11-11 }} It functions as an emulsifier, stabilizer and texturizer; it is also a buffering agent, and chelating agent especially for the calcium in milk products.{{cite web|url=https://us.myprotein.com/thezone/supplements/dipotassium-phosphate-used/|title=What is dipotassium phosphate?|date=30 April 2018|access-date=2020-09-09}}
As a food additive, dipotassium phosphate is generally recognized as safe by the United States Food and Drug Administration,{{cite web|url=http://www.cfsan.fda.gov/~dms/opascogd.html|title=Database of Select Committee on GRAS Substances (SCOGS) Reviews|access-date=2008-03-22|archive-date=2007-05-21|archive-url=https://web.archive.org/web/20070521071111/http://www.cfsan.fda.gov/~dms/opascogd.html|url-status=dead}} (listed as "potassium phosphate, dibasic") and is commonly used (in conjunction with other inorganic salts) to add taste to bottled water.{{Cite web|url=https://waterpurificationguide.com/brands-of-bottled-water-with-electrolytes/|title=Brands Of Bottled Water With Electrolytes (Confirmed By Lab Tests) - Water Purification Guide}}
References
{{Phosphates}}
{{Potassium compounds}}
Category:Inorganic fertilizers
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